全文获取类型
收费全文 | 39138篇 |
免费 | 3430篇 |
国内免费 | 5514篇 |
专业分类
测绘学 | 3324篇 |
大气科学 | 4388篇 |
地球物理 | 7681篇 |
地质学 | 20760篇 |
海洋学 | 3136篇 |
天文学 | 2010篇 |
综合类 | 3623篇 |
自然地理 | 3160篇 |
出版年
2024年 | 171篇 |
2023年 | 465篇 |
2022年 | 1001篇 |
2021年 | 1138篇 |
2020年 | 941篇 |
2019年 | 998篇 |
2018年 | 5747篇 |
2017年 | 4857篇 |
2016年 | 3529篇 |
2015年 | 1330篇 |
2014年 | 1239篇 |
2013年 | 1237篇 |
2012年 | 2278篇 |
2011年 | 3970篇 |
2010年 | 3232篇 |
2009年 | 3380篇 |
2008年 | 2826篇 |
2007年 | 3177篇 |
2006年 | 798篇 |
2005年 | 801篇 |
2004年 | 842篇 |
2003年 | 782篇 |
2002年 | 630篇 |
2001年 | 413篇 |
2000年 | 381篇 |
1999年 | 340篇 |
1998年 | 243篇 |
1997年 | 214篇 |
1996年 | 192篇 |
1995年 | 143篇 |
1994年 | 169篇 |
1993年 | 116篇 |
1992年 | 93篇 |
1991年 | 69篇 |
1990年 | 54篇 |
1989年 | 43篇 |
1988年 | 45篇 |
1987年 | 32篇 |
1986年 | 16篇 |
1985年 | 23篇 |
1984年 | 4篇 |
1983年 | 9篇 |
1982年 | 10篇 |
1981年 | 28篇 |
1980年 | 28篇 |
1979年 | 15篇 |
1976年 | 9篇 |
1958年 | 10篇 |
1957年 | 7篇 |
1954年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
81.
François Farges 《Physics and Chemistry of Minerals》2009,36(8):463-481
Cr K-edge XANES spectra were obtained for a variety of Cr-bearing model compounds containing Cr(II), Cr(III), Cr(IV), Cr(V) and Cr(VI), in which the Cr-site symmetry is D4h, Oh and Td. The centroid position of the pre-edge feature is a better indicator of the Cr valence than the edge position. In Cr-rich oxides, higher-energy transitions must be excluded in order to refine a robust valence for Cr. The pre-edge for chromates is not unique and varies as a function of the CrO4 2? moiety distortion, which is often related to Cr-polymerization (monochromate vs. dichromate). Both the analogy with the Mn K-pre-edge information and ab initio FEFF calculations of the pre-edge feature for Cr(III) and Cr(VI) confirm the experimental trends. This methodology is applied to the Cr K-edge pre-edge feature collected in gems (emerald, spinel and ruby), the layered minerals fuchsite and kämmererite, two Cr-bearing aqueous solutions and a set of sodo-calcic silicate glasses used for bottling sparkling white wine. In emerald and fuchsite, the Cr-site is differently distorted than its ruby or spinel counterpart. In a Cr(III)-bearing aqueous solution and sodo-calcic glass, no evidence for Cr(III) with Td and C3v symmetry is detected. However, minor amounts of chromate moieties (most likely monomeric) are detected in a glass synthesized in air. Preliminary spectra for the wine bottle glass suggest that only trace amounts of chromates might possibly be present in these glasses. 相似文献
82.
83.
西藏甲玛-卡军果推-滑覆构造系特征 总被引:5,自引:0,他引:5
通过矿区填图和路线调查,结合室内研究,指出:①甲玛-卡军果推-滑覆构造系由印度-欧亚板块碰撞引发,具有递进变形、自盆地中心向边部推覆、新盖老等特点,强变形于50Ma±。②推覆体下盘为叶巴组构造岩系;推覆体由上侏罗统和下白垩统碳酸盐-碎屑沉积岩系构成,主体为轴面北倾的复式褶皱,自南而北分为前部带、中部带和后部带。滑覆构造系推覆形成的复背斜轴部高位岩块失稳向北滑覆形成,自南而北分为后部带、中部带和前部带。③导致矿区蚀变的主要岩浆活动发生于推覆强变形后的松弛期,上侵受近南北向基底断裂和推覆断裂联合控制,就位受控于前部带推-滑覆褶断系,其后发生多次构造-岩浆-成矿液叠加,造就甲玛铜多金属矿床。 相似文献
84.
Despite a recent increase in the number of vulnerability analyses there has been relatively little discussion of vulnerability
assessment of social–environment system, especially when they face multiple hazards. In this study, we developed an applicable
and convenient method to assess vulnerability of social–environment system at a regional scale. Vulnerability is quantified
by measuring three critical elements (i.e. hazards, sensitivity, and resilience) through some key variables. The results showed
that vulnerability is high in Miaofeng Mountain in Mengtougou District, the hills of Pinggu County and the riparian zones
of the lower courses of the Beiyun and Yongding Rivers; but low in the city of Beijing and the southwestern part of the Fangshan
District. Areas of very high, high, medium, and low-vulnerability account for 6.19, 25.48, 33.06, and 35.27% of the total
area, respectively. The degree of vulnerability decreases in a northwest direction in mountainous areas and declines from
watercourses to riparian zones along a lateral direction in the plain. Some adaptive strategies are also proposed. 相似文献
85.
The soil leakage ratio in the Mudu watershed,China 总被引:3,自引:0,他引:3
86.
储层沉积-成岩过程中物性演化的主控因素 总被引:4,自引:0,他引:4
对鄂尔多斯盆地Y25、Zh40区块长6段储层的岩石学特征、微观孔隙结构、成岩作用等进行详细研究.研究发现,胶结作用对储层质量的影响具有双重作用.胶结作用一定程度上提高储层的抗压实能力,也为后期的次生溶蚀提供物质基础,但胶结物的产生也占据一定的孔隙空间.两区块储层成岩作用是物性演化的最主要控制因素,储层类型为次生低渗透储层(或成岩型低渗透储层).Y25区块表现为早期胶结作用和后期的溶蚀作用强;Zh40区块表现为早期压实作用强,后期溶蚀作用、交代作用强.储层形成过程中物性演化的主要控制因素是沉积环境基础上,成岩场和构造应力场共同作用的结果. 相似文献
87.
Bristen granite is a body of fine-grained leucogranite occurring in the Gotthard rail base tunnel in the Central Alps. During construction of the tunnel, Bristen granite (Brgr) has been drilled along a 600 m long section. The aplite-granite belongs to the suite of Variscan granitoid intrusions of the Aar massif and contains a variety of accessory minerals typical of highly differentiated granites. Rock forming fluorite, partly enriched in yttrium (Y) and rare earth elements (REE), is intergrown with the late Y- and REE-bearing carbonate mineral synchysite. The granite contains a variety of Ti- and Y-REE-niobates, thorite, and zircon. Compared with the calc-alkaline central Aar granite (cAgr), Bristen granite is strongly depleted in Ti, P, Mg, Sr, and Ba and shows a remarkable enrichment in incompatible elements such as Rb, Th, U, Nb, Y, HREE and F. Bristen granite is the most evolved granitoid rock of the Aar massif. The composition of Brgr is typical of post-collisional reduced (ferroan) A-type granites. The Brgr melt formed in the lower crust and crystallized from a highly differentiated melt at the cotectic point in the quartz-feldspar system close to 100 MPa and 700 °C. The Brgr intruded as a small isolated stock pre-Variscan gneisses with sharply discordant contacts. The primary igneous host of Nb, Ta, Y, U, Th and REE is biotite in addition to minor amounts of allanite, and zircon. The presence of Y-REE-fluorite, synchysite, parisite and Y- and Ti-niobates and other REE-minerals can be related to reaction of igneous biotite and primary fluorite with hydrothermal fluids. The reaction is associated with alpine metamorphism, because Y-bearing fluorite and synchysite have been reported from Alpine fissures. The transformation of primary biotite to chlorite and muscovite released the heavy metal oxides under lower greenschist facies conditions that formed the Alpine diagnostic mineral stilpnomelane at about 300 °C. 相似文献
88.
区内中—下三叠统隆务河群(T1-2L)属巨厚复理石相,显示出以浊流为主的深海沉积特征;通过沉积相分析,整个隆务河群由下而上呈一个明显的变细、变薄的序列,呈一个较完整的海底扇退积型沉积序列。 相似文献
89.
Kazem Kazemi Ali Kananian Yilin Xiao Fatemeh Sarjoughian 《Arabian Journal of Geosciences》2018,11(22):717
The Haji Abad intrusion is a well-exposed Middle Eocene I-type granodioritc pluton in the Urumieh–Dokhtar magmatic assemblage (UDMA). The major constituents of the investigated rocks are K-feldspar, quartz, plagioclase, pyroxene, and minor Fe–Ti oxide and hornblende. The plagioclase compositions fall in the labradorite, andesine, and oligoclase fields. The amphiboles range in composition from magnesio-hornblende to tremolite–hornblende of the calcic-amphibole group. Most pyroxenes principally plot in the field of diopside. The calculated average pressure of emplacement is 1.9 kbar for the granodioritic rocks, crystallizing at depths of about 6.7 km. The highest pressure estimated from clinopyroxene geobarometry (5 kbar) reflects initial pyroxene crystallization pressure, indicating initial crystallization depth (17.5 km) in the Haji Abad granodiorite. The estimated temperatures using two-feldspar thermometry give an average 724 °C. The calculated average temperature for clinopyroxene crystallization is 1090 °C. The pyroxene temperatures are higher than the estimated temperature by feldspar thermometry, indicating that the pyroxene and feldspar temperatures represent the first and late stages of magmatic crystallization of Haji Abad granodiorite, respectively. Most pyroxenes plot above the line of Fe3+?=?0, indicating they crystallized under relatively high oxygen fugacity or oxidized conditions. Furthermore, the results show that the Middle Eocene granitoids crystallized from magmas with H2O content about 3.2 wt%. The relatively high water content is consistent with the generation environment of HAG rocks in an active continental margin and has allowed the magma to reach shallower crustal levels. The MMEs with ellipsoidal and spherical shapes show igneous microgranular textures and chilled margins, probably indicating the presence of magma mixing. Besides, core to rim compositional oscillations (An and FeO) for the plagioclase crystals serve as robust evidence to support magma mixing. The studied amphiboles and pyroxenes are grouped in the subalkaline fields that are consistent with crystallization from I-type calc-alkaine magma in the subduction environment related to active continental margin. Mineral chemistry data indicate that Haji Abad granodiorites were generated in an orogenic belt related to the volcanic arc setting consistent with the subduction of Neo-Tethyan oceanic crust beneath the central Iranian microcontinent. 相似文献
90.
采用分子动力学模拟方法,对舍烷基长链阳离子表面活性剂改性有机蒙脱石的层间域内分子环境及烷基长链排列状况进行模拟研究,并考察改性剂负载量与层间域含水量的改变对烷基链排列方式和活动性以及表面活性剂离子中N,C原子的分布状况的影响.1.0倍阳离子交换容量改性的有机蒙脱石在含少量水的情况下(干态),N,C原子均呈双层分布,表明烷基长链为双层平卧排列.含水量的提高(湿态)会导致烷基链从双层分布向在层闻域内均匀分布转变.2.0倍阳离子交换容量改性的有机蒙脱石在舍少量水的情况下(干态),烷基链呈双层倾斜分布于层间域内,烷基链的头部靠近四面体片层.含水量的提高(湿态)对烷基链在层间域内分布状态影响有限,但会导致烷基链整体向层间域中心平面移动,水分子优先占据靠近四面体片层的位置. 相似文献