THERMOLUMINESCENCE AND THE TERRESTRIAL AGE OF METEORITES

The use of thermoluminescence (TL) to determine the terrestrial age of meteorites is investigated. It is found that meteorites can be divided into two groups. One group, in which members lose their low temperature TL rather rapidly (the “low retentivity” group), may be dated up to about 100 years after fall, although with little accuracy. The other (the “high” group) is more retentive, and may still be dated several hundred years after fall. A meteorite of unknown date of fall may be assigned to the high or low group by laboratory determination of the rate of decay of the low temperature TL. Weathering coats the grains with limonite and lowers the intensity of the TL. The percentage reduction is constant for various intensities, but the peak height ratio is changed. Therefore, for weathered specimens, a method which examines the decrease in the intensity of a single peak is preferred to one which depends upon peak height ratios: this is made possible by artificially irradiating the meteorites. The following terrestrial ages for finds were obtained: Plainview 225–300 years; Dimmitt 280–330 years; Calliham 350–400 years. Bluff, Etter, Potter, Shields and Wellman (c) proved to be too old to be dated by our methods (≥ 500 years). None of the low group finds available to us proved to be young enough to be dated precisely. Terrestrial ages indicate an extremely low efficiency of recovery (≤ 1%) for meteorites that are not seen to fall. Artificially irradiating the meteorites also revealed the fact that 9 of our 19 meteorites were saturated with respect to thermoluminescence when they entered the atmosphere, and therefore that a technique based on this phenomenon would not be applicable to such specimens to obtain their cosmic ray exposure age.     

Assessing the suitability of OSPAR EcoQOs for eutrophication vs ICES criteria for England and Wales

This paper provides a preliminary evaluation of the suitability of OSPAR Ecological Quality objectives for eutrophication for coastal and offshore waters of England and Wales on the basis of ICES criteria. In principle, EcoQOs are easy to understand, but responses to nutrient enrichment are complex. Few studies provide unequivocal evidence of links between inputs and response. Monitoring is generally feasible and in place, but needs to be improved. The best EcoQO is winter nutrient concentrations. Chlorophyll concentrations are a good indicator in environments susceptible to nutrient enrichment. The EcoQO for zoobenthos/fish kills potentially meets all criteria for a good indicator; EcoQOs for phytoplankton indicator species, oxygen concentrations and zoobenthos changes do not. Greater emphasis needs to be placed on seasonal effects of nutrient inputs and phytoplankton response, natural susceptibility of different water bodies, differences between coastal and offshore environments, and developing longer time series of data.     

Cluster analysis of a regional-scale soil geochemical dataset in northern California

A regional-scale soil geochemical study was conducted within a 22,000 km² area in northern California including the Sierra Nevada, Sacramento Valley, and northern Coast Range. Over 1300 soil samples were chemically analyzed for 42 elements. The distribution of distinct groups of elements demonstrates the interplay of geologic, hydrologic, geomorphologic and anthropogenic factors; however, it is difficult to fully appreciate the complexity of geochemical transport and weathering processes on a landscape-scale in an area of very complex geology with such a large dataset containing more than 40 variables. To examine the data from a perspective of multi-element groupings, cluster analyses were applied to the dataset. The analysis identified several groups of elements whose spatial patterns could be related to specific geologic sources.     

Distribution patterns of soil lichens across the principal biomes of southern Africa

The present study was undertaken to assess baseline distribution patterns for soil lichens occurring in the principal biomes of southern Africa, and to analyse their relationship to selected environmental parameters. Among the lichen species found across our survey sites, four distinct groups could be delineated, each as distinct consortium of lichen species sharing particular morphological characters (e.g. growth-form, pigmentation and type of photobiont kind). These groups are largely correlated with specific environmental parameters. These findings suggest that lichens may serve as valuable bioindicators for evaluating climate and soil change in this region of Africa.     

Dissolved copper and copper-organic complexes in the Narragansett Bay estuary

The geochemistry of dissolved copper-organic complexes was investigated in the estuarine waters of Narragansett Bay. A transect survey was conducted in August 1980, while one mid-bay station was monitored from March through August of that year. The transect data indicated that most of the copper-organic complexes enter the bay via sewage effluent which is discharged into the Providence River at the head of the bay. Organic copper concentrations in the estuary ranged from 0.12 to 2.30 μg kg^?1 and comprised from 14 to 70% of the total dissolved copper. The concentration of copper-organic complexes was not directly related to the amount of dissolved organic matter; and recently generated organic material from phytoplankton production within the bay had a negligible influence on the fraction of dissolved copper which was organically bound.The major source of total copper to the bay is anthropogenic inputs from sewage effluents. Particulate and dissolved copper concentrations ranged from 0.06 to 2.42 and 0.23 to 16.4 μg kg^?1, respectively, giving average values of about 40% particulate and 60% dissolved copper. Particulate copper concentrations decreased rapidly from the upper to the lower bay as a result of both removal and dilution. About 75% of the dissolved copper entering the bay is rapidly removed in the Providence River and upper bay, and the remaining portion (which is largely organic copper) follows conservative mixing in the mid to lower bay. The data suggest that copper binding by dissolved organic matter may be an important control on the riverine flux of dissolved copper through estuaries into coastal and oceanic waters.     

Late‐glacial and Holocene river development in the Teleorman Valley on the southern Romanian Plain

This paper reports on a radiocarbon‐dated sequence of alluvial terraces from the Teleorman Valley in the southern Romanian Plain and represents the first Late‐glacial and well‐constrained Holocene alluvial sequence from the lower Danube Valley of southeast Europe. The two earliest and most extensive terraces (T1 and T2) are dissected by large, high‐amplitude palaeochannels, which are dated to ca. 12 800 yr BP and are comparable to large meandering palaeochannels identified from other Late glacial contexts across northern and central Europe. The remaining sequence of alluvial deposits show changes in river activity and accelerated sedimentation around 4900–4800 yr BP, 4000–3800 yr BP, 3300–2800 yr BP, 1000 yr BP and within the past 200 yr. A phase of tributary stream alluvial fan deposition is dated to ca. 2400 yr BP. All these periods of alluvial sedimentation correlate well with episodes of climatic cooling, higher rainfall and enhanced river activity, both in terms of incision and greater lateral mobility as well as increased flood frequency and magnitude identified elsewhere in central, western and northern Europe. Human activity appears to have had little effect on this river environment and significant fine‐grained sedimentation is not noted until ca. 2400 yr BP, approximately 5000 yr after the first neolithic farmers settled the area. Whether this record of river activity truly reflects the impact of prehistoric societies on this catchment will only be elucidated through further, ongoing detailed archaeological research. Copyright © 2003 John Wiley & Sons, Ltd.     

Sulfur chemistry in the middle atmosphere of Venus

Venus Express measurements of the vertical profiles of SO and SO₂ in the middle atmosphere of Venus provide an opportunity to revisit the sulfur chemistry above the middle cloud tops (～58 km). A one dimensional photochemistry-diffusion model is used to simulate the behavior of the whole chemical system including oxygen-, hydrogen-, chlorine-, sulfur-, and nitrogen-bearing species. A sulfur source is required to explain the SO₂ inversion layer above 80 km. The evaporation of the aerosols composed of sulfuric acid (model A) or polysulfur (model B) above 90 km could provide the sulfur source. Measurements of SO₃ and SO (a¹Δ → X³Σ^-) emission at 1.7 μm may be the key to distinguish between the two models.