Further birth records of elephant seals Mirounga leonina in New Zealand (note)

The second and third recorded births of southern elephant seals Mirounga leonina on the mainland of New Zealand occurred at Kaikoura in mid‐October 1976. One female pup died within 14 d of birth and the other (sex unknown) disappeared from the region with its mother on 19 November 1976.     

The crystal structure of waylandite from Wheal Remfry, Cornwall, United Kingdom

Sr- and Ca-rich waylandite, $ {\left( {{\hbox{B}}{{\hbox{i}}_{0.{54}}}{\hbox{S}}{{\hbox{r}}_{0.{31}}}{\hbox{C}}{{\hbox{a}}_{0.{25}}}{{\hbox{K}}_{0.0{1}}}{\hbox{B}}{{\hbox{a}}_{0.0{1}}}} \right)_{\Sigma 1.12}}{{\hbox{H}}_{0.{18}}}{\left( {{\hbox{A}}{{\hbox{l}}_{{2}.{96}}}{\hbox{C}}{{\hbox{u}}_{0.0{2}}}} \right)_{\Sigma 2.98}}{\left[ {{{\left( {{{\hbox{P}}_{0.{97}}}{{\hbox{S}}_{0.0{3}}}{\hbox{S}}{{\hbox{i}}_{0.0{1}}}} \right)}_{\Sigma 1.00}}{{\hbox{O}}_4}} \right]_2}{\left( {\hbox{OH}} \right)_6} $ , from Wheal Remfry, Cornwall, United Kingdom has been investigated by single-crystal X-ray diffraction and electron microprobe analyses. Waylandite crystallises in space group R $ \overline 3 $ ? m, with the cell parameters: a?=?7.0059(7) Å, c?=?16.3431(12) Å and V?=?694.69(11) ų. The crystal structure has been refined to R ₁?=?3.76%. Waylandite has an alunite-type structure comprised of a rhombohedral stacking of (001) composite layers of corner-shared AlO₆ octahedra and PO₄ tetrahedra, with (Bi,Sr,Ca) atoms occupying icosahedrally coordinated sites between the layers.     

Breaks and unit roots in global and hemispheric temperatures: an updated analysis

The unit root testing within a breaking trend framework for global and hemispheric temperatures of Gay-Garcia, Estrada and Sánchez Clim Chang 94:333–349, 2009 is extended in two directions: first, the extended HadCRUT3 temperature series from Brohan et al. J Geophys Res 111:D12106, 2006 are used and, second, new breaking trend estimators and unit root tests are employed, along with direct modelling of breaking trend and unit root processes for the series. Some differences to the results of Gay-Garcia et al. are found: break dates are shifted to 1976 for global and northern hemisphere temperatures and to 1964 for the southern hemisphere. Although the results are somewhat ambiguous, global and northern hemisphere temperatures are probably best modelled by unit root processes with a break in drift, while southern hemisphere temperatures follow a breaking trend process with stationary fluctuations about this trend. Irrespective of the models selected, there is little evidence of trend warming before the breaks, i.e., until the third quarter of the 20th century, and after the breaks northern hemisphere and global trend temperatures warm quicker than in the southern hemisphere, the range being between 0.01 and 0.02 °C per annum.     

Chemical studies of copper-organic complexes isolated from estuarine waters using C18 reverse-phase liquid chromatography

Dissolved organic matter (DOM) and dissolved copper-organic complexes were isolated from the estuarine waters of Narragansett Bay, RI, using reverse-phase liquid chromatography employing C₁₈ Sep-Pak cartridges (Waters Associates). The cartridges were found to have a constant retention efficiency for processing ? 1-l volumes of seawater. Fractionation of the isolated material, by sequential elution of the Sep-Pak with water: methanol mixtures of increasing organic solvent concentration, yielded a fraction of the organic matter with a specific copper activity six times greater than the overall activity for the isolated DOM. Analysis of this fraction by high performance liquid chromatography suggested that the organic components are of intermediate polarity and have appreciable aromatic character.An investigation of the protonation characteristics of the isolated complexes indicated that most of the copper is associated with a broad range of acidic sites on the DOM. Analysis by electron paramagnetic resonance spectroscopy confirmed the organic association of the isolated copper and also suggested the presence of several types of binding sites which probably involve oxygen donor ligands.Studies of the exchange of ⁶⁴Cu with these binding sites on the isolated DOM indicated that 70% of the sites undergo rapid exchange with copper in seawater while 20% of these sites did not exchange in a 24-h time period.     

Isolation of dissolved organic matter and copper-organic complexes from estuarine waters using reverse-phase liquid chromatography

Reverse-phase liquid chromatography was used for the isolation of dissolved organic matter and dissolved copper-organic complexes from the estuarine waters of Narragansett Bay, Rhode Island. The procedure isolates 10–30% of the organic matter and up to 50% of the total dissolved copper from various bay samples. Chromatograms obtained by high-performance liquid chromatography of the isolated organic matter showed qualitative differences between sampling stations progressing from the Providence River in the upper bay to the lower bay.     

The clearing of the Illawarra rainforests: problems in reconstructing Pre‐European vegetation patterns

Historical information is used in conjunction with a detailed knowledge of the environment and vegetation types of the Illawarra district to reconstruct the original extent of rainforest in the district. While most of the literature and popular opinion suggest that much of the Illawarra was covered in rainforest vegetation, historical accounts and the patterns of existing vegetation clearly indicate that the rainforests were much less extensive than this. Based on historical evidence, the present occurrence of rainforest and other vegetation and a detailed knowledge of the environmental requirements for local rainforest development, three major concentrations of rainforest have been delineated. Termed the ‘Illawarra’, ‘Yarrawa’ and ‘Berkeley’ brushes, these areas covered 12,000, 2,450 and 1,600 hectares, respectively. These brushes represented 70 per cent of the 23,000 ha of rainforest estimated to have occurred in the district before European settlement. Historical information is a valuable tool in ecological research, but a detailed knowledge of the interactions of the vegetation and environment are also required to reconstruct original vegetation patterns.     

Thrust faulting and crust—upper mantle structure in East Australia

Summary. The mid-crustal earthquake of 1973 March 9 (m_b= 5.5, h ≤ 20 km) located 60 km south-west of Sydney, Australia, provides unambiguous evidence of contemporary thrust faulting in South-eastern Australia — a region of high heat flow and Cenozoic basaltic volcanism. Aftershock locations suggest a steeply dipping fault in the depth range from 8 to 24 km with a lateral extent of about 8 km. The mechanism solution is consistent with a tectonic stress field that is dominated by east—west horizontal compression. A seismic moment of 5.7 ± 10²³± 20 per cent dyne-cm was computed from surface-wave amplitudes. Minimum values of slip and stress drop, 2 cm and 1 bar respectively, were estimated from the moment and a fault size taken' from aftershock locations.
Refinement modelling by a controlled Monte Carlo technique was used to provide unbiased models directly from multimode group velocities. The dispersion of fundamental and higher mode surface waves recorded at the digital high-gain station at Charters Towers, Queensland, and the WWSSN station at Adelaide, South Australia, is satisfied by crust- and upper-mantle models which have neither pronounced S-wave low-velocity zones nor thick high-velocity lids within 140 km of the Earth's surface. These models have subcrustal shear velocities of 4.20–4.32 km/s which are 0.4–0.5 km/s slower than Canadian shield shear velocities (CANSD).     

Scale of pluton/wall rock interaction near May Lake,Yosemite National Park,CA, USA

Interaction of magma with wall rock is an important process in igneous petrology, but the mechanisms by which interactions occur are poorly known. The western outer granodiorite of the Cretaceous Tuolumne Intrusive Suite of Yosemite National Park, California, intruded a variety of metasedimentary and igneous wall rocks at 93.1 Ma. The May Lake metamorphic screen is a metasedimentary remnant whose contact zone exhibits a variety of interaction phenomena including xenolith incorporation, disaggregation, and partial melting. The chemical contrast of these metasedimentary rocks with the invading pluton provides an excellent measure of pluton/wall rock interactions. Wall rock xenoliths (mostly pelitic quartzite) are predominantly located in an elongate horizon surrounded by a hybridized fine-grained granodiorite. Initial Sr and Nd isotopic ratios of the hybridized granodiorite indicate significant local incorporation of crustal material. Major- and trace-element geochemical data indicate that contamination of the granodiorite occurred via selective assimilation of both high-K and low-K, high-silica partial melts derived from pelitic quartzite. Although the hybridized granodiorite shows significant amounts of contamination, adjacent to xenoliths the proportion of contamination is undetectable more than a meter away. These results indicate that the chemical and isotopic variability of the Tuolumne Intrusive Suite is not caused by magma contamination via in situ wall rock assimilation.     

Using qPCR Assays to Predict Rates of Cometabolism of TCE in Aerobic Groundwater

Monitored natural attenuation (MNA) is commonly used as a remedy for trichloroethene (TCE) in anaerobic groundwater; however, MNA has not been applied to TCE contamination in aerobic groundwater. Under aerobic conditions, bacteria initiate the degradation of many organic substances with oxygenase enzymes. Several of these enzymes are known to degrade TCE through a fortuitous reaction known as cometabolism. There are commercially available qPCR assays that can determine the number of gene copies of these enzymes. If the qPCR assay could be used to predict the first-order rate constant for cometabolism of TCE, the qPCR assay could be used to screen sites to determine whether MNA was a plausible remedy for TCE contamination. This study reevaluated data from water samples that were collected from 19 wells on five sites in Minnesota, New York, and Utah. Data had previously been published on the rate constant for cometabolism of TCE in the water samples as determined by a ¹⁴C-assay and the abundance of gene copies for five enzymes that cometabolize TCE as determined using a qPCR assay. The Michaelis-Menten (Haldane) kinetic parameters for cometabolism of TCE and the abundance of DNA for the five oxygenase enzymes were used to predict the rate constant for cometabolism of TCE. The predicted rate constants were evaluated and validated by comparing them to the rate constants derived from the ¹⁴C-assay. For predicted rate constants greater than 0.003 per year, the predicted rate constants agreed with the measured rate constants within a factor of three. The qPCR assay serves as a convenient screening tool to determine whether MNA is a plausible remedy for an aerobic plume of TCE.