利用AutoPrep技术抑制型电导离子色谱法检测土壤中碘

利用AutoPrep自动样品前处理技术，对土壤燃烧吸收液进行在线预浓缩，抑制型电导进行检测，建立了一种全新思路的检测土壤样品中碘的方法。选择亲水性非常强的氢氧化物选择性IonPac AS16阴离子交换色谱柱，淋洗液发生装置在线产生KOH进行等梯度淋洗，抑制型电导检测。结果表明，对于土壤燃烧吸收液中碘离子的测定，方法检出限（S／N=3）可达1．2μg/L，线性相关系数为0．9998，方法精密度（RSD，n=7）为1．161％～4．566％，回收率在90．6％～100．8％。采用AutoPrep电导检测和脉冲安培检测离子色谱法测定不同土壤样品中的碘，两种方法的检测结果基本一致。方法在提供了稳定的系统空白的同时，还具备自动化程度高、操作简单、重现性好、灵敏度高、系统稳定、节约时间、成本低廉和对环境友好等多方面特点，适合于大批量土壤普查中碘的分析。     

Space exploration and the RAS

Mike Hapgood and Ian Crawford assess the relevance of the BNSC UKSEWG Report for the Royal Astronomical Society.     

SCAP meeting no.10

Mike Bode , Phil Charles and Carlos Frenk report the minutes of the tenth meeting of the Standing Conference of Astronomy Professors, held at the RAS, Burlington House on 30 January 2001.     

Impact of the Montreal protocol and its amendments on the rate of change of global radiative forcing

Increases in chlorinated and brominated halocarbons are believed to be responsible for the depletion of stratospheric ozone observed over much of the globe in the past decade or so. Ozone depletion is in turn believed to lead to a negative radiative forcing, tending to cool the stratosphere and the surface. We show that the increasing atmospheric concentrations of ozone-depleting halocarbons and onset of related ozone depletion likely led to a negative forcing of the climate system in the 1980s that slowed significantly the rate of change of total anthropogenic radiative forcing due to the combined effect of all greenhouse gases over that decade. Within the next decade, emissions of these halocarbons are expected to rapidly decrease, with corresponding impacts on ozone and radiative forcing. As the emissions of ozone-depleting gases are reduced and eventually phased out, the rate of ozone depletion is expected to decrease and eventually reverse. All other things being equal, we show that the change from deepening ozone depletion in the 1980s to ozone increases in the future should lead to a pronounced increase in the decadal rate of change of anthropogenic greenhouse forcing of the next few decades, perhaps to levels unprecedented in this century.     

A 1951–80 global land precipitation climatology for the evaluation of general circulation models

Previous evaluations of model precipitation fields have suffered from two weaknesses; they have used only mean observed climatologies which have prevented an explicit evaluation of interannual variability, and they have generally failed to quantify the significance of differences between model and observed fields. To rectify these weaknesses, a global precipitation climatology is required which is designed with model evaluation in mind. This paper describes such a climatology representative of the period 1951–80. The climatology is based on historical gauge-precipitation measurements from over 2500 land-based station time series representing over 28% of the Earth's surface. It is necessarily biased towards terrestrial areas. The climatology (CRU5180) is derived from month-by-month gridbox precipitation estimates at 5° resolution. Although other global precipitation climatologies exist, this is the first one to have used a consistent reference period for each station, and to include the details of interannual variability. Fields of mean seasonal and annual precipitation and mean temporal variability are presented, and the variability of global-mean precipitation over 1951–80 assessed. The resulting mean monthly global precipitation fields are compared briefly with two other observed climatologies used for model evaluation, those prepared by Jaeger and Legates and Willmott. The global and hemispheric means, mean seasonal cycles, and spatial patterns of the three cimatologies are compared. Although based on a smaller set of stations than Legates and Willmott, the CRU5180 precipitation estimates agree closely with their uncorrected climatology.     

Wave packet propagation in an amplifying medium and its application to the dispersion characteristics and to the generation mechanisms of Pc 1 events

The formulae which give the propagation characteristics of a wave packet in a dispersive and amplifying medium, are established. Application is made to the propagation of Pc 1 elements through a magnetosphere constituted of a cold plasma and a high energy proton population. It is shown that the spectral shape, in a frequency-time coordinate system, of the Pc 1 elements is related to two terms : v = d²ω/dk², which represents the variation of the group velocity with frequency and which depends only on the cold plasma characteristics, and μ = -d²γ/dk², in which γ is the amplification coefficient depending on the frequency and which is related to the high energy particle distribution function. When v ? μ, only the usual dispersion effects occur, but a new method is found for determining the line of force on which the micropulsations are generated, without making any assumption about the cold plasma density distribution inside the magnetosphere. It is also possible to deduce some characteristics about the high energy proton distribution. Theoretical computations are presented, which give the frequency variation of the amplification coefficient as a function of the e-folding energy and the anisotropy factor of these high energy protons. Applications are made to ~30 pearl events which are analysed in detail according to this theory. When μ ? v, other effects do appear. After a preliminary phase, the pearl elements can become parallel for a while, or even re-erect before lying again; the duration of each element gives an indication about the number of interacting particles. The conditions for the validity of the quasi-linear theory, and some other non-linear effects related with the interpretation of Pc 1 micropulsations are also discussed.