Chemical composition of glacial meltwaters and river waters within the Aktru river basin (Gornyi Altai)

An assessment was made of the mean levels of major and trace elements and of biogenic and organic matter in glacial and river waters within the Aktru river basin (Gornyi Altai, Russia). The analysis showed a general tendency for an increase in mineralization along the direction from the region of alimentation of glaciers to the mouth of the river. A relatively abrupt increase was revealed in Al, Zn, Cu, Pb, Si, NO₂ ^? and NH₄ ⁺ concentrations in the source of the Aktru river and its glacial tributaries, with their subsequent decrease downstream. The mechanism for such changes is governed by the conditions of interaction of rocks with meltwaters and river waters.     

Clay Minerals in Basalt Sills from the Sediment Cover,East Pacific Rise

Clay minerals in basalt sills from the northern East Pacific Rise, covered by Upper Pleistocene clayey–sandy–silty sediments (turbidites, hemipelagites, and diatom oozes) sampled from DSDP Holes 477, 478, and 481A, were studied by X-ray methods based on the modeling of diffraction patterns. Trioctahedral smectites formed in thin (0.1–0.5 and 1.8–4 m) fissured sills that are well permeable for water delivered from the water-saturated host sediments heated by the sills. Smectites in basalts are found in the interstices (20–40 vol % in the rock and up to 50–80 vol % in hyalobasalts). They replace olivine and fill cracks and vesicles. Plagioclase and clinopyroxene are generally unaltered. The structure of smectites is characterized by different height of layers depending on the composition of cations in the interlayers and the degree of their hydration. The different-height layers either make up individual smectite phases or alternate in different proportions and with a high degree of segregation in the mixed-layer structures. Under conditions of a prolonged cooling, thick (43 m) sills are distinguished from the thin varieties by the formation of trioctahedral minerals (smectite–chlorite, chlorite, defective chlorite, and talc). They are found mainly in the interstices that make up 3–7 vol % of the rock.     

High temperature calorimetry of sulfide systems

The standard enthalpies of formation of FeS (troilite), FeS₂ (pyrite), Co_0.9342S, Co₃S₄ (linnaeite), Co₉S₈ (cobalt pentlandite), CoS₂ (cattierite), CuS (covellite), and Cu₂S (chalcocite) have been determined by high temperature direct reaction calorimetry at temperatures between 700 K and 1021 K. The following results are reported: $$\Delta {\rm H}_{f,FeS}^{tr} = - 102.59 \pm 0.20kJ mol^{ - 1} ,$$ $$\Delta {\rm H}_{f,FeS}^{py} = - 171.64 \pm 0.93kJ mol^{ - 1} ,$$ $$\Delta {\rm H}_{f,Co_{0.934} S} = - 99.42 \pm 1.52kJ mol^{ - 1} ,$$ $$\Delta {\rm H}_{f,Co_9 S_8 }^{ptl} = - 885.66 \pm 16.83kJ mol^{ - 1} ,$$ $$\Delta {\rm H}_{f,Co_3 S_4 }^{In} = - 347.47 \pm 7.27kJ mol^{ - 1} ,$$ $$\Delta {\rm H}_{f,CoS_2 }^{ct} = - 150.94 \pm 4.85kJ mol^{ - 1} ,$$ $$\Delta {\rm H}_{f,Cu_2 S}^{cc} = - 80.21 \pm 1.51kJ mol^{ - 1} ,$$ and $$\Delta {\rm H}_{f,CuS}^{cv} = - 53.14 \pm 2.28kJ mol^{ - 1} ,$$ The enthalpy of formation of CuFeS₂ (chalcopyrite) from (CuS+FeS) and from (Cu+FeS₂) was determined by solution calorimetry in a liquid Ni_0.60S_0.40 melt at 1100 K. The results of these measurements were combined with the standard enthalpies of formation of CuS, FeS, and FeS₂, to calculate the standard enthalpy of formation of CuFeS₂. We found \(\Delta {\rm H}_{f,CuFeS_2 }^{ccp} = - 194.93 \pm 4.84kJ mol^{ - 1}\) . Our results are compared with earlier data given in the literature; generally the agreement is good and our values agree with previous estimates within the uncertainties present in both.     

Physical Libration of the Moon: An Extended Problem

Astronomy Reports - The work is devoted to the study of the physical libration of the Moon. Interest in the traditional topic related to the rotation of the Moon is stirred up by the activity of...     

Convection Regime of the Development of an Impulse–Buoyant Transient Jet Submerged in a Homogeneous Fluid

An intergral model of a transient vertical impulse–buoyant jet is suggested. The model contains a universal equation describing the propagation of the upper boundary of the convection front depending on the strength of the point source of buoyancy and momentum. The convective regime of jet propagation is considered, which includes a class of self-similar solutions corresponding to the buoyancy sources, whose strength varies with time following power and exponential laws. The obtained numerical solutions are compared with available experimental data on the profiles of vertical velocity and buoyancy on the jet axis.     

О ВЗАИМОДЕЙСТВИИ МЕЖДУ ВЫСОТНЫМИ АТМОСФЕРНЫМИ ВИХРЯМИ И НАЗЕМНЫМ ТЕЧЕНИЕМ

Summary It is shown that non-divergent vortices may induce, as a result of the resonance effect, a rapid surface development.     

Shock Wave Effects from the Impacts of Cosmic Objects with Diameters from 20 m to 3 km

Izvestiya, Physics of the Solid Earth - Abstract—Destruction on the Earth’s surface caused by a shock wave is one of the most important and dangerous effects from asteroid and comet...     

Detailed mineralogical-geochemical study of a large spinel Lherzolite xenolith in alkali basalt of Shavaryn Tsaram paleovolcano,Mongolia

Mineralogical-geochemical data obtained on a large xenolith of spinel lherzolite from basanites of Shavaryn Tsaram volcano (Middle Pleistocene) provide evidence that the xenolith was affected by heat and fluid that came from the basalt melt and induced geochemical heterogeneity of the xenolith. Olivine crystals from the central portion of the xenolith contain much more CaO than this mineral from the peripheral zones of the xenolith as well as in xenocrystals of the host basalts. The large xenolith was unevenly annealed by the host basalt melt, and this predetermined the heterogeneous diffusion-controlled “purification” of olivine crystals from their CaO admixture. The xenolith is heterogeneously enriched in LREE and some trace elements (Zr, Hf, Nb, Th, and U), and their distribution demonstrates unclearly pronounced concentric zoning: these elements enriched the outer portions of the xenolith. The enrichment of the xenolith in LREE and other mobile trace elements is explained by their occurrence not only as structurally bound (isomorphic) components in minerals but also in the form of nonstructural admixtures (contaminant), as minute grains of compounds hosted in the interstitial space and tiny cracks cutting mineral grains. The enrichment of the xenolith in these admixtures proceeded via their infiltration-controlled introduction with fluid from the basalt along minute cracks.