The short term climatic sensitivity of carbonate and silicate weathering fluxes: Insight from seasonal variations in river chemistry

Large seasonal variations in the dissolved load of the headwater tributaries of the Marsyandi river (Nepal Himalaya) for major cations and ⁸⁷Sr/⁸⁶Sr ratios are interpreted to result from a greater dissolution of carbonate relative to silicate at high runoff. There is up to a 0.003 decrease in strontium isotope ratios and a factor of 3 reduction in the Si(OH)₄/Ca ratio during the monsoon. These variations, in small rivers sampling uniform lithologies, result from a different response of carbonate and silicate mineral dissolution to climatic forcing. Similar trends are observed in compiled literature data, from both Indian and Nepalese Himalayan rivers. Carbonate weathering is more sensitive to monsoonal runoff because of its faster dissolution kinetics. Silicate weathering increases relative to carbonate during the dry season, and may be more predominant in groundwater with longer water-rock interaction times. Despite this kinetic effect, silicate weathering fluxes are dominated by the monsoon flux, when between 50% and 70% of total annual silicate weathering flux occurs.     

Year 11 geography teachers' response to the Darfield earthquake

When events such as the Darfield earthquake take place, it is assumed that the response from the geography teaching community provides the opportunity to reinforce the relevance of geography. This article reports the findings of a questionnaire which seeks to explore the question, ‘What were the characteristics of the learning and teaching of Year 11 Geography teachers in the weeks following the Darfield earthquake, September 4, 2010?’ The data offer empirical support for the agency of geography teachers' impressing the relevance of the subject to school students in response to an extreme natural event under New Zealand's collective backyard.     

Stardust interstellar dust calibration: Hydrocode modeling of impacts on Al‐1100 foil at velocities up to 300 km s−1 and validation with experimental data

Abstract– We present initial results from hydrocode modeling of impacts on Al‐1100 foils, undertaken to aid the interstellar preliminary examination (ISPE) phase for the NASA Stardust mission interstellar dust collector tray. We used Ansys’ AUTODYN to model impacts of micrometer‐scale, and smaller projectiles onto Stardust foil (100 μm thick Al‐1100) at velocities up to 300 km s^?1. It is thought that impacts onto the interstellar dust collector foils may have been made by a combination of interstellar dust particles (ISP), interplanetary dust particles (IDP) on comet, and asteroid derived orbits, β micrometeoroids, nanometer dust in the solar wind, and spacecraft derived secondary ejecta. The characteristic velocity of the potential impactors thus ranges from <<1 to a few km s^?1 (secondary ejecta), approximately 4–25 km s^?1 for ISP and IDP, up to hundreds of km s^?1 for the nanoscale dust reported by Meyer‐Vernet et al. (2009) . There are currently no extensive experimental calibrations for the higher velocity conditions, and the main focus of this work was therefore to use hydrocode models to investigate the morphometry of impact craters, as a means to determine an approximate impactor speed, and thus origin. The model was validated against existing experimental data for impact speeds up to approximately 30 km s^?1 for particles ranging in density from 2.4 kg m^?3 (glass) to 7.8 kg m^?3 (iron). Interpolation equations are given to predict the crater depth and diameter for a solid impactor with any diameter between 100 nm and 4 μm and density between 2.4 and 7.8 kg m^?3.     

Determination of shale stiffness tensor from standard logs

A technique allowing inversion of the shale stiffness tensor from standard logging data: sonic velocities, density, porosity and clay content is developed. The inversion is based on the effective medium theory. The testing of the technique on laboratory measurements of the elastic wave velocities in shale samples shows that the inversion makes it possible to predict the elastic wave velocities V_P, V_S1 and V_S2 in any direction within an error of a few per cent. The technique has been applied for the stiffness tensor inversion along a well penetrating a shale formation of the Mississippian age altered by thin layers of limestone. It is demonstrated that the symmetry of a stiffness tensor inverted at the sonic frequency (2 kHz) is slightly orthorhombic and taking into account the experimental errors, can be related to the vertical transverse isotropy symmetry. For the productive interval of the shale formation, the Thomsen parameters ?, γ, and δ average, respectively, 0.32, 0.25 and 0.21, which indicate anelliptic behaviour of the velocities in this shale. The coefficients of anisotropy of this shale interval are around 24% and 20% for the compressional and shear waves, respectively. The values of the inverted velocities in the bedding plane for this interval are in good agreement with the laboratory measurements. The technique also allows inversion of the water saturation of the formation (Sw) and the inverted values are in agreement with the Sw values available for this formation. A Backus‐like upscaling of the inverted stiffness tensors is carried out for the lower and upper bounds of the frequency band used in the crosswell tomography (100 Hz and 500 Hz). These results can serve as an initial velocity model for the microearthquake location during hydrofracking of the shale formation.     

The prelude of the end-Permian mass extinction predates a postulated bolide impact

The mass extinction at the Permian–Triassic Boundary (PTB) is said to have been abrupt and probably caused by an extraterrestrial impact. However, evidence from the Global Stratotype Section and Point (GSSP) of the base of the Induan at Meishan, China, shows that the biotic crisis began prior to the level, in beds 25 and 26 at which the postulated impact event occurred. Evidence of such an earlier biotic crisis occurs in other sections in South China, and in central and western Tethyan regions. This event is characterized by the extinction of a range of faunas, including corals, deep-water radiolarians, most fusulinids and pseudotirolitid ammonoids, and many Permian brachiopods. In all sections, this extinction level is usually a few decimeters to meters below that of the main mass extinction in the event beds (25 and 26) at Meishan, and their correlatives elsewhere. This earlier extinction event happened before the postulated bolide impact at the level of beds 25 and 26, and constrains interpretation of the mechanisms that brought about this greatest mass extinction. Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.     

Gully erosion in Mangatu Forest,New Zealand,estimated from digital elevation models

The methodology and errors involved in determining the amount of sediment produced during two (19·5 and 33·2 year) periods by 11 (c. 0·01 − >0·20 km²) gullies within a 4 km² area in the headwaters of the Waipaoa River basin, New Zealand, using sequential digital elevation models are described. Sediment production from all gullies within the study area was 0·99 ± 0·03 × 10⁶ t a⁻¹ (2480 ± 80 t ha⁻¹ a⁻¹) during the period from 1939 to 1958. It declined to 0·62 ± 0·02 × 10⁶ t a⁻¹ (1550 ± 50 t ha⁻¹ a⁻¹) during the period from 1958 to 1992, when many of the smaller gullies were stabilized by a programme of afforestation, which commenced in 1960. Both figures are very high by global standards. The two largest (the Tarndale and Mangatu) gully complexes together generated 73 and 95 per cent of the sediment in the specified time periods, but the latter amount is equivalent to only c. 5 per cent of the total annual sediment load of the Waipaoa River. © 1998 John Wiley & Sons, Ltd.     

Some analyses and numerical simulations of meiyu in east asia in 1983

In this paper the differences between Meiyu and Baiu front in 1983 have firstly been analysed, the trajectories of air on and to the north side of Meiyu and Baiu fronts during the Meiyu period have then been traced, and the fore-casting and simulating of 4 sets of Meiyu onset of the year have finally been run utilizing the global model at UK Me-teorological Office. The results show: 1) Meiyu fronts are different from Baiu ones in temperature, humidity and stratification fields in lower atmosphere; and the possibly reasons for it are explained. 2) The Bay of Bengal is the main moisture source for Meiyu front, the South China Sea and the Pacific, for Baiu ones; and some existed argu-ments on it are also discussed. 3) The onset of Meiyu and its rainfall and rain belts are sensitive to the Tibetan Plateau, and the water vapour conditions over the Bay of Bengal and the South China Sea, but not sensitive to the SST over the equatorial area or to the East of Japan.     

The influence of basement faults on local extension directions: Insights from potential field geophysics and field observations

Complex arrays of faults in extensional basins are potentially influenced by pre‐existing zones of weakness in the underlying basement, such as faults, shear zones, foliation, and terrane boundaries. Separating the influence of such basement heterogeneities from far‐field tectonics proves to be challenging, especially when the timing and character of deformation cannot be interpreted from seismic reflection data. Here we aim to determine the influence of basement heterogeneities on fault patterns in overlying cover rocks using interpretations of potential field geophysical data and outcrop‐scale observations. We mapped >1 km to meter scale fractures in the western onshore Gippsland Basin of southeast Australia and its underlying basement. Overprinting relationships between fractures and mafic intrusions are used to determine the sequence of faulting and reactivation, beginning with initial Early Cretaceous rifting. Our interpretations are constrained by a new Early Cretaceous U‐Pb zircon isotope dilution thermal ionization mass spectrometry age (116.04 ± 0.15 Ma) for an outcropping subvertical, NNW‐SSE striking dolerite dike hosted in Lower Cretaceous Strzelecki Group sandstone. NW‐SE to NNW‐SSE striking dikes may have signaled the onset of Early Cretaceous rifting along the East Gondwana margin at ca. 105–100 Ma. Our results show that rift faults can be oblique to their expected orientation when pre‐existing basement heterogeneities are present, and they are orthogonal to the extension direction where basement structures are less influential or absent. NE‐SW to ENE‐WSW trending Early Cretaceous rift‐related normal faults traced on unmanned aerial vehicle orthophotos and digital aerial images of outcrops are strongly oblique to the inferred Early Cretaceous N‐S to NNE‐SSW regional extension direction. However, previously mapped rift‐related faults in the offshore Gippsland Basin (to the east of the study area) trend E‐W to WNW‐ESE, consistent with the inferred regional extension direction. This discrepancy is attributed to the influence of NNE‐SSW trending basement faults underneath the onshore part of the basin, which caused local re‐orientation of the Early Cretaceous far‐field stress above the basement during rifting. Two possible mechanisms for inheritance are discussed—reactivation of pre‐existing basement faults or local re‐orientation of extension vectors. Multiple stages of extension with rotated extension vectors are not required to achieve non‐parallel fault sets observed at the rift basin scale. Our findings demonstrate the importance of (1) using integrated, multi‐scale datasets to map faults and (2) mapping basement geology when investigating the structural evolution of an overlying sedimentary basin.     

Graphite oxidation in the Apollo 17 orange glass magma: Implications for the generation of a lunar volcanic gas phase

An Apollo 17 picritic orange glass composition has been used to experimentally investigate the conditions at which graphite would oxidize to form a CO-rich gas, and ultimately produce lunar fire-fountain eruptions. Isothermal decompression experiments run above the A17 orange glass liquidus temperature (>1350 °C) suggest that the initial CO-rich gas phase produced by graphite oxidation would be generated during magma ascent at a pressure of 40 MPa, 8.5 km beneath the lunar surface. Additional experiments with 2000 ppm S and 1000 ppm Cl showed that the presence of these dissolved gas species would not affect the depth of graphite oxidation, verifying that the first volcanic gas phase would be generated by the oxidation of graphite.A simple ideal chemical mixing model for calculating melt FeO activity in a Fe-metal/silicate melt system was tested with a series of 0.1 MPa controlled oxygen fugacity experiments. Agreement between the model and experiments allows the model to be used to calculate oxygen fugacity in picritic lunar glass compositions such as the A17 orange glass. Using this model in a reanalysis of chemical equilibria between the natural A17 orange glass melt and the metal spherules (Fe₈₅Ni₁₄Co₁) trapped within the glass beads indicates a log oxygen fugacity of −11.2, 0.7 log units, more oxidized than previous estimates. At the A17 orange glass liquidus temperature (1350 ± 5 °C), this f_O2 corresponds to a minimum pressure of 41 MPa on the graphite–C–O surface. The fact that the same critical graphite oxidation pressure was determined in decompression experiments and from the Fe–FeO activity model for the natural A17 orange glass–metal assemblage strongly supports this pressure (8.5 km depth) for volcanic gas formation in lunar basalts. Generation of a gas by oxidation of C in ascending magma is likely to have been important in getting dense lunar magmas to the surface as well as in generating fire-fountain eruptions. The vesicles common in many lunar basalts and the ubiquitous Fe-metal in these rocks are also likely generated by the oxidation of carbon. The presence of carbon in the lunar basalts and the recent discovery of ppm levels of water in lunar basalts indicate that at least parts of the lunar interior still contained volatiles at 3.9 bybp.     

Ethnohistoric and Geoarchaeological Landscape Chronology at Kawaihae,Leeward Hawai‘i Island

The royal court of the Kamehameha Dynasty in Kawaihae, Hawai‘i Island, presents an unequalled opportunity to examine the ethnohistoric rendering of a cultural landscape, in comparison to the geoarchaeological record of physical transformation of this same landscape. Beneath the surface, earlier occupation layers predate the historic royal precinct of the A.D. 1790s through 1820s. Drawing on results of 19 controlled excavations, point‐specific cultural activities are situated within the last several centuries of natural terrain formation, beginning A.D. 1200–1400 and ending A.D. 1830–present. Geoarchaeological excavations provide the means to place the stratified cultural deposits, occupational horizons, and activity areas in the context of depositional history, environmental transformation, and changing social circumstances in a continuous sequence. The material‐based geoarchaeological landscape chronology and the ethnohistorically defined cultural landscape are combined for a more holistic view than either one could provide independently.