Neoarchean suprasubduction zone arc magmatism in southern India: Geochemistry,zircon U-Pb geochronology and Hf isotopes of the Sittampundi Anorthosite Complex

The Sittampundi Anorthosite Complex (SAC) in southern India is one of the well exposed Archean layered anorthosite-gabbro-ultramafic rock associations. Here we present high precision geochemical data for the various units of SAC, coupled with zircon U-Pb geochronology and Hf isotopic data for the anorthosite. The zircon ages define two populations, the older yield a concordia age of 2541 ± 13 Ma, which is interpreted as the best estimate of the magmatic crystallization age for the Sittampundi anorthosite. A high-grade metamorphic event at 2461 ± 15 Ma is suggested by the upper intercept age of the younger zircon population. A Neoproterozoic event at 715 ± 180 Ma resulted in Pb loss from some of the metamorphic zircons. The magmatic age of the anorthosite correlates well with the timing of crystallization of the arc-related ~ 2530 Ma magmatic charnockites in the adjacent Salem Block, while the metamorphic age is synchronous with the regional metamorphic event. The geochemical data suggest that the rocks were derived from a depleted mantle source. Sub-arc mantle metasomatism of slab derived fluids and subsequent partial melting produced hydrous, aluminous basalt magma. The magma fractionated at depth to produce a variety of high-alumina basalt compositions, from which the anorthositic complex with its chromite-rich and amphibole-rich layers formed as cumulates within the magma chamber of a supra-subduction zone arc. The coherent initial¹⁷⁶Hf/¹⁷⁷Hf ratios and positive εHf values (1.7 – 4.5) of the magmatic zircons in the anorthosite are consistent with derivation of a rather homogeneous juvenile parent magma from a depleted mantle source. Our study further confirms that the southern part of the Dharwar Craton was an active convergent margin during the Neoarchean with the generation and emplacement of suprasubduction zone arc magmas which played a significant role in continental growth.     

Geostatistical characterization of soil moisture and chloride distribution in deep vadose profiles of the Badain Jaran Desert,Northwestern China

Geostatistical analysis of soil moisture and ion accumulation can provide a deep understanding of aspects of a region’s hydrology such as recharge rates and flow paths. By combining this approach with detrended canonical correspondence analysis, the present study investigated the vertical and spatial variation of soil moisture and chloride (Cl^?) in vadose profiles of megadunes near lakes in the southeastern Badain Jaran Desert, northwestern China. Soil moisture varied vertically within the dune profiles following exponential, logarithmic, or log-normal distributions at different sites as a result of regulation by different local controls. The main local controls for Cl^? concentration were slope and orientation of the dune. Cl^? was not affected by local controls at depths >5 m. Sills of spatial variation in soil moisture and Cl^? in the variogram analysis were highly sensitive to local controls in the top 4 m of the profiles, and the values were three times those at depths >4 m. The lag for soil moisture was insensitive to local controls, and was 50–60 m in the top 4 m of the profiles and 20 m in deeper layers, whereas the lag for Cl^? was about 20 m at all depths. The results demonstrate that understanding recharge rates using factors such as Cl^? accumulation requires a careful survey to ensure that the local controls that regulate these factors are adequately accounted for.     

Resolution studies for Magnetic Resonance Sounding (MRS) using the singular value decomposition

We present a new approach to analyse the subsurface water content distribution obtained by inversion of MRS data in terms of resolution and penetration depth. It is based on a singular value decomposition (SVD) of the MRS forward operator to derive the model resolution matrix including regularisation parameters, i.e. including noise conditions. The approach takes loop size, subsurface resistivity distribution and noise conditions as input parameters affecting MRS into account and allows an assessment on resolution and penetration.The application of the new approach shows that the loop diameter must be carefully chosen depending on the investigation site to obtain optimal resolution and penetration. Using the introduced resolution measures the quality and reliability of the estimated model can be assessed.     

Petrogenesis and tectonic setting of bimodal volcanism in the Sakoli Mobile Belt, Central Indian shield

The Sakoli Mobile Belt comprises bimodal volcanic rocks that include metabasalt, rhyolite, tuffs, and epiclastic rocks with metapelites, quartzite, arkose, conglomerate, and banded iron formation (BIF). Mafic volcanic rocks are tholeiitic to quartz‐tholeiitic with normative quartz and hypersthene. SiO₂ shows a large compositional gap between the basic and acidic volcanics, depicting their bimodal nature. Both the volcanics have distinct geochemical trends but display some similarity in terms of enriched light rare earth element–large ion lithophile element characteristics with positive anomalies for U, Pb, and Th and distinct negative anomalies for Nb, P, and Ti. These characteristics are typical of continental rift volcanism. Both the volcanic rocks show strong negative Sr and Eu anomalies indicating fractionation of plagioclases and K‐feldspars, respectively. The high Fe/Mg ratios for the basic rocks indicate their evolved nature. Whole rock Sm–Nd isochrons for the acidic volcanic rocks indicate an age of crystallization for these volcanic rocks at about 1675 ± 180 Ma (initial ¹⁴³Nd/¹⁴⁴Nd = 0.51017 ± 0.00017, mean square weighted deviate [MSWD] = 1.6). The εNd_t (t = 2000 Ma) varies between ?0.19 and +2.22 for the basic volcanic rock and between ?2.85 and ?4.29 for the acidic volcanic rocks. Depleted mantle model ages vary from 2000 to 2275 Ma for the basic and from 2426 to 2777 Ma for the acidic volcanic rocks, respectively. These model ages indicate that protoliths for the acidic volcanic rocks probably had a much longer crustal residence time. Predominantly basaltic magma erupted during the deposition of the Dhabetekri Formation and part of it pooled at crustal or shallower subcrustal levels that probably triggered partial melting to generate the acidic magma. The influence of basic magma on the genesis of acidic magma is indicated by the higher Ni and Cr abundance at the observed silica levels of the acidic magma. A subsequent pulse of basic magma, which became crustally contaminated, erupted as minor component along with the dominantly acidic volcanics during the deposition of the Bhiwapur Formation.     

Data reporting norms for 40Ar/39Ar geochronology

Data reported in ⁴⁰Ar/³⁹Ar geochronology studies are commonly insufficient to allow computation of ages. This deficiency renders it difficult to compare ages based on different standards or constants, and often hinders critical evaluation of the results. Herein are presented an enumeration of the data that should be reported in all ⁴⁰Ar/³⁹Ar studies, including a discussion in support of these requirements. The minimum required data are identified and distinguished from parameters that are useful but may be derived from them by calculation. Finally, recommendations are made for metadata needed to document age calculations (e.g., from age spectrum or isochron analyses).     

Age and nature of eclogites in the Huwan shear zone,and the multi-stage evolution of the Qinling-Dabie-Sulu orogen,central China

In situ LA-ICPMS U-Pb, trace element, and Hf isotope data in zircon demonstrate a Carboniferous age for eclogite-facies metamorphism in Siluro-Devonian protoliths in the Huwan shear zone, Dabie Mountains, Central China. This age contrasts with the more prevailing Triassic age for high- to ultrahigh pressure (HP to UHP) metamorphism in the Qinling-Dabie-Sulu orogen. Metamorphic zircon in two eclogite samples from Sujiahe is characterized by low Th/U ratios, small negative Eu anomalies, flat HREE patterns, and low ¹⁷⁶Lu/¹⁷⁷Hf ratios. These geochemical signatures suggest that the zircon crystallized in the presence of garnet and in the absence of plagioclase feldspar. Furthermore, temperatures of ~ 655 and ~ 638 °C, calculated using the Ti content of zircon, are consistent with their formation during eclogite-facies metamorphism. The weighted mean ²⁰⁶Pb/²³⁸U age of 309 ± 4 Ma (2δ) for this zircon improves previous age estimates for eclogite-facies metamorphism in the Huwan shear zone, ranging from 420 to 220 Ma. Metamorphic zircon from one eclogite sample from Hujiawan, most likely formed during prograde metamorphism, yields an equivalent age estimate of 312 ± 11 Ma. Magmatic zircon cores in the three samples yield ages for the magmatic protoliths of the eclogites ranging from 420 ± 7 to 406 ± 5 Ma, and post-dating the middle Paleozoic collision of the North China and the Qinling terrain. The zircon crystals in the three eclogite samples display a large variation of ε_Hf (t) values of ? 4.9 to 21.3. The metamorphic zircon overgrowths show the same range of ε_Hf (t) values as those of the inherited magmatic crystal interiors. This suggests that the metamorphic zircon overgrowths may have formed by dissolution-reprecipitation of pre-existing magmatic zircon thereby preserving their original Hf isotopic composition. The high ε_Hf (t) values suggest that the protoliths were derived from depleted mantle sources, most likely Paleotethyan oceanic crust; while the low ε_Hf (t) values are attributed to crustal contamination. Some eclogites in the Huwan shear zone have a distinctive signature of continental crust most probably derived from the Yangtze Craton. The coexistence of Paleozoic oceanic crust and Neoproterozoic continental crust with similar metamorphic ages in the Huwan shear zone implies that Paleozoic Paleotethyan oceanic crust was produced within a marginal basin of the northern Yangtze Craton. The opening of the Paleo-Tethyan ocean was slightly younger than the collision of the North China Craton and the Qinling terrain during the Late Paleozoic in the Qinling-Dabie-Sulu orogen. Subduction of the Paleo-Tethyan oceanic crust and associated continental basement resulted in the 309 ± 2 Ma (2σ) eclogite-facies metamorphism in the Huwan shear zone. The subsequent Triassic continent-continent collision led to the final coalescence of the Yangtze and Sino-Korean cratons. Amalgamation of the Yangtze and North China cratons was, therefore, a multistage process extending over at least 200 Ma.     

Biological and Molecular Geochemical Evidence for Dinoflagellate Ancestors in the Upper Sinian-Cambrian

Dinoflagellates are single celled organisms that reflect the ecological conditions in modern oceans and lakes. Their earliest undisputed fossil record suggests that dinoflagellates originated from the Middle Triassic (c. 240 Ma ago). However, the presence of molecular biomarkers (dinosterane, 4α-methyl-24-ethylcholestane and tria-romatic dinosteroids) in rock extracts and coccoid dinoflagellate fossils from the upper Sinian to Cambrian of the Tarim basin confirms the hypothesis that dinoflagellates have an ancient origin, and predate the oldest undisputed dinoflagellate fossils at least by 300 Ma, as early as the late Sinian-Cambrian.     

Participatory diagramming: deploying qualitative methods through an action research epistemology

Summary In the context of a pilot study on the role that gender relations play in the transmission of HIV in Zimbabwe, this paper explores participatory diagramming, an exciting qualitative research technique largely under-utilized by geographers. It argues for a deployment of the technique within an action research epistemology in order that it might facilitate the reflection and action of participants in praxis, not simply the production of nuanced multiple truths in text Such an approach offers geographers embedded in an audit-oriented academy one means to political engagement while at the same time generating rigorous, 'publishable outputs'.     

Predicted changes in fire weather suggest increases in lightning fire initiation and future area burned in the mixedwood boreal forest

Forecasting future fire activity as a function of climate change is a step towards understanding the future state of the western mixedwood boreal ecosystem. We developed five annual weather indices based on the Daily Severity Rating (DSR) of the Canadian Forest Fire Weather Index System and estimated their relationship with annual, empirical counts of lightning fire initiation for 588 landscapes in the mixedwood boreal forest in central-eastern Alberta, Canada from data collected between 1983 and 2001 using zero-inflated negative binomial regression models. Two indices contributed to a parsimonious model of initiation; these were Seasonal Severity Rating (SSR), and DSR-sequence count. We used parameter estimates from this model to predict lightning fire initiation under weather conditions predicted in 1 × CO₂ (1975–1985), 2 × CO₂ (2040–2049) and 3 × CO₂ (2080–2089) conditions simulated by the Canadian Regional Climate Model (CRCM). We combined predicted initiation rates for these conditions with existing empirical estimates of the number of fire initiations that grow to be large fires (fire escapes) and the fire size distribution for the region, to predict the annual area burned by lightning-caused fires in each of the three climate conditions. We illustrated a 1.5-fold and 1.8-fold increase of lightning fire initiation by 2040–2049 and 2080–2089 relative to 1975–1985 conditions due to changes in fire weather predicted by the CRCM; these increases were calculated independent of changes in lightning activity. Our simulations suggested that weather-mediated increases in initiation frequency could correspond to a substantial increase in future area burned with 1.9-fold and 2.6-fold increases in area burned in 2040–2049 and 2080–2089 relative to 1975–1985 conditions, respectively. We did not include any biotic effects in these estimates, though future patterns of initiation and fire growth will be regulated not only by weather, but also by vegetation and fire management.