Evolution of hillslope soils: The geomorphic theater and the geochemical play

How and how fast do hillslope soils form as the landscape’s morphology changes over time? Here results are shown from an ongoing study that simultaneously examines the morphologic and geochemical evolution of soil mantled hillslopes that have been exposed to distinctively different denudation history. In Northern Sierra Nevada, California, the authors are investigating a tributary basin to the Middle Fork Feather River. A major incision signal from the river is well marked in a knickpoint within the tributary basin which stretches from its mouth to the Feather River at an elevation of ～700 m to the plateau at an elevation of ～1500 m. Hillslopes are significantly steeper below the knickpoint. The area’s total denudation rates are currently being constrained using cosmogenic radio nuclides, but a previous study suggested an order of magnitude difference in total denudation rates below and above the knickpoint. When compared with topographic attributes calculated from LIDAR data, physical erosion rates can be modeled as a linear function of ridge top curvature. Surprisingly, over the wide range of total denudation rates, soil thicknesses do not vary significantly until a threshold point where soil mantled landscapes abruptly shift to bedrock dominated landscapes. Bioturbation by tree falls appear to buffer soil thickness over the wide range of physical soil erosion rates. From three hillslopes with different physical erosion rates, the concentrations of Zr, which were considered conserved during dissolution and leaching, were determined and used as a proxy for the degree of mass losses via chemical denudation. There is a general trend that colluvial soils along the hillslopes with lower physical erosion rates are enriched in fine size fractions, Zr, and pedogenic crystalline Fe oxides. Likewise, the saprolites show greater degrees of chemical denudation at the sites above the knickpoint, presumably because of the saprolites’ longer turnover time in the slowly eroding landscapes. In the two steep hillslopes below the knickpoint, no significant or systematic topgraphic trends were found for soil geochemistry. However, soils show increasing Zr enrichment in the downslope direction in the hillslope above the knickpoint, which suggests a critical denudation rate beyond which soils’ turnover time is too short to develop a geochemical catena. As detailed CRN-based soil production rates and catchment scale denudation rates are acquired, the data will be combined with a mass balance model to calculate the rates of chemical denudation and weathering in soils and saprolites along the denudation gradient.     

Theory and Experiment on an Elastically Moored Cylindrical Buoy

In this paper, we compare simulated forces and accelerations for a moored floating buoy with full-scale experimental results in real ocean waves. The buoy is moored with a wire connected by springs to a concrete foundation situated at the seafloor. This study aims to develop a computer model using potential theory with a linearized free-surface boundary condition to describe the motion of such a system. The intention is to use the model for future study of wave-energy absorption and design of converters. Another objective is to see how complex a model is required to get accurate results. The method used is computationally fast and makes it possible to couple linear buoy wave interaction with nonlinear generator models, so that different loads and latching can be studied. A computationally fast method is required to model farms of wave-energy converters     

Geochemical mapping using stream sediments in west-central Nigeria: Implications for environmental studies and mineral exploration in West Africa

This paper provides an overview of regional geochemical mapping using stream sediments from central and south-western Nigeria. A total of 1569 stream sediment samples were collected and 54 major and trace elements determined by ICP-MS and Au, Pd and Pt by fire assay. Multivariate statistical techniques (e.g., correlation analysis and principal factor analysis) were used to explore the data, following appropriate data transformation, to understand the data structure, investigate underlying processes controlling spatial geochemical variability and identify element associations. Major geochemical variations are controlled by source geology and provenance, as well as chemical weathering and winnowing processes, more subtle variations are a result of land use and contamination from anthropogenic activity.     

Impact of climate on landscape form,sediment transfer and the sedimentary record

The relationship between climate, landscape connectivity and sediment export from mountain ranges is key to understanding the propagation of erosion signals downstream into sedimentary basins. We explore the role of connectivity in modulating the composition of sediment exported from the Frontal Cordillera of the south-central Argentine Andes by comparing three adjacent and apparently similar semi-glaciated catchment-fan systems within the context of an along-strike precipitation gradient. We first identify that the bedrock exposed in the upper, previously glaciated reaches of the cordillera is under-represented in the lithological composition of gravels on each of three alluvial fans. There is little evidence for abrasion or preferential weathering of sediment sourced from the upper cordillera, suggesting that the observed bias can only be explained by sediment storage in these glacially widened and flattened valleys of the upper cordillera (as revealed by channel steepness mapping). A detailed analysis of the morphology of sedimentary deposits within the catchments reveals catchment-wide trends in either main valley incision or aggradation, linked to differences in hillslope–channel connectivity and precipitation. We observe that drier catchments have poor hillslope–channel connectivity and that gravels exported from dry catchments have a lithological composition depleted in clasts sourced from the upper cordillera. Conversely, the catchment with the highest maximum precipitation rate exhibits a high degree of connectivity between its sediment sources and the main river network, leading to the export of a greater proportion of upper cordillera gravel as well as a greater volume of sand. Finally, given a clear spatial correlation between the resistance of bedrock to erosion, mountain range elevation and its covariant, precipitation, we highlight how connectivity in these semi-glaciated landscapes can be preconditioned by the spatial distribution of bedrock lithology. These findings give insight into the extent to which sedimentary archives record source erosion patterns through time.     

Displaced-Beam Small Aperture Scintillometer Test. Part I: The Wintex Data-Set

The friction velocity (u_*) and the sensible heat flux density (H) determined with a displaced-beam small aperture scintillometer (DBSAS) and a hot-film eddy correlation system are compared. Random errors in the DBSAS are relatively small, compared to scatter found with two eddy-correlation systems. Assuming that the hot-film system yields the true fluxes, theDBSAS appears to overestimate u_* when u_* is less than 0.2 m s^-1 and to underestimate u_* at high wind speeds. This implies that the DBSAS measurements of theinner scale length of turbulence, l₀, a direct measure for the dissipation rate of kinetic turbulent energy, are biased. Possible causes for these results are discussedin detail. A correction procedure is presented to account for effects of random noise and of so-called inactive turbulence or sensor vibrations. The errors in u_* cause errors in the DBSAS measurements of the structure parameter of temperature C_T ². The derived H appears to be less sensitive to errors in l₀ and C_T ², because errors in these quantities tend to cancel out.     

Comparison of UV and IR Laser Ablation ICP-MS on Silicate Reference Materials and Implementation of Normalisation Factors for Quantitative Measurements

Direct analysis of geological reference materials was performed by LA-ICP-MS using two Nd:YAG laser systems operating at 266 nm and 1064 nm. The aim of this work was to compare UV and IR laser ablation and to assess the potential of the technique for the quantitative bulk analysis of rocks, sediments and soils. The laser sampling process was investigated and the analytical performance of both systems was compared. The influence of the laser operating conditions and the nature of the matrix on ICP-MS response factors calculated for major, minor and trace elements was evaluated. Under consistent laser settings, the response factors appeared to be matrix dependent. For a given matrix, the response factors were also significantly different for the two lasers. Normalisation with a single matrix element was effective only for matrices with similar mineralogy. When operating at 266 nm instead of 1064 nm, matrix effects could be reduced but not overcome. However, variations of the response factors between the different matrices appeared to be similar within distinct groups of elements, reflecting geochemical associations. When using multiple internal standards, matrix effects but also effects of the laser wavelength, could be fully compensated.     

Duration of soil cadmium and lead pollution from shale-based alum production

The scope of this study is to assess the present impact from an historical emission source, in order to provide information on the duration of this metal pollution problem.The present distribution of cadmium and lead, emitted from a Swedish alumworks between 1726–1840, was studied in soils, sediments and ground water. The soil data imply that cadmium has disappeared from the surface soils during the 150 to 250 years that have passed since the emissions ceased. Lead concentrations of the soil are elevated only within 200 m from the site of the works. Further away, the lead concentrations are almost at background level. A possible explanation for this pattern, is that lead dispersed in large particles has not yet fully disintegrated and leached down the soil profile, in contrast to the smaller particles deposited further away.The metal concentrations in the ground water wells are slightly higher than the Swedish average but probably governed by the pH of the water, rather than the occurrence of large amounts of metals. Elevated lead concentrations were found in a few sediment samples in the river mouth downstream from the works. These elevated concentrations coincided with the abundant occurrence of small particles of used shale, indicating their origin.Cadmium is not found, at present, in the soil around the alumworks in concentrations substantially above background levels. Consequently, it is likely that the cadmium deposited in the area, has leached through the upper layers of the soil profile on its way to the sea sediments. Likewise, the lead concentrations in the soil beyond 200 m from the alumworks are not above background levels which indicate that losses through leaching have occurred at a rate of 0.5 to 1.5% yr⁻¹.Finally, comparisons with other long-term perspective studies give an opportunity to discuss the rate for the disappearance of an environmental problem.