Bioaccumulation of nitroarenes in bivalves at Osaka Bay, Japan

This paper reports for the first time the detection and occurrence of nitroarenes (NPAHs) in marine organisms. Mussels and oysters collected from Osaka Bay, Japan, had total NPAHs concentrations that ranged from 2380 to 24,688 pg/g dry and 2672 to 25,961 pg/g dry, respectively. Relatively higher concentrations were detected in sampling sites located near the central district and suburbs of Osaka City implying that the most probable sources of NPAHs in the two bivalves are exhaust gases and smokes emitted by automobiles and industrial plants. Bivalves had relatively higher residues of 1-nitronaphthalene, 2-nitronaphthalene, 3-nitrophenanthrene, and 9-nitrophenanthrenes. Residues of 2-nitrofluorene, 1-nitropyrene, 4-nitropyrenes, and 6-nitrochrysene were much lower compared to nitronaphthalenes and nitrophenanthrenes. Inter-species differences was only observed for 2-nitronaphthalene with oysters exhibiting significantly higher residues than mussels.     

A discontinuous Galerkin method for two-phase flow in a porous medium enforcing H(div) velocityand continuous capillary pressure

We consider the slightly compressible two-phase flow problem in a porous medium with capillary pressure. The problem is solved using the implicit pressure, explicit saturation (IMPES) method, and the convergence is accelerated with iterative coupling of the equations. We use discontinuous Galerkin to discretize both the pressure and saturation equations. We apply two improvements, which are projecting the flux to the mass conservative H(div)-space and penalizing the jump in capillary pressure in the saturation equation. We also discuss the need and use of slope limiters and the choice of primary variables in discretization. The methods are verified with two- and three-dimensional numerical examples. The results show that the modifications stabilize the method and improve the solution.     

Japan’s Nation-Wide Electronic Geotechnical Database Systems by Japanese Geotechnical Society

On October 15, 2010, the Japanese Geotechnical Society (JGS) announced the public release of ‘Nation-wide Electronic Geotechnical Database Systems,’ which provides geotechnical information to the public on the internet. The information the system provides is a collection of ground models at 250 m by 250 m in plan built by using data from various geotechnical information databases. The paper first describes historical development of the geotechnical information databases in Japan, and introduces a 5-year project, ‘Integrated Geophysical and Geological Information Database in Japan,’ led by the National Research Institute for Earth Science and Disaster Prevention (NIED), and participated by the JGS. The paper then presents the JGS’ ‘Nation-wide Electronic Geotechnical Database Systems,’ and describes why such system was proposed and built, followed by the presentation of the examples for possible application of the system.     

Investigation of the sliding behavior between steel and mortar for seismic applications in structures

The friction developed between a steel base plate and a mortar base contributes shear resistance to the building system during a seismic event. In order to investigate the possible sliding behavior between the base plate and the mortar, a shake table study is undertaken using a large rigid mass supported by steel contact elements which rest on mortar surfaces connected to the shake table. Horizontal input accelerations are considered at various magnitudes and frequencies. The results provide a constant friction coefficient during sliding with an average value of approximately 0.78. A theoretical formulation of the friction behavior is also undertaken. The theoretical equations show that the sliding behavior is dependent on the ratio of the friction force to the input force. The addition of vertical accelerations to the system further complicates the sliding behavior as a result of the varying normal force. This results in a variable friction resistance which is a function of the amplitude, phase, and frequency of the horizontal and vertical input motions. In general, this study showed a consistent and reliable sliding behavior between steel and mortar. Copyright © 2009 John Wiley & Sons, Ltd.     

Recent Results from Studies of Electric Discharges in the Mesosphere

The paper reviews recent advances in studies of electric discharges in the stratosphere and mesosphere above thunderstorms, and their effects on the atmosphere. The primary focus is on the sprite discharge occurring in the mesosphere, which is the most commonly observed high altitude discharge by imaging cameras from the ground, but effects on the upper atmosphere by electromagnetic radiation from lightning are also considered. During the past few years, co-ordinated observations over Southern Europe have been made of a wide range of parameters related to sprites and their causative thunderstorms. Observations have been complemented by the modelling of processes ranging from the electric discharge to perturbations of trace gas concentrations in the upper atmosphere. Observations point to significant energy deposition by sprites in the neutral atmosphere as observed by infrasound waves detected at up to 1000 km distance, whereas elves and lightning have been shown significantly to affect ionization and heating of the lower ionosphere/mesosphere. Studies of the thunderstorm systems powering high altitude discharges show the important role of intracloud (IC) lightning in sprite generation as seen by the first simultaneous observations of IC activity, sprite activity and broadband, electromagnetic radiation in the VLF range. Simulations of sprite ignition suggest that, under certain conditions, energetic electrons in the runaway regime are generated in streamer discharges. Such electrons may be the source of X- and Gamma-rays observed in lightning, thunderstorms and the so-called Terrestrial Gamma-ray Flashes (TGFs) observed from space over thunderstorm regions. Model estimates of sprite perturbations to the global atmospheric electric circuit, trace gas concentrations and atmospheric dynamics suggest significant local perturbations, and possibly significant meso-scale effects, but negligible global effects.     

Geochemical analyses of geological layers and groundwater flows

X-ray fluorescent spectroscope analysis easily finds ratios of geochemical elements in soil. Applying the method of ratio matching to measured ratios, the classification of geological layers, and the flow directions of groundwater can be determined. This method is applied to three hill slopes in Japan and the results are in good agreement with the observations and measurements of soil cores obtained by drilling. The classification of geological layers is found to be quantitatively connected with the rates of organic matter in soil cores. Received: 5 February 1999 · Accepted: 7 September 1999     

Raman spectra of methane hydrate up to 86 GPa

High-pressure Raman studies of methane hydrate were performed using a diamond anvil cell in the pressure range of 0.1–86 GPa at room temperature. Raman spectra of the methane molecules revealed that new softened intramolecular vibration mode of ν ₁ appeared at 17 GPa and that the splitting of vibration mode of ν ₃ occurred at 15 GPa. The appearance of these two modes indicates that an intermolecular attractive interaction increases between the methane molecules and the host water molecules and between the neighboring methane molecules. These interactions might result in the exceptional stability of a high-pressure structure, a filled ice Ih structure (FIIhS) for methane hydrate, up to 40 GPa. At 40 GPa, a clear change in the slope of the Raman shift versus pressure occurred, and above 40 GPa the Raman shift of the vibration modes increased monotonously up to 86 GPa. A previous XRD study showed that the FIIhS transformed into another new high-pressure structure at 40 GPa. The change in the Raman spectra at 40 GPa may be induced by the transition of the structure.     

Mesoscale structures of two types of cold-air outbreaks over the East China Sea and the effect of coastal sea surface temperature

Two types of cold-air outbreaks over the Yellow and East China Seas are investigated using a regional mesoscale model. Distinct patterns of surface turbulent heat fluxes and precipitation are identified between the two cases. The sea surface heat flux and frictional velocity are strongly influenced by mesoscale differences between high- and low-resolution datasets of sea surface temperature (SST). The influence of the SST difference on atmospheric water is spread to the downstream area of the outbreak with the phase transition of water. The air mass transformation around 800?hPa over the Kuroshio is partly influenced by the upstream SST difference. In particular, the SST difference near the mouth of the Yanzi River strongly modifies the air mass around Taiwan. Thus, in addition to the Kuroshio front, the mesoscale Chinese coastal SST structure is also important in the air mass transformation over the East China Sea.     

Ore mineralogy and sulfur isotope study of the massive sulfide deposit of Filon Norte,Tharsis Mine,Spain

The volcanogenic massive sulfide deposit of Filon Norte at Tharsis is hosted by carbonaceous black slate and connected only partly with stockwork veins. The massive ores are usually composed of fine-grained pyrite with subordinate amounts of sphalerite, chalcopyrite, galena and arsenopyrite. Monoclinic pyrrhotite sometimes occurs in massive pyritic ores in the apparently middle and upper horizons of the orebody, and siderite-rich ores are interstratified with compact pyritic ores in the apparently lower horizons. From the occurrence of monoclinic pyrrhotite, together with the FeS contents of sphalerite mostly ranging from 11 to 16 mol %, it is inferred that the sulfide minerals of the massive orebody were precipitated in euxinic muds on the sea-floor at temperatures below 250°C. The negatively shifted, highly variable ³⁴S values of the massive ores and their close similarity to those of the underlying black slates strongly suggest that the sulfide sulfur of the massive orebody and the slates is cognate and biogenic.