Boron incorporation into mullite

Summary Boron-doped mullites were synthesized using aluminium nitrate-nonahydrate, tetraethoxysilane and boric acid in a sol–gel process with subsequent annealing at 950 and 1300 °C for five hours. Two different bulk compositions with constant Al₂O₃ contents (60 and 70 mol%, respectively) and varying SiO₂ plus B₂O₃ contents were investigated. X-ray powder diffraction analyses yielded a linear decrease of the lattice parameters with increasing bulk B₂O₃ content, which was interpreted as to be due to boron incorporation. Related to the increasing boron content, corresponding infrared spectra revealed a slight and continuous shift for most of the absorption bands. These data show that mullite is able to incorporate large amounts of boron into its structure (up to about 20 mol% B₂O₃ depending on the bulk composition of the starting materials). Infrared analyses suggest that boron is incorporated into the mullite structure in form of planar three-fold coordinated BO₃ groups. Author’s address: A. Beran, Institut für Mineralogie und Kristallographie, Universit?t Wien-Geozentrum, Althanstra?e 14, 1090 Wien, Austria     

Azimuth determination by equatorial stars

Summary Difficulties in the determination of precise azimuth from observations on Polaris at high latitudes suggested an investigation of azimuth determination from other stars. A proposed method for determining azimuth by observing the time of crossing of stars in the vertical plane through the reference object is discussed theoretically, and results of a field test of the method are given.

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Zusammenfassung Genaue Azimutbestimmungen mit Hilfe des Polarsterns sind in h?heren Breiten schwierig. Der Verfasser untersucht daher die Azimutbestimmung mit Hilfe anderer Sterne. Der Aufsatz er?rtert die Theorie eines Messverfahrens, bei dem die Durchgangszeiten von Sternen durch die Referenz-Lotebene beobachtet werden. Ergebnisse von Versuchsmessungen werden mitgeteilt.

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Resumen La dificultad de efectuar determinaciones precisas de azimut con la estrella polar, han conducido al autor a estudiar esta determinación con otras estrellas. El artículo discute la teoría de un método de determinación por observación del instante de pasos de estrellas por el plano vertical de la referencia y presenta resultados experimentales.

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Résumé La difficulté des déterminations précises d'azimuth sur l'étoile polaire, aux hautes latitudes, ont amené l'auteur à étudier cette détermination sur d'autres étoiles. L'article discute la théorie d'une méthode de détermination par observation de l'instant de passage des étoiles dans le plan vertical de la référence et présente des résultats expérimentaux.

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Riassunto La difficoltà di effettuare determinazioni precise d'azimut con la Polare, ad alte latitudini, ha indotto l'Autore a studiare tale determinazione con altre stelle. L'articolo tratta la teoria di un metodo di determinazione con osservazione dell'istante di passaggio delle stelle nel piano verticale di riferimento e presenta alcuni risultati sperimentali.

     

Geodesic polygons on surfaces of revolution

This paper presents a way for computing geodesic polygons on real surfaces of revolution with partly continuous curvature and gives an application to coordinate transformations in geodesic coordinate systems. The specific formulas for an ellipsoid of revolution are briefly mentioned.     

On the origin of early Archaean gneisses: A reply

The use of metamorphosed basic dykes as one of the most important single field criteria for subdividing gneisses in high grade areas into different chronological units is defended. The universal applicability of the lower greenstone-granite-upper greenstone model to all Archaean terrains is questioned using documented sequences of events in the North Atlantic craton. We prefer a chronology based on field criteria to one based on the application of theoretical crustal development models taken from one tectonic environment and used to explain the sequence of events in another.It is shown that the average K₂O and Rb content from the 3600 m.y. sialic rocks of the North Atlantic craton ranges between 2.26 (Amîtsoq grey gneisses, Greenland) to 2.66 (Uivak grey gneisses, Labrador). Average K/Rb ratios are respectively 200 and 177, Rb/Sr, 0.33 and 0.29 for the two areas. K and Rb values are thus markedly higher than those reported from most other Archaean gneiss suites. Secondary redistribution of K and Rb at about 3600 m.y. is demonstrated by the documentation of the massive addition of these elements to basic rocks included in the gneisses. Whole sale addition of alkalies during migmatisation to the level of crust now exposed is postulated as one explanation of the unusually high K and Rb contents. It is argued on statistical grounds that if Rb metasomatism occurred it is not possible to use low initial Sr ratios alone to preclude the possibility that part of the Archaean gneiss complexes consist of tonalitic gneiss which are much older than conventional Sr₀ interpretations allow.     

The logistics of household hurricane evacuation

Although there is a substantial amount of research on households’ hurricane evacuation decision making, there is much less research on the logistical issues involved in implementing those evacuations. The limited research on household evacuation logistics has consistently shown that most evacuees stay in the homes of friends and relatives or in commercial facilities rather than in public shelters. However, evacuation logistics—which can be defined as the activities and associated resources needed to reach a safe location and remain there until it is safe to return—encompasses a much broader range of behaviors than this. The present study extends previous research by reporting data on other aspects of evacuation logistics such as departure timing, vehicle use, evacuation routes, travel distance, shelter type, evacuation duration, and evacuation cost. Hurricane Lili evacuation data at the county level are generally consistent with the data from previous hurricanes, but there is notable variation across counties studied here. There were only modest correlations of demographic and geographic variables with the evacuation logistics variables, a result that indicates further research is needed to better understand what happens between the time an evacuation decision is made and the time re-entry is begun. Moreover, research is needed to understand the logistics of evacuation by special populations such as transients and households with disabled members.     

Groundwater recharge in natural dune systems and agricultural ecosystems in the Thar Desert region, Rajasthan, India

Water and nutrient availability for crop production are critical issues in (semi)arid regions. Unsaturated-zone Cl tracer data and nutrient (NO₃ and PO₄) concentrations were used to quantify recharge rates using the Cl mass balance approach and nutrient availability in the Thar Desert, Rajasthan, India. Soil cores were collected in dune/interdune settings in the arid Thar Desert (near Jaisalmer) and in rain-fed (nonirrigated) and irrigated cropland in the semiarid desert margin (near Jaipur). Recharge rates were also simulated using unsaturated zone modeling. Recharge rates in sparsely vegetated dune/interdune settings in the Jaisalmer study area are 2.7–5.6 mm/year (2–3% of precipitation, 165 mm/year). In contrast, recharge rates in rain-fed agriculture in the Jaipur study area are 61–94 mm/year (10–16% of precipitation, 600 mm/year). Minimum recharge rates under current freshwater irrigated sites are 50–120 mm/year (8–20% of precipitation). Nitrate concentrations are low at most sites. Similarity in recharge rates based on SO₄ with those based on Cl is attributed to a meteoric origin of SO₄ and generally conservative chemical behavior in these sandy soils. Modeling results increased confidence in tracer-based recharge estimates. Recharge rates under rain-fed agriculture indicate that irrigation of 20–40% of cultivated land with 300 mm/year should be sustainable.     

Turbulent flows over mountainous terrain modelled by the Reynolds equations

A numerical model based upon fundamental principles, a standard (k, ) turbulence closure and a finite element integration technique, is applied to separated flows over hills. Predictions are compared to experimental data from a wind tunnel. Although few-equation turbulence closures have been shown to have obvious deficiencies with respect to comparable flows, the model predicts remarkably accurately, without coefficient adjustments of any kind. Even the turbulent intensity is predicted quite realistically.     

Masses of stellar black holes and testing theories of gravitation

The paper analyzes the mass distribution of stellar black holes derived from the light and radial-velocity curves of optical stars in close binary systems using dynamical methods. The systematic errors inherent in this approach are discussed. These are associated primarily with uncertainties in models for the contribution from gaseous structures to the optical brightness of the systems under consideration. The mass distribution is nearly flat in the range 4–15M _⊙. This is compared with the mass distribution for black holes in massive close binaries, which can be manifest as ultrabright X-ray sources (L _x >10³⁹ erg/s) observed in other galaxies. If the X-ray luminosities of these objects correspond to the Eddington limit, the black-hole mass distribution should be described by a power law, which is incompatible with the flat shape derived dynamically from observations of close binaries in our Galaxy. One possible explanation of this discrepancy is the rapid evaporation of stellar-mass black holes predicted in recent multi-dimensional models of gravity. This hypothesis can be verified by refining the stellar black-hole mass spectrum or finding isolated or binary black holes with masses below ～3M _⊙.     

Determination of the concentration of chemical main and trace elements (chemical matrix) in the aerosol from 1972 to 1982 at a North-alpine pure air station at 1780 m a.s.l.

Summary Aerosol particles have been separated by filter at a mountain station at 1780 m a.s.l. continuously since 1972. The station (a WMO-BAPMoN station with extended program) is freely exposed to all sides and in no way influenced by local aerosol sources. In the cold seasons it lies almost exclusively above the convection layer (very often over inversions) so that real background data can be acquired in these cases. By means of analytical methods the chemical components are determined on the exposed filters. This includes (apart from crust elements) also cations and anions from man-made and maritime sources as well as some important trace elements (in all, 15 components). Filters are exposed over 1–4 days. Filter exchange is determined by the respective weather situation with due regard to all changes so that the requirements for a reasonable correlation of the measured values with the meteorological conditions are met. Additionally, all meteorological parameters are determined, as well as intensity of the vertical exchange, number density of Aitken nuclei, concentration of natural radioactivity (RaB), and other variables. In the present paper the components of the aerosol chemical matrix are related to the behavior of the parameters below and the results are discussed in detail: Dependence of the individual components on total aerosol mass per volume, type of air mass; representation of two single cases of long-range transport of crust elements (source areas: Sahara, Colorado); vertical exchange coefficient, concentration of natural radioactivity, temperature gradient between valley and mountain station, temperature at the sampling site, relative humidity, precipitation rate, wind direction. occurrence of fog.Zusammenfassung An einer allseitig frei exponierten Bergstation in 1780 m NN werden seit 1982 die Aerosolpartikel auf Filtern gesammelt. Die Station (eine WMO-BAPMoN-Station mit erweitertem Programm) wird nicht durch lokale Aerosolquellen in irgendeiner Weise beeinflußt. Sie liegt in den kalten Jahreszeiten fast ausschließlich über der Konvektionsschicht (sehr oft oberhalb von Inversionen), so daß in diesen Fällen echte Background-Daten erfaßt werden. Mittels analytischer Verfahren werden an den exponierten Filtern alle chemischen Hauptkomponenten (von den Krustenelementen abgesehen auch die Kationen und Anionen sowohl anthropogenen als auch maritimen Ursprungs), sowie einige gewichtige Spurenelemente (insgesamt 15 Komponenten) bestimmt. Die Filter werden 1–4 Tage lang exponiert. Der Filterwechsel wird durch den jeweiligen Wetterzustand bzw. seiner Veränderung gesteuert, so daß eine gute Voraussetzung für eine Zuordnung der Meßwerte zu den meteorologischen Bedingungen gegeben ist. Zusätzlich werden alle meteorologischen Parameter, sowie die Intensität des Vertikalaustausches, Zahl der Aitken-Kerne, Konzentration der natürlichen Radioaktivität (RaB) und andere Größen bestimmt. In der vorliegenden Arbeit werden die Komponenten der chemischen Aerosolmatrix zum Verhalten der folgenden Parameter in Beziehung gesetzt und die Ergebnisse eingehend diskutiert:Abhängigkeit der Einzelkomponenten von: Gesamt-Aerosohnasse pro Volumen; Typ der Luftmasse und Darstellung von zwei Einzelfällen eines Ferntransportes von Krustenelementen (Quellgebiete: Sahara, Colorado); vertikaler Austauschkoeffizient; Konzentration der natürlichen Radioaktivität; Temperaturgradient zwischen Tal- und Bergstation; Temperatur an der Probennahmestelle; relative Feuchte; Niederschlagsintensität; Windrichtung; Auftreten von Nebel.

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Bestimmung der Konzentration chemischer Haupt- und Spurenstoffe (chemische Matrix) im Aerosol von 1972 bis 1982 an einer nordalpinen Reinluftstation in 1780 m NN.Teil II: Parametrische Korrelationsanalyse der chemischen Matrix mit Berücksichtigung meteorologischer Größen

     

Ra’s Abdah of the north Eastern Desert of Egypt: the role of granitic dykes in the formation of radioactive mineralization,evidenced by zircon morphology and chemistry

Syenogranitic dykes in the north of Egypt’s Eastern Desert are of geological and economic interest because of the presence of magmatic and supergene enrichment of radioactive mineralization. Zircon crystal morphology within the syenogranitic dykes allows precise definition of sub-alkaline series granites and crystallized at mean temperature of about 637 °C. The growth pattern of the zircons suggest magmatic and hydrothermal origins of radioactive mineralization. Hydrothermal processes are responsible for the formation of significant zircon overgrowth; high U-zircon margins might have occurred contemporaneously with the emplacement of syenogranitic dykes which show anomalous uranium (eU) and thorium (eTh) contents of up to 1386 and 7330 ppm, respectively. Zircon chemistry revealed a relative increase of Hf consistent with decreasing Zr content, suggesting the replacement of Zr by Hf during hydrothermal activity. Visible uranium mineralization is present and recognized by the presence of uranophane and autunite.