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61.
62.
Margarida Nunes Filipe Martinho Anaïs Vernisseau Philippe Marchand Bruno Le Bizec Henk W. van der Veer Henrique N. Cabral Fernando Ramos Miguel A. Pardal 《Marine pollution bulletin》2014
Contamination levels and profiles of 7 polychlorinated-p-dioxins, 10 polychlorinated furans (PCDD/Fs) and 12 dioxin-like polychlorinated biphenyls (dl-PCBs) were investigated in juvenile European flounder (Platichthys flesus) captured in different nursery areas in the northeastern Atlantic coast across its geographical distribution range. The toxic equivalent concentrations (WHO-TEQfish) were also determined in order to evaluate which P. flesus population was more exposed to dioxin-like toxicity. Juveniles caught in the Sørfjord (Norway) showed the lowest WHO-TEQfish concentration (0.052 pg WHO-TEQfish g−1 wet weight) whereas the highest value was observed in fish from the Wadden Sea (The Netherlands; 0.291 pg WHO-TEQfish g−1 ww), mainly due to the greater contribution of 2,3,7,8-tetrachlorodibenzo-p-dioxin, the most toxic congener. Nonetheless, when comparing the results with existent tissue residue-based toxicity benchmarks, no adverse effects resulting from PCDD/Fs and dl-PCBs are expected to occur in flounder from the studied systems. 相似文献
63.
This paper presents an analysis of the mobilization of the dolmen of Dombate, a megalithic monument situated in the Northwest of Spain. The study is founded on simple static principles, with the application of basic concepts of soil mechanics (soil reactions were computed by the reaction modulus method) and rock mechanics (a simple secant approach was adopted to model the contact between orthostats). In addition, a simplified geometric model for dolmens was adopted. On the basis of these concepts, a numerical solver able to provide quick estimations of the system's mobilization was developed. Using this tool, a number of sensitivity analyses were conducted to estimate the mobilization that could be caused by a conservation project currently under consideration. It was found that mobilization might be excessive, and therefore, a safer procedure is proposed. In short, this paper puts forth a new rational approach for archaeological practices which may help to estimate the possible consequences of excavations and rehabilitations on megalithic structures. 相似文献
64.
Miguel Angelo Stipp Basei Benjamim Bley Brito Neves Oswaldo Siga Junior Marly Babinski Marcio Martins Pimentel Colombo Celso Gaeta Tassinari Maria Helena Bezerra Hollanda Allen Nutman Umberto Giuseppe Cordani 《Precambrian Research》2010
The South-American continent is constituted of three major geologic–geotectonic entities: the homonym platform (consolidated at the end of the Cambrian), the Andean chain (essentially Meso-Cenozoic) and the Patagonian terrains, affected by tectonism and magmatism through almost all of the Phanerozoic. The platform is constituted by a series of cratonic nuclei (pre-Tonian, fragments of the Rodinia fission) surrounded by a complex fabric of Neoproterozoic structural provinces. 相似文献
65.
Soil contamination from urban and industrial activity: example of the mining district of Linares (southern Spain) 总被引:1,自引:0,他引:1
J. Martínez J. F. Llamas E. de Miguel J. Rey M. C. Hidalgo 《Environmental Geology》2008,54(4):669-677
The Linares region (southern Spain) has been subjected to two important sources of pollution: the intensive mining works and
the urban-industrial activity. To obtain a geochemical characterisation of the soil, 31 trace elements were analysed and 669
soil samples were collected. By means of clustering analysis, we identified groups of elements and grid squares in which relations
could be established concerning soil lithology, urban and industrial activities and the degree of pollution impact; in addition,
we were able to characterise the geochemical background of the study area. The multivariate study led us to identify four
factors. Particularly important was factor 2, which represented the elements associated with mineral paragenesis (Cu, Pb,
As, Co, Mn, Zn, Sn, Ba). This factor also contains elements related with an urban-industrial activity, such as Pb, Cu, Zn,
As and Ba. Furthermore, we identified factor 4, associating Ni, V and Cr, and which is related to the use of fuels. 相似文献
66.
Fluxes and sources of suspended organic matter in an estuarine turbidity maximum region during low discharge conditions 总被引:6,自引:1,他引:6
Miguel A. Goni Mary W. Cathey Yong H. Kim George Voulgaris 《Estuarine, Coastal and Shelf Science》2005,63(4):683-700
Water column concentrations of total suspended solids (TSS), particulate organic carbon (POC) and particulate nitrogen (PN) were measured at three different depths in four different locations bracketing the estuarine turbidity maximum (ETM) along the main channel of a temperate riverine estuary (Winyah Bay, South Carolina, USA). Measurements were carried out over full tidal cycle (over 24 h). Salinity, temperature, current magnitude and direction were also monitored at the same time throughout the water column. Tidally averaged net fluxes of salt, TSS, POC and PN were calculated by combining the current measurements with the concentration data. Under the extreme low river discharge conditions that characterized the study period, net landward fluxes of salt were measured in the lower part of the study area, suggesting that the landward transport through the main channel of the estuary was probably balanced by export out through the sides. In contrast, the net fluxes of salt in the upper reaches of the study area were near zero, indicating a closed salt balance in this part of the estuary. In contrast to salt, the net fluxes of TSS, POC and PN in the deeper parts of the water column were consistently landward at all four sites in Winyah Bay indicating the non-conservative behavior of particulate components and their active transport up the estuary in the region around the ETM.The carbon contents (%POC), carbon:nitrogen ratios (org[C:N]a) and stable carbon isotopic compositions (δ13CPOC) of the suspended particles varied significantly with depth, location and tidal stage. Tidally averaged compositions showed a significant increase up the estuary in the %POC and org[C:N]a values of suspended particles consistent with the preferential landward transport of carbon-rich particles with higher vascular plant debris content. The combination of tidal resuspension and flood-dominated flow appeared to be responsible for the hydrodynamic sorting of particles along the estuary that resulted in denser, organic-poor particles being transported landward less efficiently. The elemental and isotopic compositions indicated that vascular C3 plants and estuarine algae were the major sources of the particulate organic matter of all the samples, without any significant contributions from salt marsh C4 vegetation (Spartina alterniflora) and/or marine phytoplankton. 相似文献
67.
David D. Bosch Alisa W. Coffin Joseph Sheridan Oliva Pisani Dinku M. Endale Tim C. Strickland 《水文研究》2021,35(8):e14334
The US Department of Agriculture-Agricultural Research Service Southeast Watershed Research Laboratory (SEWRL) initiated a hydrologic research program on the Little River Experimental Watershed (LREW) in 1967. Long-term (52 years) streamflow data are available for nine sites, including rainfall-runoff relationships and hydrograph characteristics regularly used in research on interactive effects of climate, vegetation, soils, and land-use in low-gradient streams of the US EPA Level III Southeastern Plains ecoregion. A summary of prior research on the LREW illustrates the impact of the watershed on building a regional understanding of hydrology and water quality. Climatic and streamflow data were used to make comparisons of scale across the nine nested LREW watersheds (LRB, LRF, LRI, LRJ, LRK, LRO, LRN, LRM, and LRO3) and two regional watersheds (Alapaha and Little River at Adel). Annual rainfall for the largest LREW, LRB, was 1200 mm while average annual streamflow was 320 mm. Annual rainfall, streamflow, and the ratio between annual streamflow and rainfall (Sratio) were similar (α = 0.05) across LREWs LRB, LRF, LRI, LRJ, LRK, and LRO. While annual rainfall within the 275 ha LRO3 was found to be similar to LRO and LRM (α = 0.05), annual streamflow and Sratio were significantly different (α = 0.05). Comparisons of annual rainfall, streamflow, and Sratio between LRB and the regional watersheds indicated no differences (α = 0.05). Based upon this analysis, most regional watersheds shared similar hydrologic characteristics. LRO3 was an exception, where increases in row crops and decreases in forest coverage resulted in increased streamflow. LREW data have been instrumental in building considerable scientific understanding of flow and transport processes for these stream systems. Continued operation of the LREW hydrologic network will support hydrologic research as well as environmental quality and riparian research programs that address emerging and high priority natural resource and environmental issues. 相似文献
68.
This study aims to determine and to model the relationship of matric suction versus water content, known as soil?Cwater characteristic curve (SWCC), for a tropical soil profile at the southeastern Brazil. This soil profile consists of a colluvial, lateritic silty clay, with thickness of about 6.5?m. The filter paper and pressure plate techniques were used to determine the SWCC. Specimens were trimmed from the undisturbed soil samples collected along soil profile depth and submitted to drying paths. Impregnated thin-layer plates and a petrographic microscope were used to examine the structure and mineralogical composition of the soil samples. Mercury intrusion porosimetry tests were performed on some soil samples to obtain the frequency histogram of the pores. SWCC with bimodal pore-size distribution were obtained by the filter paper technique and SWCC with unimodal pore-size distribution were obtained by the pressure plate technique. The SWCC showed values of air-entry ranging from 1 to 3?kPa, depending on the technique used, resembling soils with macroporosity, as the lateritic soils. Combining both techniques, the SWCC could be fitted by a model that takes into consideration soils with macro and microporosity. 相似文献
69.
Sources and distribution of organic matter in a river-dominated estuary (Winyah Bay, SC, USA) 总被引:12,自引:0,他引:12
Miguel A. Goi Maria J. Teixeira David W. Perkey 《Estuarine, Coastal and Shelf Science》2003,57(5-6):1023-1048
The sources and distribution of organic matter (OM) in surface waters and sediments from Winyah Bay (South Carolina, USA) were investigated using a variety of analytical techniques, including elemental, stable isotope and organic biomarker analyses. Several locations along the estuary salinity gradient were sampled during four different periods of contrasting river discharge and tidal range. The dissolved organic carbon (DOC) concentrations of surface waters ranged from 7 mg l−1 in the lower bay stations closest to the ocean to 20 mg l−1 in the river and upper bay samples. There was a general linear relationship between DOC concentrations and salinity in three of the four sampling periods. In contrast, particulate organic carbon (POC) concentrations were significantly lower (0.1–3 mg l−1) and showed no relationship with salinity. The high molecular weight dissolved OM (HMW DOM) isolated from selected water samples collected along the bay displayed atomic carbon:nitrogen ratios ([C/N]a) and stable carbon isotopic compositions of organic carbon (δ13COC) that ranged from 10 to 30 and from −28 to −25‰, respectively. Combined, such compositions indicate that in most HMW DOM samples, the majority of the OM originates from terrigenous sources, with smaller contributions from riverine and estuarine phytoplankton. In contrast, the [C/N]a ratios of particulate OM (POM) samples varied significantly among the collection periods, ranging from low values of 5 to high values of >20. Overall, the trends in [C/N]a ratios indicated that algal sources of POM were most important during the early and late summer, whereas terrigenous sources dominated in the winter and early spring.In Winyah Bay bottom sediments, the concentrations of the mineral-associated OM were positively correlated with sediment surface area. The [C/N]a ratios and δ13COC compositions of the bulk sedimentary OM ranged from 5 to 45 and from −28 to −23‰, respectively. These compositions were consistent with predominant contributions of terrigenous sources and lesser (but significant) inputs of freshwater, estuarine and marine phytoplankton. The highest terrigenous contents were found in sediments from the river and upper bay sites, with smaller contributions to the lower parts of the estuary. The yields of lignin-derived CuO oxidation products from Winyah Bay sediments indicated that the terrigenous OM in these samples was composed of variable mixtures of relatively fresh vascular plant detritus and moderately altered soil OM. Based on the lignin phenol compositions, most of this material appeared to be derived from angiosperm and gymnosperm vascular plant sources similar to those found in the upland coastal forests in this region. A few samples displayed lignin compositions that suggested a more significant contribution from marsh C3 grasses. However, there was no evidence of inputs of Spartina alterniflora (a C4 grass) remains from the salt marshes that surround the lower sections of Winyah Bay. 相似文献
70.
Daniela?Castro Camilo Miguel?de CarvalhoEmail authorView authors OrcID profile 《Stochastic Environmental Research and Risk Assessment (SERRA)》2017,31(7):1603-1613
We introduce a density regression model for the spectral density of a bivariate extreme value distribution, that allows us to assess how extremal dependence can change over a covariate. Inference is performed through a double kernel estimator, which can be seen as an extension of the Nadaraya–Watson estimator where the usual scalar responses are replaced by mean constrained densities on the unit interval. Numerical experiments with the methods illustrate their resilience in a variety of contexts of practical interest. An extreme temperature dataset is used to illustrate our methods. 相似文献