An overview of the Gulf of Batabanó (Cuba): Environmental features as revealed by surface sediment characterisation

The main environmental features of the Gulf of Batabanó, Cuba, Caribbean, were investigated through the analyses of surface sediments collected at 23 sites. In order to highlight the potential threats affecting the sedimentary compartment of this area, samples were analysed for: granulometry, mineralogy, heavy metals concentration (As, Cd, Cu, Mn, Ni, Pb, Zn), organic carbon, total nitrogen and radionuclides. Findings were compared with published data and “grey” literature.Results showed: granulometric homogeneity and a widespread carbonatic condition all over the gulf, probably due to stable bathymetry and lack of terrigenous input (except for the La Coloma basin); a rather pristine environment for what concerns heavy metals pollution, except for La Coloma where a large arsenic input was recorded; very low levels of natural and artificial radioactivity; a relevant quantity of sedimentary organic matter, providing biota with useful substrate for feeding and enhancing the food-web development while indirectly supplying lobster fisheries. Combined data highlighted the impact of the Dique Sur in reducing terrigenous input in the coastal area.Future studies should focus on dating of sediment cores for identifying and quantifying the changes acting in the gulf and on investigating the origins of the large arsenic input to La Coloma.     

Cotton Fiber/ZrO2, A New Material for Adsorption of Cr(VI) Ions in Water

The natural cotton fiber was used to synthesize an anion exchange, containing ZrO₂ film on its surface, NCFZC (natural cotton fiber/ZrO₂ composite). This anion exchanger was produced by the reaction of the zirconium oxychloride and hydroxyl groups on surface of the natural cotton fiber. The material was used for Cr(VI) ions adsorption studies. Adsorption equilibrium time and optimum pH for Cr(VI) adsorption were found to be 6 h and 4.0, respectively. The Langmuir and Temkin isotherms were used to models adsorption equilibrium data. The adsorption capacity of NCFZC was found to be 1.33 mmol/g. Kinetic studies showed that the rate of adsorption of Cr(VI) on NCFZC obeyed a pseudo‐second‐order kinetic model.     

Paleosecular variation and absolute geomagnetic paleointensity records retrieved from the Early Cretaceous Posadas Formation (Misiones,Argentina)

The Early Cretaceous may be considered a key period for understanding the evolution of the Earth’s magnetic field. Some still unsolved problems are related to the mode of paleosecular variation (PSV) of the Earth’s magnetic field before and during the Cretaceous Normal Superchron. We report here a detailed rock-magnetic, paleomagnetic and paleointensity investigation from 28 lava flows (331 standard paleomagnetic cores) collected in the Argentinean part of the Parana Flood Basalts (Formation Posadas) in order to contribute to the study of PSV during the early Cretaceous and to obtain precise Cretaceous paleomagnetic pole positions for stable South America. The average paleofield direction is precisely determined from 26 sites, which show small within-site dispersion and high directional stability. Five sites show evidences for the self-reversal of thermoremanent magnetization. 23 sites yielded normal polarity magnetization and only 3 are reversely magnetized. Moving windows averages were used to analyze the sequential variation of virtual geomagnetic pole’s (VGP) axial positions. Interestingly, the axial average VGP path traces an almost complete cycle around the geographical pole and passes near the location of all previously published Paraná Magmatic Province poles. Both paleomagnetic poles and average VGP paths are significantly different from the pole position suggested by fixed hotspot reconstructions, which may be due to true polar wander or the hotspot motion itself. Only 15 samples from 5 individual basaltic lava flows, yielded acceptable paleointensity estimates. The site mean paleointensities range from 25.2 ± 2.2 to 44.0 ± 2.2 μT. The virtual dipole moments (VDMs) range from 4.8 to 9.9 × 10²² Am². This correspond to a mean value of 7.7 ± 2.1 × 10²² Am² which is 96% of the present day geomagnetic field strength. These intensities agree with the relatively high values already reported for Early Cretaceous, which are consistent with some inferences from computer simulations previously published.     

An audio-magnetotelluric investigation in Terceira Island (Azores)

Ten audio-magnetotelluric soundings have been carried out along a profile crossing the Serra do Cume caldera in the eastern part of the Terceira Island (Azores). The main objectives of this investigation were to detect geoelectrical features related with tectonic structures and to characterize regional hydrological and hydrothermal aspects mainly those related to geothermal fluid dynamics.Three-dimensional numerical investigation showed that the data acquired at periods shorter than 1 s are not significantly affected by ocean effect. The data was analysed using the Smith's decomposition method in order to investigate possible distortions caused by superficial structures and to estimate a global regional strike. The results suggest that in general the soundings were not distorted. A regional N55°W strike was chosen for the two-dimensional data inversion.The low-resistivity zones (10–30 ohm-m) displayed in the central part of the 2-D geoelectrical model have been interpreted as caused by hydrothermal circulation. The low-resistivity anomalies at the ends of the profile might be attributed to alteration zones with interaction of seawater intrusion. High-resistivity (> 300 ohm-m) values have been related with less permeable zones in the SW of Cinco Picos and Guilherme Moniz caldera walls.     

Characteristics of the seismic attenuation in two tectonically active zones of Southern Europe

The seismic energy attenuation in the frequency range of 1–18 Hz was studied in the two tectonically active zones of Irno Valley (Southern Italy) and Granada Basin (South-East Spain). Data were recorded by short period vertical components seismographs for low-magnitude local earthquakes. The method of coda waves, assuming singleS toS scattering approximation, was used to calculate the quality factorQ from the two data set. Results show a quality factor increasing with frequency, following the empirical lawQ=Q _o f ⁿ .Q _o andn are lower for the Irno Valley than for Granada. This result is interpreted in terms of different scattering environments present in the two investigated areas.     

Screening model for volatile pollutants in dual porosity soils

This paper develops mass fraction models for transport and fate of agricultural pollutants in structured two-region soils. Mass fraction index models, based on a semi-infinite domain solution, are derived that describe leaching at depth, vapor losses through soil surface, absorption, and degradation in the dynamic- and stagnant-water soil regions. The models predict that leaching is the result of the combined effect of the upward vapor-phase transport relative to downward advection, residence time relative to half-life, dispersion, and lateral diffusive mass transfer. Simulations show that leached fraction of volatile compounds does not always decrease monotonically with increased residence time relative to the pollutant half-life, as a result of complex interactions among the different physical and biochemical processes. The results show that leaching, volatilization, and degradation losses can be affected significantly by lateral diffusive mass transfer into immobile-water regions and advection relative to dispersion (i.e. Peclet number) in the mobile-water regions. It is shown that solute diffusion into the immobile phase and subsequent biochemical decay reduces leaching and vapor losses through soil surface. Potential use of the modified leaching index for the screening of selected pesticides is illustrated for different soil textures and infiltration rates. The analysis may be useful to the management of pesticides and the design of landfills.     

Early contamination of European flounder (Platichthys flesus) by PCDD/Fs and dioxin-like PCBs in European waters

Contamination levels and profiles of 7 polychlorinated-p-dioxins, 10 polychlorinated furans (PCDD/Fs) and 12 dioxin-like polychlorinated biphenyls (dl-PCBs) were investigated in juvenile European flounder (Platichthys flesus) captured in different nursery areas in the northeastern Atlantic coast across its geographical distribution range. The toxic equivalent concentrations (WHO-TEQ_fish) were also determined in order to evaluate which P. flesus population was more exposed to dioxin-like toxicity. Juveniles caught in the Sørfjord (Norway) showed the lowest WHO-TEQ_fish concentration (0.052 pg WHO-TEQ_fish g⁻¹ wet weight) whereas the highest value was observed in fish from the Wadden Sea (The Netherlands; 0.291 pg WHO-TEQ_fish g⁻¹ ww), mainly due to the greater contribution of 2,3,7,8-tetrachlorodibenzo-p-dioxin, the most toxic congener. Nonetheless, when comparing the results with existent tissue residue-based toxicity benchmarks, no adverse effects resulting from PCDD/Fs and dl-PCBs are expected to occur in flounder from the studied systems.     

Mathiasite-loveringite and priderite in mantle xenoliths from the Alto Paranaíba Igneous Province,Brazil: genesis and constraints on mantle metasomatism

Alkali-bearing Ti oxides were identified in mantle xenoliths enclosed in kimberlite-like rocks from Limeira 1 alkaline intrusion from the Alto Paranaíba Igneous Province, southeastern Brazil. The metasomatic mineral assemblages include mathiasite-loveringite and priderite associated with clinopyroxene, phlogopite, ilmenite and rutile. Mathiasite-loveringite (55–60 wt.% TiO₂; 5.2–6.7 wt.% ZrO₂) occurs in peridotite xenoliths rimming chromite (～50 wt.% Cr₂O₃) and subordinate ilmenite (12–13.4 wt.% MgO) in double reaction rim coronas. Priderite (Ba/(K+Ba)< 0.05) occurs in phlogopite-rich xenoliths as lamellae within Mg-ilmenite (8.4–9.8 wt.% MgO) or as intergrowths in rutile crystals that may be included in sagenitic phlogopite. Mathiasite-loveringite was formed by reaction of peridotite primary minerals with alkaline melts. The priderite was formed by reaction of peridotite minerals with ultrapotassic melts. Disequilibrium textures and chemical zoning of associated minerals suggest that the metasomatic reactions responsible for the formation of the alkali-bearing Ti oxides took place shortly prior the entrainment of the xenoliths in the host magma, and is not connected to old (Proterozoic) mantle enrichment events.