Variation in biogeochemical parameters across intertidal seagrass meadows in the central Great Barrier Reef region

This survey provides baseline information on sediment characteristics, porewater, adsorbed and plant tissue nutrients from intertidal coastal seagrass meadows in the central region of the Great Barrier Reef World Heritage Area. Data collected from 11 locations, representative of intertidal coastal seagrass beds across the region, indicated that the chemical environment was typical of other tropical intertidal areas. Results using two different extraction methods highlight the need for caution when choosing an adsorbed phosphate extraction technique, as sediment type affects the analytical outcome. Comparison with published values indicates that the range of nutrient parameters measured is equivalent to those measured across tropical systems globally. However, the nutrient values in seagrass leaves and their molar ratios for Halophila ovalis and Halodule uninervis were much higher than the values from the literature from this and other regions, obtained using the same techniques, suggesting that these species act as nutrient sponges, in contrast with Zostera capricorni. The limited historical data from this region suggest that the nitrogen and phosphorus content of seagrass leaves has increased since the 1970s concomitant with changing land use practice.     

A comparative mineralogical and geochemical study of sulfide mine tailings at two sites in New Mexico, USA

A comparative study of sulfide mine tailings from two sites near Silver City in southwest New Mexico has shown the need for environmental monitoring in a geological context. The Cyprus-Piños Altos and Cleveland deposits consist of Cu and Zn skarn mineralization in the Piños Altos Mountains of New Mexico. Primary ore minerals in both deposits include chalcopyrite, sphalerite, and galena. The Cyprus-Piños Altos Mine ceased operation in 1995 and the Cleveland Mill closed in 1950. The deposits have similar mineralogical characteristics; however, the tailings are different in terms of age, degree of oxidation and method of disposal. The Cyprus-Piños Altos tailings (CPAT) are stored in a lined, bermed impoundment. They are dominantly water-saturated and exhibit no secondary-phase formation. The grains are not cemented and show no evidence of primary-mineral dissolution. The geochemical data show a predominantly primary signature. The tailings pond water is neutral to slightly alkaline (pH?from 7 to 8.3), partly as a result of processing methods. The Cleveland mill tailings (CMT) were deposited in a valley at the headwaters of an ephemeral stream. They are highly oxidized and differentially cemented. They have undergone numerous wet/dry cycles resulting in extensive oxidation. Secondary minerals predominate, and consist mainly of jarosite, goethite, hematite, and Fe-oxyhydroxides and -oxyhydroxysulfates. The pH of the stream draining the CMT is as high as 2.15. Maximum metal contents in the stream immediately downstream from the tailings are 5305?ppm Zn, 454?ppm Cu, 1.16?ppm Pb, 17.5?ppm Cd, 1.4?ppm As, and 0.01?ppm Hg.     

<Emphasis Type="Italic">Deepwater Horizon</Emphasis> Oil Spill Impacts on Salt Marsh Fiddler Crabs (<Emphasis Type="Italic">Uca</Emphasis> spp.)

The Deepwater Horizon oil spill was the largest marine oil spill in US waters to date and one of the largest worldwide. Impacts of this spill on salt marsh vegetation have been well documented, although impacts on marsh macroinvertebrates have received less attention. To examine impacts of the oil spill on an important marsh invertebrate and ecosystem engineer, we conducted a meta-analysis on fiddler crabs (Uca spp.) using published sources and newly available Natural Resources Damage Assessment (NRDA) and Gulf of Mexico Research Initiative (GoMRI) data. Fiddler crabs influence marsh ecosystem structure and function through their burrowing and feeding activities and are key prey for a number of marsh and estuarine predators. We tested the hypothesis that the spill affected fiddler crab burrow density (crab abundance), burrow diameter (crab size), and crab species composition. Averaged across multiple studies, sites, and years, our synthesis revealed a negative effect of oiling on all three metrics. Burrow densities were reduced by 39 % in oiled sites, with impacts and incomplete recovery observed over 2010–2014. Burrow diameters were reduced from 2010 to 2011, but appeared to have recovered by 2012. Fiddler crab species composition was altered through at least 2013 and only returned to reference conditions where marsh vegetation recovered, via restoration planting in one case. Given the spatial and temporal extent of data analyzed, this synthesis provides compelling evidence that the Deepwater Horizon spill suppressed populations of fiddler crabs in oiled marshes, likely affecting other ecosystem attributes, including marsh productivity, marsh soil characteristics, and associated predators.     

Impacts of climate, lake size, and supra- and sub-permafrost groundwater flow on lake-talik evolution, Yukon Flats, Alaska (USA)

In cold regions, hydrologic systems possess seasonal and perennial ice-free zones (taliks) within areas of permafrost that control and are enhanced by groundwater flow. Simulation of talik development that follows lake formation in watersheds modeled after those in the Yukon Flats of interior Alaska (USA) provides insight on the coupled interaction between groundwater flow and ice distribution. The SUTRA groundwater simulator with freeze–thaw physics is used to examine the effect of climate, lake size, and lake–groundwater relations on talik formation. Considering a range of these factors, simulated times for a through-going sub-lake talik to form through 90 m of permafrost range from ～200 to >?1,000  years (vertical thaw rates <?0.1–0.5  m?yr^?1). Seasonal temperature cycles along lake margins impact supra-permafrost flow and late-stage cryologic processes. Warmer climate accelerates complete permafrost thaw and enhances seasonal flow within the supra-permafrost layer. Prior to open talik formation, sub-lake permafrost thaw is dominated by heat conduction. When hydraulic conditions induce upward or downward flow between the lake and sub-permafrost aquifer, thaw rates are greatly increased. The complexity of ground-ice and water-flow interplay, together with anticipated warming in the arctic, underscores the utility of coupled groundwater-energy transport models in evaluating hydrologic systems impacted by permafrost.     

Encounters with an unearthly mudstone: Understanding the first mudstone found on Mars

The Sheepbed mudstone forms the base of the strata examined by the Curiosity rover in Gale Crater on Mars, and is the first bona fide mudstone known on another planet. From images and associated data, this contribution proposes a holistic interpretation of depositional regime, diagenesis and burial history. A lake basin probably received sediment pulses from alluvial fans. Bed cross‐sections show millimetre to centimetre‐scale layering due to distal pulses of fluvial sediment injections (fine‐grained hyperpycnites), fall‐out from river plumes, and some aeolian supply. Diagenetic features include mineralized synaeresis cracks and millimetre‐scale nodules, as well as stratiform cementation. Clay minerals were initially considered due to in situ alteration, but bulk rock chemistry and mineralogy suggests that sediments were derived from variably weathered source rocks that probably contained pre‐existing clay minerals. X‐ray diffraction analyses show contrasting clay mineralogy in closely spaced samples, consistent with at least partial detrital supply of clay minerals. A significant (ca 30 wt%) amorphous component is consistent with little post‐depositional alteration. Theoretical modelling of diagenetic reactions, as well as kinetic considerations, suggest that the bulk of diagenetic clay mineral formation occurred comparatively late in diagenesis. Diagenetic features (synaeresis cracks and nodules) were previously thought to reflect early diagenetic gas formation, but an alternative scenario of synaeresis crack formation via fabric collapse of flocculated clays appears more likely. The observed diagenetic features, such as solid nodules, hollow nodules, matrix cement and ‘raised ridges’ (synaeresis cracks) can be explained with progressive alteration of olivine/glass in conjunction with centrifugal and counter diffusion of reactive species. Anhydrite‐filled fractures in the Sheepbed mudstone occurred late in diagenesis when fluid pressures built up to exceed lithostatic pressure. Generating fluid overpressure by burial to facilitate hydraulic fracturing suggests a burial depth of at least 1000 m for the underlying strata that supplied these fluids.     

Hydraulic Performance of the Horizontal Reactive Media Treatment Well: Pilot and Numerical Study

This study is focused on a passive treatment system known as the horizontal reactive treatment well (HRX Well®) installed parallel to groundwater flow, which operates on the principle of flow focusing that results from the hydraulic conductivity (K) ratio of the well and aquifer media. Passive flow and capture in the HRX Well are described by simplified equations adapted from Darcy's Law. A field pilot-scale study (PSS) and numerical simulations using a finite element method (FEM) were conducted to verify the HRX Well concept and test the validity of the HRX Well-simplified equations. The hydraulic performance results from both studies were observed to be within a close agreement to the simplified equations and their hydraulic capture width approximately five times greater than the well diameter (0.20 m). Key parameters affecting capture included the aquifer thickness, well diameter, and permeability ratio of the HRX Well treatment media and aquifer material. During pilot testing, the HRX Well captured 39% of flow while representing 0.5% of the test pit cross-sectional volume, indicating that the well captures a substantial amount of surrounding groundwater. While uncertainty in the aquifer and well properties (porosity, K, well losses), including the effects of boundary conditions, may have caused minor differences in the results, data from this study indicate that the simplified equations are valid for the conceptual design of a field study. A full-scale HRX Well was installed at Site SS003 at Vanderberg Air Force Base, California, in July/August 2018 based on outcomes from this study.     

Freshwater reserves of mid-atlantic coast barrier Islands

A multiple regression model was constructed for the purpose of predicting barrier island hydrology from easily measureable island characteristics. The model was developed using data obtained from 17 sites on the Outer Banks of North Carolina. The accuracy of the model for predicting key hydrologic variables was evaluated by statistical and graphic procedures. In general, agreement between observed and predicted values of the hydrologic variables was very good, suggesting that the quantity of potable water at various island sites can be estimated without resorting to extensive field investigations. The model was then applied to Assateague Island, a barrier island located off the coasts of Maryland and Virginia. Results indicate that the original model developed for the Outer Banks may be applied to other barrier islands but that errors involved may necessitate corrections in detailed studies. Correction for bias in predictions for Assateague was shown to be possible with limited field data from surface resistivity surveys.     

Définition et datation de la Formation de Venaco (Corse) : dépôt d’origine gravitaire d’âge Priabonien

Priabonian age is highlighted for the first time in Corsica in the Venaco Formation using the presence of specific microfauna (in particular some representatives of Turborotalia cerroazulensis lineage). This silicoclastic formation is mainly represented by coarse facies. It is composed of three members from south to north and from oldest towards youngest: member of Uboli, Cardo and Orsu. The sedimentologic analysis reveals a gravity depositional environment, involving different type of currents. Sedimentologic and chronologic characteristics make the Venaco Formation and the Annot Formation (p.p.) equivalent. Dating the Venaco Fm. brings confirmation that the green schist metamorphism of the Variscan batholith and the related deformation are from the pre-Priabonian period.