Geochemical effects on metals following permanganate oxidation of DNAPLs

The application of in situ chemical oxidation for dense, nonaqueous phase liquid (DNAPL) remediation requires delivery of substantial levels of oxidant chemicals into the subsurface to degrade target DNAPLs and to satisfy natural oxidant demand. This practice can raise questions regarding changes in subsurface conditions, yet information regarding potential effects, especially at the field scale, has been lacking. This paper describes an evaluation of the effects on metals associated with in situ chemical oxidation using potassium permanganate at Launch Complex 34 (LC34), Cape Canaveral Air Station, Florida. At LC34, high concentrations of permanganate (1 to 2 wt%) were injected into the subsurface as part of a demonstration of DNAPL remediation technologies. In a companion experimental effort at the Colorado School of Mines, field samples were characterized and laboratory batch and mini-column studies were completed to assess effects of permanganate oxidation on metals in the subsurface one year after completion of the field demonstration. Results indicated there was potential for long-term immobilization of a portion of introduced manganese and no treatment-induced loss in subsurface permeability due to deposition of manganese oxides particles, which are a product of the oxidation reactions. Permanganate treatment did cause elevated manganese, chromium, and nickel concentrations in site ground water within the treated region. Some of these metals effects can be attenuated during downgradient flow through uncontaminated and untreated aquifer sediments.     

Remediating Ground Water with Zero-Valent Metals: Chemical Considerations in Barrier Design

To gain perspective and insight into the performance of permeable reactive barriers containing granular iron metal, it is useful to compare the degradation kinetics of individual chlorinated solvents over a range of operating conditions. Pseudo first-order disappearance rate constants normalized to iron surface area concentration (k_SA) recently have been reported for this purpose. This paper presents the results of further exploratory data analysis showing the extent to which variation in k_SA is due to initial halocarbon concentration, iron type, and other factors. To aid in preliminary design calculations, representative values of k_SA and a reactive transport model have been used to calculate the minimum barrier width needed for different ground water flow velocities and degrees of halocarbon conversion. Complete dechlorination of all degradation intermediates requires a wider treatment zone, but the effect is not simply additive because degradation occurs by sequential and parallel reaction pathways.     

Planetary perturbations of the Moon in ELP 2000

A new solution for the planetary perturbations of the Moon is being built in the frame of ELP 2000, using Bretagnon's planetary theories, and achieved at the first order. It contains the two actions commonly distinguished: direct and indirect. The internal precision of computation is 2×10^–6 arcsec. First-order planetary perturbations, in the direct case (Venus & Mars), have been compared to Standaert's solution. The major discrepancy reaches 70 cm in the longitude of Venus. Perturbations of the second order with respect to planetary masses, have been undertaken and illustrations are given. Finally, new values for the perigee and node motions are proposed.Proceedings of the Conference on Analytical Methods and Ephemerides: Theory and Observations of the Moon and Planets. Facultés universitaires Notre Dame de la Paix, Namur, Belgium, 28–31 July, 1980.     

The planet formation imager

The Planet Formation Imager (PFI, www.planetformationimager.org) is a next-generation infrared interferometer array with the primary goal of imaging the active phases of planet formation in nearby star forming regions. PFI will be sensitive to warm dust emission using mid-infrared capabilities made possible by precise fringe tracking in the near-infrared. An L/M band combiner will be especially sensitive to thermal emission from young exoplanets (and their disks) with a high spectral resolution mode to probe the kinematics of CO and H₂O gas. In this paper, we give an overview of the main science goals of PFI, define a baseline PFI architecture that can achieve those goals, point at remaining technical challenges, and suggest activities today that will help make the Planet Formation Imager facility a reality.     

Immune inhibition in marine mussels by polycyclic aromatic hydrocarbons

Polycyclic aromatic pollutants produced by a range of industrial processes and the combustion of fossil fuels. They eventually enter the marine environment, and are bioaccumulated in the tissues of sessile, filter-feeding bivalves, causing a variety of sublethal effects. Few studies, however, have examined immune inhibition in molluscs by these xenobiotics. Here, the immunotoxic effects of PAHs were investigated in marine mussels (Mytilus edulis) by means of in vivo exposure experiments. Animals were exposed to a PAH cocktail of anthracene, fluoranthene and phenanthrene for 2 or 4 weeks. The haemolymph was then extracted, and phagocytosis and lysosomal neutral red retention assays performed to examine the effects of PAHs on particle uptake by haemocytes and lysosome integrity, respectively. PAHs were found to inhibit phagocytosis and damage lysosomes. It is hypothesized that PAHs exert their toxicity directly on the lysosomes. A possible consequence of such lysosomal damage will be immune impairment in mussels leading to reduced resistance to infectious diseases.     

Land, ethnic, and gender change: Transnational migration and its effects on Guatemalan lives and landscapes

Migration to the United States of America from Guatemala effects many aspects of Guatemalan life. We document, through extensive ethnographic fieldwork, how migrants and their remittances effect gender relations, ethnicity, land use, and land distribution. Our evidence is drawn from research in four communities. San Pedro Pinula and Gualán represent communities of eastern Guatemala. San Cristóbal Totonicapán is an Indigenous town in Guatemala’s western highlands, and San Lucas is a lowland frontier community in the Guatemalan department of Ixcán, which borders Chiapas, Mexico. Our results reveal that migrants and their remittances, both social and tangible, result in significant changes in land use and land distribution in Ixcán. Migrant money permits the conversion of rainforest into cattle pasture and also results in the accumulation of land in the hands of migrants. In terms of land use, we see in San Pedro Pinula that migrant money also allows the Pokoman Maya to make small entries into the Ladino (non-indigenous) dominated cattle business. In San Pedro Pinula, the migration and return of Maya residents also permits them to slowly challenge ethnic roles that have developed over the last five centuries. When we look at how migration effects gender roles in Gualán and San Cristóbal we also note that migration and social remittances permit a gradual challenge and erosion of traditional gender roles in Guatemala. We point out, however, that migration-related changes to traditional gender and ethnic roles is gradual because migrants, despite their increased earnings and awareness, run into a social structure that resists rapid change. This is not the case when we examine land transformations in Ixcán. Here, migrants encounter few barriers when they attempt to put their new money and ideas to work. Despite the advantages that migration brings to many families, especially in the face of a faltering national economy and state inactivity regarding national development, we conclude that migration and remittances do not result in community or nation-wide development. At this stage migrant remittances are used for personal advancement and very little money and effort is invested in works that benefit communities or neighborhoods. We call for continued studies of the effects of international migration on Guatemalan hometowns that build on our initial studies to better understand the longer-term ramifications of migration in a country where no community is without migrants.     

A 12,000-Year Pollen Record from Lake Maliq, Albania

Pollen data from Lake Maliq, the first from Albania, contribute new information to the discussion of the vegetational, hydrological, and climatological history of the Balkans since 12,000 yr B.P. During late-glacial time, a perennial lake expanded at Maliq. It was surrounded by a complex vegetation association composed of steppe and mixed forest elements. The highly diverse forest flora suggest that late-glacial forest refugia were more developed here at middle altitude, rather than at higher altitude as previously suggested. The forest developed after 9800 yr B.P., while the water level remained high in the Korçë basin until 5000 yr B.P. Different environmental conditions, characterized by lower available moisture and warmer winters, progressively took place after this date. Human activity in the Korçë basin ca. 4500 yr B.P. was coeval with conditions characterized by an increase in winter temperatures and a decrease in summer moisture.     

Use of an ion exchange technique to measure copper complexing capacity on the continental shelf of the southeastern United States and in the Sargasso Sea

An ion exchange technique has been used to determine the copper complexing capacity (CuCC) of strong organic complexing agents at 21 stations across the continental shelf of the southeastern United States and in the western Sargasso Sea. The concentration of dissolved organic carbon (DOC) and total particulate materal (TPM), two pools of potential complexing agents, was also measured at each station. The CuCC ranged from 0.014 to 1.681 μM Cu dm⁻³ on the inner shelf, from 0.043 to 0.095 μM Cu dm⁻³ in mid and outer shelf waters, and from < 0.010 to 0.036 μM Cu dm⁻³ at the Sargasso Sea stations. The correlation between CuCC and both DOC and TPM is highly significant (α < 0.01). Two synoptic surveys of the distribution of DOC and TPM across the shelf showed that DOC ranges from > 3 mg C dm⁻³ nearshore to <1 mg C dm⁻³ offshore and that TPM ranges from > 50 mg dm⁻³ nearshore to <1 mg dm⁻³ offshore. Both TPM and DOC are most variable on the inner shelf. These data are consistent with CuCC data which indicate that the CuCC of inner shelf waters was relatively high and very heterogeneous. In contrast, DOC, TPM and copper complexing capacity are low and nearly invariant at the Sargasso Sea stations. We present a model of the distribution of complexing agents in different marine environments and hypothesize that the mechanisms underlying differences between environments relate to differences in the source(s) and nature of complexing agents in each system.