Transport of elemental mercury in the unsaturated zone from a waste disposal site in an arid region

Mercury contained in buried landfill waste may be released via upward emission to the atmosphere or downward leaching to groundwater. Data from the US Geological Survey’s Amargosa Desert Research Site (ADRS) in arid southwestern Nevada reveal another potential pathway of Hg release: long-distance (10² m) lateral migration of elemental Hg (Hg⁰) through the unsaturated zone. Gas collected from multiple depths from two instrumented boreholes that sample the entire 110-m unsaturated zone thickness and are located 100 and 160 m away from the closest waste burial trench exhibit gaseous Hg concentrations of up to 33 and 11 ng m⁻³, respectively. The vertical distribution of gaseous Hg in the borehole closest to the disposal site shows distinct subsurface peaks in concentration at depths of 1.5 and 24 m that cannot be explained by radial diffusive transport through a heterogeneous layered unsaturated zone. The inability of current models to explain gaseous Hg distribution at the ADRS highlights the need to advance the understanding of gas-phase contaminant transport in unsaturated zones to attain a comprehensive model of landfill Hg release.     

Splintered networks: The colonial and contemporary waters of Jakarta

This paper queries the relevance of the ‘splintering urbanism’ thesis to postcolonial cities of the South, and responds to calls for the production of a decentered theory of urbanization through a case study of Jakarta. Drawing on archival and interview data, the paper demonstrates that Jakarta has, since its inception, been characterized by a high degree of differentiation of access to water supply, and of fragmentation of water supply networks. We document the origins of this fragmentation in the colonial era, and trace the legacy of the colonial constructions within the postcolonial city. Moreover, we demonstrate that the introduction of private sector management (in 1988) has not significantly disrupted, and certainly not caused, this pattern. In short, we provide evidence to support our claim that Jakarta’s water supply system is ‘splintered’ rather than ‘splintering’, and demonstrate that this phenomenon was not caused by the rise (or fall) of the ‘modern infrastructural ideal’. In order to explain this sustained fragmentation of infrastructure and access, the paper develops a conceptual framework of postcolonial governmentality that emphasizes the interrelationship between materiality, governmentality, identity, and urbanization, in particular through demonstrating how contested and evolving process of social differentiation are linked to the differentiation of water supply infrastructures and of urban spaces. Although we are wary of any simplistic comparisons between the colonial past and present, we argue that the optic of postcolonial governmentality provides a powerful lens for dissecting the power relations that continue to structure access to water supply and urban space in cities in the South.     

Water availability and land subsidence in the Central Valley,California, USA

The Central Valley in California (USA) covers about 52,000 km² and is one of the most productive agricultural regions in the world. This agriculture relies heavily on surface-water diversions and groundwater pumpage to meet irrigation water demand. Because the valley is semi-arid and surface-water availability varies substantially, agriculture relies heavily on local groundwater. In the southern two thirds of the valley, the San Joaquin Valley, historic and recent groundwater pumpage has caused significant and extensive drawdowns, aquifer-system compaction and subsidence. During recent drought periods (2007–2009 and 2012-present), groundwater pumping has increased owing to a combination of decreased surface-water availability and land-use changes. Declining groundwater levels, approaching or surpassing historical low levels, have caused accelerated and renewed compaction and subsidence that likely is mostly permanent. The subsidence has caused operational, maintenance, and construction-design problems for water-delivery and flood-control canals in the San Joaquin Valley. Planning for the effects of continued subsidence in the area is important for water agencies. As land use, managed aquifer recharge, and surface-water availability continue to vary, long-term groundwater-level and subsidence monitoring and modelling are critical to understanding the dynamics of historical and continued groundwater use resulting in additional water-level and groundwater storage declines, and associated subsidence. Modeling tools such as the Central Valley Hydrologic Model, can be used in the evaluation of management strategies to mitigate adverse impacts due to subsidence while also optimizing water availability. This knowledge will be critical for successful implementation of recent legislation aimed toward sustainable groundwater use.     

Late Holocene Environmental Reconstructions from Lake Solai,Kenya

Playa lake systems tend to be overlooked archives of paleoenvironmental change due to the likelihood of a short and intermittent record of deposition. Groundwater-fed wetlands associated with these climate-sensitive playas, however, preserve changes in hydrologic budget and are thus valuable archives for semiarid regions. This study examines the paleoecological record of a groundwater-fed wetland from Lake Solai, Kenya. Biological proxies are used to reconstruct paleoenvironmental change and climate impacts over the past millennium. Dry conditions persisted between CE 1115 and 1490, followed by wetter conditions during the Little Ice Age. Near surface sediments indicate increasing anthropogenic impact through pastoralism.     

Use of an ion exchange technique to measure copper complexing capacity on the continental shelf of the southeastern United States and in the Sargasso Sea

An ion exchange technique has been used to determine the copper complexing capacity (CuCC) of strong organic complexing agents at 21 stations across the continental shelf of the southeastern United States and in the western Sargasso Sea. The concentration of dissolved organic carbon (DOC) and total particulate materal (TPM), two pools of potential complexing agents, was also measured at each station. The CuCC ranged from 0.014 to 1.681 μM Cu dm⁻³ on the inner shelf, from 0.043 to 0.095 μM Cu dm⁻³ in mid and outer shelf waters, and from < 0.010 to 0.036 μM Cu dm⁻³ at the Sargasso Sea stations. The correlation between CuCC and both DOC and TPM is highly significant (α < 0.01). Two synoptic surveys of the distribution of DOC and TPM across the shelf showed that DOC ranges from > 3 mg C dm⁻³ nearshore to <1 mg C dm⁻³ offshore and that TPM ranges from > 50 mg dm⁻³ nearshore to <1 mg dm⁻³ offshore. Both TPM and DOC are most variable on the inner shelf. These data are consistent with CuCC data which indicate that the CuCC of inner shelf waters was relatively high and very heterogeneous. In contrast, DOC, TPM and copper complexing capacity are low and nearly invariant at the Sargasso Sea stations. We present a model of the distribution of complexing agents in different marine environments and hypothesize that the mechanisms underlying differences between environments relate to differences in the source(s) and nature of complexing agents in each system.     

Marine protected areas in Puerto Rico: Historical and current perspectives

In Puerto Rico, the environmental legislation for establishing marine protected areas (MPAs) is complex due to its current political position with the United States (US) as not only local but also federal US laws affect designations. Historically, during the Spanish rule, mangrove forests were protected for extractive reasons (i.e., charcoal) and the first protected area was established by 1918 as an Insular Forest. Currently, of the 37 MPAs recognized and investigated in this work, the vast majority (73%) are Natural Reserves, followed by Commonwealth Forests (13.5%). Most MPAs in Puerto Rico were implemented using a top-down approach (i.e., government) which follows US federal guidelines for protecting endangered species, critical habitats, and natural and cultural resources. The development of management plans for MPAs on the island is increasingly adopting a public participatory process. However, this latter process is new for the government of Puerto Rico that has not incorporated a policy based on an Integrated Coastal Management.     

Climate change, reproductive performance and diet composition of marine birds in the southern California Current system, 1969–1997

We studied the effects of low-frequency climate change on the reproductive performance of 11 species of marine bird in the southern California Current system, 1969–1997. Reproductive performance of Brown Pelican (Pelecanus occidentalis) and Double-crested Cormorant (Phalacrocrax auritus) in southern California demonstrated an increase in the 1970s and early 1980s, attributable to recovery from organochlorine contamination (primarily DDE). Brandt's Cormorant (Phalacrocorax penicillatus) in central California was the only species to demonstrate a secular increase in performance through time, a pattern that remains unexplained. Ashy Storm-petrel (Oceanodroma homochroa) and Pelagic Cormorant (Phalacrocorax pelagicus) demonstrated curvilinear patterns of change, with decreasing reproductive performance in the past decade. All other species including Western Gull (Larus occidentalis), Pigeon Guillemot (Cepphus columba), Xantus's Murrelet (Synthiloboramphus hypoleucus), Common Murre (Uria aalge), Cassin's Auklet (Ptychoramphus aleuticus) and Rhinoceros Auklet (Cerorhinca monocerata) showed diminishing reproductive performance through time. Patterns of change for the murre and auklets were not significant, presumably because of a lack of reproductive variation for these species, which display a conservative breeding effort (i.e. single-egg clutches). Changes in the birds' abilities to provision young and maintain chick survival during May–July each year appeared most closely related to overall changes in reproductive performance. Dietary change indicated a decline in use of juvenile rockfish (Sebastes spp.) by marine birds in central California. There was also significant interannual variability in consumption of juvenile rockfish and the euphausiid Thysanoessa spinifera. Patterns of change in marine bird reproductive performance were generally concordant between southern and central California after considering the period of recovery for Brown Pelican and Double-crested Cormorant. The decline in reproductive performance and changes in diet composition do not appear directly related to the polarity reversal of the Pacific Decadal Oscillation in 1976/1977. Instead, reproductive performance and dietary characteristics indicate substantial change in the late 1980s, suggesting another regime-shift at that time.