Disproportionation of Fe<Superscript>2+</Superscript> in Al-free silicate perovskite in the laser heated diamond anvil cell as recorded by electron probe microanalysis of oxygen

Experimental evidence is reported for Fe²⁺ disproportionation in Al-free perovskite (Pv), when submitted to large temperature gradients (i.e., under off-equilibrium conditions) in a laser heated diamond anvil cell (LHDAC). To enable this effect, the experimental procedure was designed to produce large radial and axial temperature gradients. In the Pv and ferropericlase (Fp) assemblage synthesized after dissociation of natural olivine, the three chemical states of iron (i.e., Fe⁰, Fe²⁺ and Fe³⁺) could be evidenced by electron probe microanalysis (EPMA), through variations of oxygen contents attached to the Fe cations. Despite inherent difficulties for determination of O-contents and Fe³⁺/ΣFe ratios using EPMA, we recorded significant changes in iron oxidation state across the laser-heated strip. These changes are correlated with variations in composition for the major elements (Fe, Mg, and Si), which evidences that the Pv/Fp assemblage experienced large segregation under the strong temperature gradients. Grains of metallic iron were detected in parts of the laser-heated strip coexisting with a Pv phase with Fe/(Mg + Fe) = 6 at% and most of its iron as Fe³⁺. This Fe²⁺-disproportionation reaction involves insertion of Fe³⁺-defects in the Pv lattice. This Fe³⁺-bearing Pv phase is presumably unstable and decomposes into a mineral assemblage including magnesioferrite, which is detected at the border of the laser-heated strip.     

Fluid-pressure controlled soft-bed deformation sequence beneath the surging Breiðamerkurjökull (Iceland, Little Ice Age)

The general subject of this paper is subglacial deformation beneath Breiðamerkurjökull, a surging Icelandic glacier. More specifically it discusses the evolution and the role of fluid pressure on the behaviour of subglacial sediments during deformation. During Little Ice Age maximum, the two outcrops studied, North Jökulsarlon (N-Jk) and Brennhola-Alda (BA), were located at 2550 m and 550 m respectively from the front of the Breiðamerkurjökull. Sedimentological analysis at the forefield of the glacier shows thick, coarse glaciofluvial deposits interbedded with thin, fine-grained shallow lacustrine/swamp deposits, overlain by a deformed till unit at N-Jk. BA outcrop shows fine-grained shallow lacustrine/swamp deposits overlain by a deformed till unit. The sequence of deformation events from one outcrop to the other is similar. First, major thrust planes, which were rooted in shallow lacustrine/swamp deposits developed by glacially induced simple shear. Next, the thrusts were folded, indicating the deformation of hydroplastic sediment assisted by moderate fluid pressure. Then clastic dyke swarms crosscut the sedimentary succession, proving that fluid overpressure caused hydrofracturing associated with fluidisation. Finally, as water escaped from the glacier bed, fluid pressure dropped, and normal faulting occurred in brittle-state subglacial sediments. Fluid-pressure variations are related to glacier dynamics. They control the deformation sequence by modifying subglacial rheological behaviour and the nature of the subglacial tectonism.     

Micromega/IR: Design and status of a near-infrared spectral microscope for in situ analysis of Mars samples

MicrOmega is an ultra miniaturized spectral microscope for in situ analysis of samples. It is composed of 2 microscopes; one with a spatial sampling less or equal to 4 μm, working in 4 colors in the visible range: MicrOmega/VIS, and a NIR hyperspectral microscope working in the spectral range 0.9–4 μm with a spatial sampling of 20 μm per pixel: MicrOmega/IR (described in this paper). MicrOmega/IR illuminates and images samples a few mm in size and acquires the NIR spectrum of each resolved pixel in up to 320 contiguous spectral channels. The goal of this instrument is to analyze in situ the composition of collected samples at almost their grain size scale, in a non-destructive way. With the chosen spectral range and resolution, a wide variety of constituents can be identified: minerals, such as pyroxene and olivine, ferric oxides, hydrated phyllosilicates, sulfates and carbonates and ices and organics. The composition of the various phases within a given sample is a critical record of its formation and evolution. Coupled to the mapping information, it provides unique clues to describe the history of the parent body (planet, satellite and small body). In particular, the capability to identify hydrated grains and to characterize their adjacent phases has a huge potential in the search for possible bio-relics.     

The formation of the Baptistina family by catastrophic disruption: Porous versus non‐porous parent body

Abstract— In this paper, we present numerical simulations aimed at reproducing the Baptistina family based on its properties estimated by observations. A previous study by Bottke et al. (2007) indicated that this family is probably at the origin of the K/T impactor, is linked to the CM meteorites and was produced by the disruption of a parent body 170 km in size due to the head‐on impact of a projectile 60 km in size at 3 km s^?1. This estimate was based on simulations of fragmentation of non‐porous materials, while the family was assumed to be of C taxonomic type, which is generally interpreted as being formed from a porous body. Using both a model of fragmentation of non‐porous materials, and a model that we developed recently for porous ones, we performed numerical simulations of disruptions aimed at reproducing this family and at analyzing the differences in the outcome between those two models. Our results show that a reasonable match to the estimated size distribution of the real family is produced from the disruption of a porous parent body by the head‐on impact of a projectile 54 km in size at 3 km s^?1. Thus, our simulations with a model consistent with the assumed dark type of the family requires a smaller projectile than previously estimated, but the difference remains small enough to not affect the proposed scenario of this family history. We then find that the break‐up of a porous body leads to different outcomes than the disruption of a non‐porous one. The real properties of the Baptistina family still contain large uncertainties, and it remains possible that its formation did not involve the proposed impact conditions. However, the simulations presented here already show some range of outcomes and once the real properties are better constrained, it will be easy to check whether one of them provides a good match.     

Numerical simulations of impacts involving porous bodies: II. Comparison with laboratory experiments

In this paper, we compare the outcome of high-velocity impact experiments on porous targets, composed of pumice, with the results of simulations by a 3D SPH hydrocode in which a porosity model has been implemented. The different populations of small bodies of our Solar System are believed to be composed, at least partially, of objects with a high degree of porosity. To describe the fragmentation of such porous objects, a different model is needed than that used for non-porous bodies. In the case of porous bodies, the impact process is not only driven by the presence of cracks which propagate when a stress threshold is reached, it is also influenced by the crushing of pores and compaction. Such processes can greatly affect the whole body's response to an impact. Therefore, another physical model is necessary to improve our understanding of the collisional process involving porous bodies. Such a model has been developed recently and introduced successfully in a 3D SPH hydrocode [Jutzi, M., Benz, W., Michel, P., 2008. Icarus 198, 242-255]. Basic tests have been performed which already showed that it is implemented in a consistent way and that theoretical solutions are well reproduced. However, its full validation requires that it is also capable of reproducing the results of real laboratory impact experiments. Here we present simulations of laboratory experiments on pumice targets for which several of the main material properties have been measured. We show that using the measured material properties and keeping the remaining free parameters fixed, our numerical model is able to reproduce the outcome of these experiments carried out under different impact conditions. This first complete validation of our model, which will be tested for other porous materials in the future, allows us to start addressing problems at larger scale related to small bodies of our Solar System, such as collisions in the Kuiper Belt or the formation of a family by the disruption of a porous parent body in the main asteroid belt.     

The World Karst Aquifer Mapping project: concept,mapping procedure and map of Europe

Karst aquifers contribute substantially to freshwater supplies in many regions of the world, but are vulnerable to contamination and difficult to manage because of their unique hydrogeological characteristics. Many karst systems are hydraulically connected over wide areas and require transboundary exploration, protection and management. In order to obtain a better global overview of karst aquifers, to create a basis for sustainable international water-resources management, and to increase the awareness in the public and among decision makers, the World Karst Aquifer Mapping (WOKAM) project was established. The goal is to create a world map and database of karst aquifers, as a further development of earlier maps. This paper presents the basic concepts and the detailed mapping procedure, using France as an example to illustrate the step-by-step workflow, which includes generalization, differentiation of continuous and discontinuous carbonate and evaporite rock areas, and the identification of non-exposed karst aquifers. The map also shows selected caves and karst springs, which are collected in an associated global database. The draft karst aquifer map of Europe shows that 21.6% of the European land surface is characterized by the presence of (continuous or discontinuous) carbonate rocks; about 13.8% of the land surface is carbonate rock outcrop.

     

The early Cretaceous orogen-scale Dabieshan metamorphic core complex: implications for extensional collapse of the Triassic HP–UHP orogenic belt in east-central China

International Journal of Earth Sciences - The Dabieshan massif is famous as a portion of the world’s largest HP–UHP metamorphic belt in east-central China that was built by the Triassic...     

The zircon evidence of temporally changing sediment transport—the NW Gondwana margin during Cambrian to Devonian time (Aoucert and Smara areas,Moroccan Sahara)

International Journal of Earth Sciences - Detrital zircon provenance studies are an established tool to develop palaeogeographic models, mostly based on zircon of siliciclastic rocks and isotope...     

Effects of thermal energy storage on shallow aerobic aquifer systems: temporary increase in abundance and activity of sulfate-reducing and sulfur-oxidizing bacteria

Aquifer thermal energy storage may result in increases in the groundwater temperature up to 70 °C and more. This may lead to geochemical and microbiological alterations in the aquifer. To study the temperature effects on the indigenous microbial community composition, sediment column experiments at four different temperatures were carried out and the effluents were characterized geochemically and microbiologically. After an equilibrium phase at groundwater temperature of 10 °C for 136 days, one column was kept at 10 °C as a reference and the others were heated to 25, 40 and 70 °C. Genetic fingerprinting and quantitative PCR revealed a change in the bacterial community composition and abundance due to the temperature increase. While at 25 °C only slight changes in geochemical composition and gene copy numbers for bacteria were observed, increasing concentrations of total organic carbon in the 40 °C column were followed by a strong increase in bacterial abundance. Thermophilic bacteria became dominant at 70 °C. Temporary sulfate reduction took place at 40 and 70 °C and this correlated with an increased abundance of sulfate-reducing bacteria (SRB). Furthermore, a coexistence of SRB and sulfur-oxidizing bacteria (SOB) at all temperatures indicated an interaction of these physiological groups in the sediments. The results show that increased temperatures led to significant shifts in the microbial community composition due to the altered availability of electron donors and acceptors. The interplay of SRB and SOB in sedimentary biofilms facilitated closed sulfur cycling and diminished harmful sulfur species.     

Experimental and numerical evaluation of single-layer covers placed on acid-generating tailings

This study focuses on the reclamation work being performed on two former acid-generating tailings sites, located in Quebec, Canada. At both sites, the tailings were partially oxidized due to extended exposure, and the pore water is acidic. The reclamation solution applied to control acid mine drainage is a monolayer cover, made of non acid-generating tailings in one case and a till in the other. The goal of this project was to assess the response of the tailings-cover systems under various conditions. Tailings samples were collected in situ and characterized in the laboratory. Large column tests were conducted to evaluate the hydrogeological and geochemical behaviour of the covered tailings following wetting and drying cycles. The instrumented columns were designed to reproduce some of the existing site conditions and provide representative results for longer term analyses. Volumetric water content, suction, and oxygen concentrations were also monitored over time. The experimental data were used to validate different numerical models including those constructed with Vadose/W (GeoSlope Int.). Additional simulations were conducted under field conditions to evaluate the effect of various influence factors such as the depth of the water table, climatic conditions and the thickness of the cover. The combination of experimental and numerical results show how the behaviour and efficiency of a monolayer cover placed over reactive tailings depend on these factors, highlighting the importance of hydrogeological properties and water table depth. In many instances, the cover materials were prone to desaturation, especially when the water table was deeper than about 2 m below the tailings-cover interface. These results tend to indicate that relatively thin monolayer covers would not be able to prevent oxygen ingress under some of the conditions observed in the field. Desaturation of the cover and/or reactive tailings is due to a combination of drainage and evaporation. In such cases, increasing the thickness of the monolayer cover only has a limited effect. A discussion follows on the practical implications of these laboratory experiments and the numerical simulations for field design of reclamation measures at these two tailings impoundments.