Spatio-temporal changes in totally and enzymatically hydrolyzable amino acids of superficial sediments from three contrasted areas

Spatio-temporal changes in totally and enzymatically hydrolyzable amino acids (THAA and EHHA) and EHAA/THAA ratios of superficial sediments were assessed during 1997-1999 in three areas (i.e., the Gulf of Lions, the Bay of Biscay, and Central Chile) differing in their primary productivity. In all three areas, and even off Central Chile where a strong El Niño event took place during 1997-1998, spatial changes were always much greater than temporal ones. The factors affecting the spatial distributions of amino acid concentrations differed among areas. In the Gulf of Lions, sediment granulometry was apparently the most important driving force of THAA, EHAA, and EHAA/THAA, and there was no marked difference between stations located on the open slope and those in submarine canyons. Conversely, in the Bay of Biscay, there were clear differences between the stations located off Cap-Breton, on the open slope, and those in the Cap-Ferret canyon; the latter two featuring lower EHAA and THAA but higher EHAA/THAA. This pattern is likely to result from the predominance of different sources of organic matter and especially from the importance of continental inputs to the Cap-Breton canyon. Off Central Chile, amino acid concentrations and ratios were both maximal around 100 m depth, probably reflecting the interaction between the primary productivity gradient and the presence of an oxygen minimum zone (OMZ) reducing the degradation of sedimentary organics. When comparing the average values collected in the three areas studied, THAA and EHAA were highest in Central Chile, intermediate in the Bay of Biscay and lowest in the Gulf of Lions. EHAA/THAA ratios were also highest in Central Chile but were lowest in the Bay of Biscay. Differences between the Gulf of Lions and the Bay of Biscay could have been affected by sampling design. In Central Chile, the use of labile organic carbon to total organic carbon (C-LOM/TOC) and EHAA/THAA as indices of organic matter lability led to very similar results. This was not the case in the Bay of Biscay. It is therefore argued that the use of C-LOM/TOC should be restricted to highly productive areas.     

Linear theory of rotating fluids using spherical harmonics part I: Steady flows

Abstract

It is shown that a systematic development of physical quantities using spherical harmonics provides analytical solutions to a whole class of linear problems of rotating fluids.

These solutions are regular throughout the whole domain of the fluid and are not much affected by the equatorial singularity of steady boundary layers in spherical geometries.

A comparison between this method and the one based on boundary layer theory is carried out in the case of the steady spin-up of a fluid inside a sphere.     

Carbon and suspended sediment transport in an impounded alpine river (Isère,France)

Carbon and total suspended sediment (TSS) loads were investigated from April 2006 to March 2008 in the mountainous watershed of the Isère River, French Alps (5570 km²). The river bed has been highly impounded for hydroelectricity production during the last century. Hydraulic flushes are managed every year to prevent TSS storage within upstream dams. The Isère River has been instrumented for high‐frequency monitoring of water, TSS by turbidity and carbon (organic, inorganic, dissolved and particulate) in order to evaluate the impact of natural floods and hydraulic flushes on annual loads. Annual TSS load which was estimated between 1.3 and 2.3 MT y^?1 (i.e. 233 to 413 T km^?2 y^?1) highlighted the high erodibility of the Isère watershed. Annual carbon load was estimated between 173 10³ T y^?1 and 199 10³ T y^?1 (i.e 31 to 36 T km^?2 y^?1). About 80% of the annual carbon loads were inorganic. The impact of hydraulic flushes on annual loads appeared limited (less than 3% for annual TSS load and about 1.5% for annual carbon load), whereas the most important natural flood event contributed to 20% of the annual TSS load and 10% of the annual carbon load. Copyright © 2012 John Wiley & Sons, Ltd.     

River flux uncertainties predicted by hydrological variability and riverine material behaviour

Data on riverine fluxes are essential for calculating element cycles (carbon, nutrients, pollutants) and erosion rates from regional to global scales. At most water‐quality stations throughout the world, riverine fluxes are calculated from continuous flow data (q) and discrete concentration data (C), the latter being the main cause of sometimes large uncertainties. This article offers a comprehensive approach for predicting the magnitude of these uncertainties for water‐quality stations in medium to large basins (drainage basin area > 1000 km²) based on the commonly used discharge‐weighted method. Uncertainty levels – biases and imprecisions – for sampling intervals of 3 to 60 days are correlated first through a nomograph with a flux variability indicator, the quantity of riverine material discharged in 2% of time (M_2%). In turn, M_2% is estimated from the combination of a hydrological reactivity index, W_2% (the cumulative flow volume discharged during the upper 2% of highest daily flow) and the truncated b_50sup exponent, quantifying the concentration versus discharge relationship for the upper half of flow values (C = a q ^b50sup, for q > q₅₀, where q₅₀ is the median flow): M_2% = W_2% + 27.6b_50sup. W_2% can be calculated from continuous flow measurements, and the b_50sup indicator can be calculated from infrequent sampling, which makes it possible to predict a priori the level of uncertainty at any station, for any type of riverine material either concentrated (b_50sup > 0) or diluted (b_50sup > 0) with flow. A large data base of daily surveys, 125 station variables of suspended particulate matter (SPM), total dissolved solids (TDS) and dissolved and particulate nutrients, was used to determine uncertainties from simulated discrete surveys and to establish relationships between indicators. Results show, for example, that for the same relatively reactive basin (W_2% > 25%), calculated fluxes from monthly sampling would yield uncertainties approaching ±100% for SPM (b_50sup > 1.4) fluxes and ±10% for TDS (b_50sup = ?0.2). The application to the nitrate survey of the river Seine shows significant trends for the 1972–2009 records. Copyright © 2012 John Wiley & Sons, Ltd.     

Orbital imprint on Holocene palaeohydrological variations in west‐central Europe as reflected by lake‐level changes at Cerin (Jura Mountains,eastern France)

This paper presents a lake‐level record for the Holocene at Lake Cerin (Jura Mountains, eastern France). It is based on a range of sedimentological techniques validated in previous studies, with a combination of systematic lithostratigraphic investigations of the infillings accumulated in the lacustrine basin, and sediment analyses of two selected cores. The chronology is based on 10 radiocarbon dates and pollen stratigraphy. On a millennial scale, the Cerin lake‐level record shows three distinct successive phases characterised by higher lake‐level conditions until ca. 9000 cal. a BP, followed by a maximal lowering at ca. 9000–8500 cal. a BP, and a progressive rise until the present. This rise was punctuated by centennial‐scale fluctuations, with major events around 4000, 2800 and after 1500 cal. a BP. Considered on a multimillennial scale, the general pattern of palaeohydrological changes reconstructed at Cerin reflects the impact of orbitally driven summer insolation. This is in agreement with other regional and extra‐regional palaeoclimatic records, although every record shows peculiarities in timing and shape depending on the proxy used for reconstruction. In this general context, centennial to multicentennial oscillations appear to have been second‐order events in comparison with the major influence of the orbital factor. Copyright © 2011 John Wiley & Sons, Ltd.     

Holocene glacier and deep water dynamics,Adélie Land region,East Antarctica

This study presents a high-resolution multi-proxy investigation of sediment core MD03-2601 and documents major glacier oscillations and deep water activity during the Holocene in the Adélie Land region, East Antarctica. A comparison with surface ocean conditions reveals synchronous changes of glaciers, sea ice and deep water formation at Milankovitch and sub-Milankovitch time scales. We report (1) a deglaciation of the Adélie Land continental shelf from 11 to 8.5 cal ka BP, which occurred in two phases of effective glacier grounding-line retreat at 10.6 and 9 cal ka BP, associated with active deep water formation; (2) a rapid glacier and sea ice readvance centred around 7.7 cal ka BP; and (3) five rapid expansions of the glacier–sea ice systems, during the Mid to Late Holocene, associated to a long-term increase of deep water formation. At Milankovich time scales, we show that the precessionnal component of insolation at high and low latitudes explains the major trend of the glacier–sea ice–ocean system throughout the Holocene, in the Adélie Land region. In addition, the orbitally-forced seasonality seems to control the coastal deep water formation via the sea ice–ocean coupling, which could lead to opposite patterns between north and south high latitudes during the Mid to Late Holocene. At sub-Milankovitch time scales, there are eight events of glacier–sea ice retreat and expansion that occurred during atmospheric cooling events over East Antarctica. Comparisons of our results with other peri-Antarctic records and model simulations from high southern latitudes may suggest that our interpretation on glacier–sea ice–ocean interactions and their Holocene evolutions reflect a more global Antarctic Holocene pattern.     

Quantifying groundwater–surface water interactions in a proglacial valley,Cordillera Blanca,Peru

A myriad of downstream communities and industries rely on streams fed by both groundwater discharge and glacier meltwater draining the Cordillera Blanca, Northern Peruvian Andes, which contains the highest density of glaciers in the tropics. During the dry season, approximately half the discharge in the region's proglacial streams comes from groundwater. However, because of the remote and difficult access to the region, there are few field methods that are effective at the reach scale to identify the spatial distribution of groundwater discharge. An energy balance model, Rhodamine WT dye tracing, and high‐definition kite‐borne imagery were used to determine gross and net groundwater inputs to a 4‐km reach of the Quilcay River in Huascaran National Park, Peru. The HFLUX computer programme ( http://hydrology.syr.edu/hflux.html ) was used to simulate the Quilcay River's energy balance using stream temperature observations, meteorological measurements, and kite‐borne areal photography. Inference from the model indicates 29% of stream discharge at the reach outlet was contributed by groundwater discharge over the study section. Rhodamine WT dye tracing results, coupled with the energy balance, show that approximately 49% of stream water is exchanged (no net gain) with the subsurface as gross gains and losses. The results suggest that gross gains from groundwater are largest in a moraine subreach but because of large gross losses, net gains are larger in the meadow subreaches. These insights into pathways of groundwater–surface water interaction can be applied to improve hydrological modelling in proglacial catchments throughout South America. Copyright © 2016 John Wiley & Sons, Ltd.