Bulk sediment properties interpreted in light of qualitative and quantitative microfabric analysis

Sediments from Eckernförde Bay, Germany, are characterized by an aggregate and channel microstructure, with channel dimensions about two orders of magnitude larger than interparticle distances within aggregates. Porosity within aggregates as determined by image analysis of transmission electron micrographs was about 12% less than bulk porosity. Illite and smectite formed the bulk of most aggregates, while numerous biogenic particles generally occurred outside or on the periphery of aggregates. Microfabric analysis provides insights into permeability and consolidometer behavior of this sediment, reveals characteristics not apparent from bulk analyses, and may have implications for geochemistry and physical behavior of the sediment.     

DIAS—a novel technique for measuring in situ shear modulus

DIAS (duomorph in situ acquisition system) is an alternate technology requiring a single duomorph probe for measuring shear modulus in situ. The duomorph probe is a bending plate device that is vibrated and the resulting deflections measured using strain gauges. The ratio between the unconstrained bending of the duomorph in air and the constrained bending in sediment is a function of the sediment dynamic modulus from which shear modulus is calculated. This paper describes the theory underlying the DIAS system, the design of the system, the data reduction methods, and results from the initial deployment of the prototype system in Eckernförde Bay.     

Contourite drift construction influenced by capture of Mediterranean Outflow Water deep-sea current by the Portimão submarine canyon (Gulf of Cadiz, South Portugal)

The margin of the Gulf of Cadiz is swept by the deep current formed by the Mediterranean Outflow Water (MOW) flowing from the Mediterranean to the Atlantic. On the northern margin of the Gulf (Algarve Margin, South Portugal), the MOW intensity is low and fine-grained contourite drifts are built up with an alongslope development. From new sedimentological data, this study emphasizes the presence of two types of contourite drifts separated only by a deep submarine canyon incising the slope with a north-south orientation (Portimão Canyon). High-resolution seismic and bathymetry interpretation shows that on the eastern side of the canyon, the MOW forms a thick and large detached drift (Albufeira Drift) prograding toward both north and west, as shown in seismic profiles, with a high sedimentation rate. On this side of the canyon, the MOW intensity is high enough to erode the slope forming a moat channel (Alvarez Cabral). On the western side of Portimão Canyon, the MOW energy is lower, preventing moat channel erosion. Only flat and thin drift develops (Portimão and Lagos Drifts) with slow aggradation and a low sedimentation rate. This difference in drift development is due to the presence of the canyon which generates an important change in hydrodynamic of the MOW, confirmed by temperature-density measurements showing that MOW flows down Portimão Canyon. The canyon is responsible for the deviation of the direction of the MOW as it partly catches the deep-sea current flowing westward (i.e. capture phenomenon). It creates, thus, a decrease of the flow energy, competency and capacity between the east and west sides of the canyon. Through this phenomenon of MOW deep-sea current capture, the canyon constitutes a morphologic feature generating an important change in the contourite deposition pattern.In addition to already known climatic and oceanographic influences, our results show the role of canyons on contourite drift building. This study provides new elements on autocyclic factors influencing the contourite sedimentation, which are important to consider in future sedimentary paleo-reconstruction interpretations.     

Motion of blocks on the surface of Phobos: New constraints for the formation of grooves

Although grooves are common on asteroids, on Phobos the grooves have been the subject of various formation hypotheses for two reasons: the fact that Phobos is orbiting around Mars close to the Roche limit, implies an unusual gravity environment as well as the presence of the huge crater impact, Stickney, which seems to be related at least to a family of grooves. Among many hypotheses, it has been suggested that the grooves could have been dug by rolling Stickney ejecta, but this hypothesis was questioned using two main arguments: no block was observed at the end of the grooves, nor do they run downslope. Thus, the study of surface and near surface dynamics on Phobos can clarify the soundness of these controversial arguments.The present study explores this idea by computing the trajectory of a test mass gliding on the surface of Phobos for any initial position and velocity. An ellipsoidal model of Phobos is used for both the gravity and surface geometry, and several orbiting distances from Mars are considered. It is shown that, due to the Phobos rotation, the trajectories generally do not run downslope even for velocities as low as ∼1 m/s. In consequence the corresponding argument against the rolling blocks hypothesis is not applicable. This hypothesis, however, is clearly ruled out for the sets of parallel grooves in the polar regions because of the curvature of the computed trajectories. On the contrary the trajectories issued from the rim of Stickney close to the equator, with velocities of a few m/s, show similitude with the corresponding groove patterns, in particular for the east–west asymmetry. In some conditions the trajectories leave the surface, which may account for regions free of grooves and for trails without blocks at the end. Consequently, the rolling block hypothesis cannot be rejected outright until further analysis is carried out. Damping of the motion on the regolith is simulated introducing a solid damping coefficient in the equations. A relatively small but not unrealistic coefficient of ∼0.1 accounts for the length of the long main western hypothetic block trails. The simulations with damping confirm that the trajectories turn downslope only at the very end for velocities ?1 m/s, but valuable comparison with the observations requires a better model.     

Factors controlling stratal pattern and facies distribution of fluvio‐lacustrine sedimentation in the Sivas mini‐basins,Oligocene (Turkey)

The Sivas Basin, located in the Central Anatolian Plateau of Turkey, is a foreland basin that records a complex interaction between sedimentation, salt tectonics and regional shortening during the Oligo‐Miocene leading to the formation of numerous mini‐basins. The Oligocene sedimentary infill of the mini‐basins consists of a thick continental succession, the Karayün Formation, comprising a vertical succession of three main sub‐environments: (i) playa‐lake, (ii) fluvial braided, and (iii) saline lacustrine. These sub‐environments are seen as forming a large Distributive Fluvial System (DFS) modified through time as a function of sediment supply and accommodation related to regional changes in climate and tectonic regime. Within neighbouring mini‐basins and despite a similar vertical stratigraphic succession, subtle variations in facies assemblages and thickness are observed in stratigraphic units of equivalent age, thus demonstrating the local control exerted by halokinesis. Stratigraphic and stratal patterns reveal in great detail the complex interaction between salt tectonics and sedimentation including different types of halokinetic structures such as hooks, wedges and halokinetic folds. The regional variations of accommodation/sediment supply led to coeval changes in the architectural patterns recorded in the mini‐basins. The type of accommodation regime produces several changes in the sedimentary record: (i) a regime dominated by regional accommodation limits the impact of halokinesis, which is recorded as very small variations in stratigraphic thickness and facies distribution within and between mini‐basins; (ii) a regime dominated by localized salt‐induced accommodation linked to the subsidence of each individual mini‐basin enhances the facies heterogeneity within the DFS, causing sharp changes in stratigraphic thickness and facies assemblages within and between mini‐basins.     

Choosing methods for estimating dissolved and particulate riverine fluxes from monthly sampling

Abstract

In discrete water quality surveys, riverine fluxes are associated with unknown uncertainties (biases and imprecisions). Annual flux errors have been determined from the generation of discrete surveys by Monte Carlo sorting for monthly sampling, from 10 years of daily records (120 records). Eight calculation methods were tested for suspended particulate matter, dissolved solids and dissolved and total nutrients in medium to large basins (10³ to 10⁶ km²) covering a wide range of hydrological conditions and riverine biogeochemistry. The performance of each method was analysed first by type of riverine material, which appeared to be much less pertinent than the flux variability matrix. The latter combines the river flow duration in two percent of time (W_2%) and the truncated exponent (b_50sup) defining the relationship of concentration vs discharge (C–Q) at higher flows (C = aQ^b50sup). As flux variability increases (high W_2% and/or high b_50sup), averaging and rating curve methods become less efficient compared to hydrograph separation methods. Flux biases and imprecisions were plotted in the [W_2%, b_50sup] matrix for discrete monthly surveys.

Editor Z. W. Kundzewicz

Citation Raymond, S., Moatar, F., Meybeck, M., and Bustillo, V., 2013. Choosing methods for estimating dissolved and particulate riverine fluxes from monthly sampling. Hydrological Sciences Journal, 58 (6), 1326–1339.     

The Jovian stratosphere in the ultraviolet

The center-of-disk reflectivity of Jupiter in the wavelength range from 1450 to 3150A?has been computed from 30 low-dispersion IUE spectra taken during solar maximum in 1978–1980. A vertically inhomogeneous radiative transfer program is used to compute model reflectivities of various stratospheric compositions for comparison. Ammonia and acetylene are well determined because they show narrow absorption bands in the ultraviolet. Above 1800A?, these two gases provide a good fit to the data, but not below. At shorter wavelengths the fit would be much improved by a small amount (5–15 ppb) of propadiene/allene (C₃H₄). Voyager IRIS spectra show that the IR bands of allene are not strong enough to be detected in such a small amount. Additional absorption around 1600A?can be reproduced best with the presence of cyclopropane (C₃H₆, <15ppb), although other absorbers (e.g., hydrocarbon molecules with more than three carbon atoms, oxygen- or nitrogen-containing molecules, or a high-attitude haze) could also explain the spectrum in this region. The data are too noisy to detect possible CO Cameron band absorption near 2000A?.     

A chlorite solid solution geothermometer the Los Azufres (Mexico) geothermal system

Chlorite constitutes a major hydrothermal alteration product of metamorphism of andesites, in the active geothermal system of Los Azufres (Mexico). Electron microprobe analyses performed on a set of crystals from each sample show wide variations in composition. Correlation coefficients among chemical constituents were calculated. It is shown that the tetrahedral charge is positively correlated with the octahedral vacancy and negatively with the iron content, and there is almost no correlation with the octahedral aluminium and magnesium content. A procedure is proposed to select end-members and substitution vectors, and to give a general formula for these chlorites.Their formation temperatures are estimated with great accuracy, combining results of microthermometric data on fluid inclusions from gangue minerals of chlorites (quartz, calcite), direct measurements in wells (Kuster equipment), and chemical geothermometers. Correlations between chlorite compositions, range and nature of site occupancy, and temperature are good. Formation temperatures of chlorites range from 130° C to 300° C. As no other thermodynamic parameter varies significantly in the studied field (composition of the host rocks, nature of the geothermal fluids, pressure, ...), these variations of site occupancy (mainly Al(IV) and the octahedral occupancy (6-Al(VI)-(Mg+Fe(2+)) = VAC) are considered mainly as temperature dependent.Molar fractions of each end-member show very different variations with increasing temperature: X-kaolinite decreases, and X-chamosite increases, while X-talc-3 brucite does not show significant change. From these data, activity coefficients and standard state chemical potential of major components, and molar free energy formation of chlorite have been calculated for each temperature of crystallisation.     

The formation of the Baptistina family by catastrophic disruption: Porous versus non‐porous parent body

Abstract— In this paper, we present numerical simulations aimed at reproducing the Baptistina family based on its properties estimated by observations. A previous study by Bottke et al. (2007) indicated that this family is probably at the origin of the K/T impactor, is linked to the CM meteorites and was produced by the disruption of a parent body 170 km in size due to the head‐on impact of a projectile 60 km in size at 3 km s^?1. This estimate was based on simulations of fragmentation of non‐porous materials, while the family was assumed to be of C taxonomic type, which is generally interpreted as being formed from a porous body. Using both a model of fragmentation of non‐porous materials, and a model that we developed recently for porous ones, we performed numerical simulations of disruptions aimed at reproducing this family and at analyzing the differences in the outcome between those two models. Our results show that a reasonable match to the estimated size distribution of the real family is produced from the disruption of a porous parent body by the head‐on impact of a projectile 54 km in size at 3 km s^?1. Thus, our simulations with a model consistent with the assumed dark type of the family requires a smaller projectile than previously estimated, but the difference remains small enough to not affect the proposed scenario of this family history. We then find that the break‐up of a porous body leads to different outcomes than the disruption of a non‐porous one. The real properties of the Baptistina family still contain large uncertainties, and it remains possible that its formation did not involve the proposed impact conditions. However, the simulations presented here already show some range of outcomes and once the real properties are better constrained, it will be easy to check whether one of them provides a good match.