Residence times in river basins as determined by analysis of long-term tritium records

The US Geological Survey has maintained a network of stations to collect samples for the measurement of tritium concentrations in precipitation and streamflow since the early 1960s. Tritium data from outflow waters of river basins draining 4500–75000 km² are used to determine average residence times of water within the basins. The basins studied are the Colorado River above Cisco, Utah; the Kissimmee River above Lake Okeechobee, Florida; the Mississippi River above Anoka, Minnesota; the Neuse River above Streets Ferry Bridge near Vanceboro, North Carolina; the Potomac River above Point of Rocks, Maryland; the Sacramento River above Sacramento, California; the Susquehanna River above Harrisburg, Pennsylvania. The basins are modeled with the assumption that the outflow in the river comes from two sources—prompt (within-year) runoff from precipitation, and flow from the long-term reservoirs of the basin. Tritium concentration in the outflow water of the basin is dependent on three factors: (1) tritium concentration in runoff from the long-term reservoir, which depends on the residence time for the reservoir and historical tritium concentrations in precipitation; (2) tritium concentrations in precipitation (the within-year runoff component); (3) relative contributions of flow from the long-term and within-year components. Predicted tritium concentrations for the outflow water in the river basins were calculated for different residence times and for different relative contributions from the two reservoirs. A box model was used to calculate tritium concentrations in the long-term reservoir. Calculated values of outflow tritium concentrations for the basin were regressed against the measured data to obtain a slope as close as possible to 1. These regressions assumed an intercept of zero and were carried out for different values of residence time and reservoir contribution to maximize the fit of modeled versus actual data for all the above rivers. The final slopes of the fitted regression lines ranged from 0.95 to 1.01 (correlation coefficient > 0.96) for the basins studied. Values for the residence time of waters within the basins and average relative contributions of the within-year and long-term reservoirs to outflow were obtained. Values for river basin residence times ranged from 2 years for the Kissimmee River basin to 20 years for the Potomac River basin. The residence times indicate the time scale in which the basin responds to anthropogenic inputs. The modeled tritium concentrations for the basins also furnish input data for urban and agricultural settings where these river waters are used.     

Development and sensitivity analysis of a model for assessing stratification and safety of Lake Nyos during artificial degassing

To prevent the recurrence of a disastrous eruption of carbon dioxide (CO₂) from Lake Nyos, a degassing plan has been set up for the lake. Since there are concerns that the degassing of the lake may reduce the stability of the density stratification, there is an urgent need for a simulation tool to predict the evolution of the lake stratification in different scenarios. This paper describes the development of a numerical model to predict the CO₂ and dissolved solids concentrations, and the temperature structure as well as the stability of the water column of Lake Nyos. The model is tested with profiles of CO₂ concentrations and temperature taken in the years 1986 to 1996. It reproduces well the general mixing patterns observed in the lake. However, the intensity of the mixing tends to be overestimated in the epilimnion and underestimated in the monimolimnion. The overestimation of the mixing depth in the epilimnion is caused either by the parameterization of the k-epsilon model, or by the uncertainty in the calculation of the surface heat fluxes. The simulated mixing depth is highly sensitive to the surface heat fluxes, and errors in the mixing depth propagate from one year to the following. A precise simulation of the mixolimnion deepening therefore requires high accuracy in the meteorological forcing and the parameterization of the heat fluxes. Neither the meteorological data nor the formulae for the calculation of the heat fluxes are available with the necessary precision. Consequently, it will be indispensable to consider different forcing scenarios in the safety analysis in order to obtain robust boundary conditions for safe degassing. The input of temperature and CO₂ to the lake bottom can be adequately simulated for the years 1986 to 1996 with a constant sublacustrine source of 18 l s^–1 with a CO₂ concentration of 0.395 mol l^–1 and a temperature of 26 °C. The results of this study indicate that the model needs to be calibrated with more detailed field data before using it for its final purpose: the prediction of the stability and the safety of Lake Nyos during the degassing process.Responsible Editor: Hans Burchard     

Quantifying bank storage of variably saturated aquifers

Numerical simulations were conducted to quantify bank storage in a variably saturated, homogenous, and anisotropic aquifer abutting a stream during rising stream stage. Seepage faces and bank slopes ranging from 1/3 to 100/3 were simulated. The initial conditions were assumed steady-state flow with water draining toward the stream. Then, the stream level rose at a constant rate to the specified elevation of the water table given by the landward boundary condition and stayed there until the system reached a new steady state. This represents a highly simplified version of a real world hydrograph. For the specific examples considered, the following conclusions can be made. The volume of surface water entering the bank increased with the rate of stream level rise, became negligible when the rate of rise was slow, and approached a positive constant when the rate was large. Also, the volume decreased with the dimensionless parameter M (the product of the anisotropy ratio and the square of the domain's aspect ratio). When M was large (>10), bank storage was small because most pore space was initially saturated with ground water due to the presence of a significant seepage face. When M was small, the seepage face became insignificant and capillarity began to play a role. The weaker the capillary effect, the easier for surface water to enter the bank. The effect of the capillary forces on the volume of surface water entering the bank was significant and could not be neglected.     

Development of two novel CYP-antibodies and their use in a PCB exposure experiment with Mytilus edulis

In an attempt to learn more about the cytochrome P450 (CYP) system of mussels, we used protein databases and alignment software to extract highly conserved CYP sequences. From these alignments synthetic peptides were produced and used for rabbit immunisation, which yielded polyclonal antibodies against the CYP families 2 and 4. The antibodies were evaluated with Western Blot and ELISA assays, using digestive gland microsomal samples from the mussel Mytilus edulis. Western Blots revealed immunoreactions for both antibodies. The anti-CYP2 sequence rendered one major immunopositive protein of approximately 49 kDa size, and weak signals for proteins of approximately 41 and 56 kDa size. The anti-CYP4 sequence rendered two major bands of approximately 56 and 59 kDa size, and also a weak immunoreaction with a protein of approximately 43 kDa size. ELISA rendered only weak signals even with a 1:50 dilution of IgG-purified serum. A 10-day exposure to Aroclor 1254 did not appear to affect any of the immunopositive proteins, while total PCBs in soft bodies increased from 14-40 ng/g DW in controls to 373-638 ng/g DW in exposed mussels.     

Deep crustal structure and rheology of the Gascoyne volcanic margin,western Australia

Interpretation of deep seismic reflection data across the Gascoyne Margin reveals six distinct seismic facies units related to the tectono-magmatic breakup history. On the outer Exmouth Plateau four large scale units are identified: (1) an extensively block-faulted upper crust; (2) a middle-crustal unit of discontinuous, undulatory reflectors; (3) a reflection-free deep crustal unit; and (4) a lower-crustal band of low-frequency, high-amplitude reflectors. Two additional units are found near the continent-ocean boundary (COB); (5) seaward-dipping reflectors (SDR); and (6) landward-dipping reflectors in the lower crust below the SDR. The lower-crustal high-reflectivity band, located near the top of a high-velocity unit (V_p > 7 kms^–1), is interpreted as magmatic underplating. There is a spatial correlation between the underplated area and the presence of extensive upper-crustal block-faulting and intrusive rocks in the shallow crust. The undulatory middle-crustal reflector unit is also only identified in the outer plateau area, and is interpreted as a zone in which the upper-crustal faults terminate. The inner parts of the margin consist of a deep basin showing little upper-crustal faulting and no evidence of middle crustal deformation or underplating. Theoretical modeling of the effect of rifting and magmatic underplating on crustal strength profiles suggests that the brittle-ductile transition may migrate at least 5 km upwards during several million years after the underplating event. Based on the seismic interpretation and crustal strength modeling we propose that the seismic structure of the outer Exmouth Plateau is severely modified by a transient change in the crustal rheological structure associated with magmatic underplating.     

Rejection of Intracoelomic Invading Material by Leptosynapta inhaerens (Echinodermata: Holothuroida): A Process of Ecological Significance?

Abstract. The synaptid holothuroid Leptosynapta inhaerens has the ability to expel unwanted particles that enter its body cavity. Intracoelomic particles ( viz. experimentally injected carmine particles) are trapped either by a coelom-produced mucoid net or by specialized organs (the vibratile urnae) that occur in bands in some interradial areas. Whatever the trapping method, particles are incorporated into dense mucoid masses that move towards the posterior part of the body cavity, in the vicinity of the rectum. These aggregates then cross the rectal wall through rectal pores, mix with the faeces, and are eventually incorporated into the wall of the synaptid burrow. Clearance of foreign particles requires 2 to 3 days. The coelom-cleaning system of synaptids appears to be the most effective within the class Holothuroidea , being well designed for endofaunal organisms whose walls are delicate and easily rupture.     

Evidence for slope instability and current-induced sediment transport,the RMSTitanic wreck search area,Newfoundland rise

The first map of the sea bed morphology and sedimentary features within the RMSTitanic search area is proposed from the interpretation of SAR side-scan sonar images. Downslope sedimentary features such as erosional furrows and crown scarps constitute a 7 km wide instability corridor. A large field (15 km²) of asymmetrical sediment waves indicating a downslope transport is identified. Current-induced features corresponding to associated sand ribbons and barchan dunes resulting from the Western Boundary Undercurrent action are mapped. The morphology of theTitanic Canyon is also precised from the SAR images. Finally, the origin of the sea bed features is discussed in an attempt to link each bed form to a sedimentary process.