Pre-1991 sulfur transfer between mafic injections and dacite magma in the Mt. Pinatubo reservoir

Before the 1991–1992 activity, a large andesite lava dome belonging to the penultimate Pinatubo eruptive period (Buag ∼ 500 BP) formed the volcano summit. Buag porphyritic andesite contains abundant amphibole-bearing microgranular enclaves of basaltic–andesite composition. Buag enclaves have lower K₂O and incompatible trace element (LREE, U, Th) contents than mafic pulses injected in the Pinatubo reservoir during the 1991–1992 eruptive cycle. This study shows that Buag andesite formed by mingling of a hot, water-poor and reduced mafic magma with cold, hydrous and oxidized dacite. Depending on their size, enclaves experienced variable re-equilibration during mixing/mingling. Re-equilibration resulted in hydration, oxidation and transfer of mobile elements (LILE, Cu) from the dacite to the mafic melts and prompted massive amphibole crystallization. In Buag enclaves, S-bearing phases (sulfides, apatite) and melt inclusions in amphibole and plagioclase record the evolution of sulfur partition among melt, crystal and fluid phases during magma cooling and oxidation. At high temperature, sulfur is partitioned between andesitic melt and sulfides (Ni-pyrrhotite). Magma cooling, oxidation and hydration resulted in exsolution of a S–Cl–H₂O vapor phase at the S-solubility minimum near the sulfide–sulfate redox boundary. Primary magmatic sulfide (pyrrhotite) and xenocrystic sulfide grains (pyrite), recycled together with olivines and pyroxenes from old mafic intrusives, were replaced by Cu-rich phases (chalcopyrite, cubanite) and, partially, by Ba–Sr sulfate. Sulfides degassed and transformed into residual spongy magnetite in response to fS₂ drop during final magma ascent and decompression. Our research suggests that a complete evaluation of the sulfur budget at Pinatubo must take into account the en route S assimilation from the country rocks. Moreover, this study shows that the efficiency of sulfur transfer between mafic recharges and injected magmas is controlled by the extent and rate of mingling, hydrous flushing and melt oxidation. Vigorous mixing/mingling and transformation of the magmatic recharge into a spray of small enclaves is required in order to efficiently strip their primary S-content that otherwise remains locked in the sulfides. Hydrous flushing increases the magma oxidation state of the recharges and modifies their primary volatile concentrations that cannot be recovered by the study of late-formed mineral phases and melt inclusions. Conversely, S stored in both late-formed Cu-rich sulfides and interstitial rhyolitic melt represents the pre-eruptive sulfur budget immediately available for release from mafic enclaves during their decompression.     

Late Hercynian remagnetization of Tournaisian series from the Laval syncline,Armorican Massif,France

Paleomagnetic investigations have been conducted on Tournaisian volcanics and sediments from the Laval syncline, in order to evaluate the consequences of the Late Variscan tectonic and thermic phases. On the southern flank of the syncline, anisotropy measurements have yielded maximum susceptibility in the schistosity planes. Thermal demagnetization exhibits only remagnetizations, characterized by a large range of blocking temperatures (from 350° to 670°C). Two phases of remagnetization seem to follow each other. The first may have occurred during the Tournaisian major orogenic phase. The second has taken place during the latest Stephanian/earliest Permian, in relation with the latest Variscan thermal event. All results are in favour of a clockwise rotation by 15–40° of the Laval syncline after the latest overprints. According to results from other regions of Brittany, this clockwise rotation involved the whole Armorican Massif. This motion may be related to the latest compression phase which has tightened the Ibero-Armorican arc, well before the Permo-Triassic opening of the Bay of Biscay.     

Projected 21st century snowfall changes over the French Alps and related uncertainties

Snowfall changes in mountain areas in response to anthropogenic forcing could have widespread hydrological, ecological and economic impacts. In this paper, the robustness of snowfall changes over the French Alps projected during the 21st century and the associated uncertainties are studied. In particular, the role of temperature changes on snowfall changes is investigated. Those issues are tackled through the analysis of the results of a very large ensemble of high-resolution regional climate projections, obtained either through dynamical or statistical downscaling. We find that, at the beginning and at the end of the cold season extending from November to March (included), temperature change is an important source of spread in snowfall changes. However, no link is found between temperature and snowfall changes in January and February. At the beginning and at the end of the cold season, the rate of change in snowfall per Kelvin does not depend much on the bias correction step, the period or the greenhouse gas scenario but mostly on the downscaling method and the climate models, the latter uncertainty source being dominant.     

Dune stabilization in central and southern Yukon in relation to early Holocene environmental change,northwestern North America

Eolian deposits of central and southern Yukon, northwestern Canada, consist of loess mantles, small areas of active dunes, and larger stabilized dune fields. Dune fields in valley settings within the region are situated both within and beyond the limit of the last glaciation. Infrared stimulation luminescence (IRSL) dating in central and southern Yukon reveals that these dune fields stabilized as late as 9–8.5 ka, well after the retreat of Cordilleran glaciers. These findings are comparable to other valley-setting dune fields and loess from central Alaska, which record activity during the period from the Lateglacial to the Holocene Thermal Maximum (HTM), and reduced or altered activity after 9–8 ka. Post-glacial dune activity was most likely related to warm, dry conditions during the HTM, under predominantly shrub-tundra vegetation. Early Holocene stabilization of these dunes probably occurred in response to cooler, moister conditions, and replacement of predominantly tundra by boreal forest cover, dominated by spruce. Stabilization of dune fields in southern Yukon and Alaska most likely represented an extension of the time-transgressive stabilization of dune fields that occurred across northwestern North America with the post-glacial expansion of the boreal forest.     

Modelling metolachlor exports in subsurface drainage water from two structured soils under maize (eastern France)

The study investigated the processes involved in metolachlor transport in two artificially drained, structured soils in eastern France. Measured losses of bromide and metolachlor in drainage water were compared with results simulated by the mechanistic, stochastic AgriFlux model. Simulated drainage water volumes were generally similar to the measured volumes when the spatial variability of the soil water properties was taken into account. When such variability was disregarded, cumulative water volumes of the clay soil were over- or underestimated by more than 20%. Two types of adsorption were tested. For instantaneous, reversible adsorption, using the partition coefficient Koc, metolachlor losses were underestimated in the first drainage water volumes and overestimated for the total study period. The use of slow adsorption and desorption kinetics (ADK) produced an export pattern similar to the observed one. A sensitivity analysis indicated that the simulated results are very sensitive to the values of the ADK rates, especially for the silty loam soil. The effect of ADK on the attenuation of metolachlor exports was more significant than the effect of degradation (2.3 and 6.7 times higher for the clay and silty loam soils, respectively). For the same four-month period, the bromide and metolachlor losses (using ADK) in the clay soil were 2.1 and 1.3 times greater, respectively, if the macroporosity was set at 10% than if it was not simulated. Conversely, macroporosity did not significantly affect these losses in the silty loam. The main factors involved in the metolachlor transport in the studied soils were: (i) the macroporosity, especially in the clay soil because of the low hydraulic conductivity of the matrix and (ii) the sorption kinetics rates which varied according to the soil physico-chemical characteristics.     

Le domaine Tariquide (arc de Gibraltar,Espagne et Maroc) : succession et hiatus de la sédimentation du Jurassique supérieur au Paléocène

The originality of the Malm–Cretaceous series of the Tariquides (Gibraltar arc), as compared to those of the Rifian–Betic ‘Dorsale’ (Alboran domain), and especially with the Penibetic (Iberia) domain, is emphasized. In the Los Pastores Group, near Algeciras, Upper Tithonian nodular limestones directly lie on the Dogger and are followed by Aptychus-bearing limestones (Late Berriasian to Barremian). In the Musa Group, Rif, radiolarites are followed by siliceous limestones (Kimmeridgian–Tithonian), then by karst and massflow breccias connected to a Berriasian tectonics, by Aptychus-bearing marly limestones, then by karst filled by Turonian limestones, and finally by Maastrichtian–Palaeocene polychrome pelites, whose micropalaeontological and mineral compositions (clay minerals, FeMn nodules) refer to a deep-sea, probably infra-CCD, sedimentation. To cite this article: M. Durand-Delga et al., C. R. Geoscience 337 (2005).     

Ignimbrites of basaltic andesite and andesite compositions from Tanna,New Hebrides Arc

Tanna island is part of a large volcanic complex mainly subsided below sea-level. On-land, two series of hydroclastic deposits and ignimbrites overlie the subaerial remains of a basal, mainly effusive volcano. The ‘Older’ Tanna Ignimbrite series (OTI), Late Pliocene or Pleistocene in age, consists of ash flows and ash- and scoria-flow deposits associated with fallout tephra layers, overlain by indurated pumice-flow deposits. Phreatomagmatic features are a constant characteristic of these tuffs. The ‘younger’ Late Pleistocene pyroclastics, the Siwi sequence, show basal phreatomagmatic deposits overlain by two successive flow units, each comprising a densely welded layer and a nonwelded ash-flow deposit. Whole-rock analyses of 17 juvenile clasts from the two sequences (vitric blocks from the phreatomagmatic deposits, welded blocks, scoriaceous bombs and pumices from the ignimbrites) show basaltic andesite and andesite compositions (SiO₂=53–60%). In addition, 296 microprobe analyses of glasses in these clasts show a wide compositional range from 51 to 69% SiO₂. Dominant compositions at ∼54, 56, 58.5 and 61–62% SiO₂ characterize the glass from the OTI. Glass compositions in the lower – phreatomagmatic – deposits from the Siwi sequence also show multimodal distribution, with peaks at SiO₂=55, 57.5, 61–62 and 64% whereas the upper ignimbrite has a predominant composition at 61–62% SiO₂. In both cases, mineralogical data and crystal fractionation models suggest that these compositions represent the magmatic signature of a voluminous layered chamber, the compositional gradient of which is the result of fractional crystallization. During two major eruptive stages, probably related to two caldera collapses, the OTI and Siwi ignimbrites represent large outpourings from these magmatic reservoirs. The successive eruptive dynamics, from phreatomagmatic to Plinian, emphasize the role of water in initiating the eruptions, without which the mafic and intermediate magmas probably would not have erupted. Received: February 19, 1993/Accepted October 10, 1993     

Contexte de mise en place des roches basiques de la ceinture de roches vertes birimienne de Diagorou-Darbani (Liptako,Niger, Afrique de l'Ouest) : plateau océanique ou environnement d'arc/bassin arrière-arc océanique

The Diagorou-Darbani Birimian greenstone belt includes (i) tholeiitic metabasalts with flat to slightly depleted LREE patterns, (ii) amphibolites having high contents in both compatible and incompatible elements with strongly fractionated spidergrams showing large HFSE negative anomalies, and (iii) metabasalts and amphibolites with intermediate features between the two previous groups. The chemical compositions of these rocks are not those of oceanic plateau basalts, but suggest a magmatic evolution from an arc environment to a back-arc oceanic basin. Source of the highly enriched amphibolites could be a depleted mantle metasomatized by slab-derived siliceous melts. To cite this article: A. Soumaila et al., C. R. Geoscience 336 (2004).