Etude de la repartition du manganese dans le Devonien Superieur de las Cabesses (Ariège)

The authors have studied the distribution of Si, Al, Ca, Mg, Fe, Mn, Ti, Ba, Cu, Ni éléments in Griotte upper devonian limestone by spectrography and polarography and have revealed a double correlation:

1. 1.
   Mn⁴⁺ - Ba confirmed as a result of the examination by Castaing microprobe micro fissures in which manganese has collected.     

Assimilation of continental crust by komatiites in the Precambrian basement of the Carswell structure (Saskatchewan,Canada)

The isotope geochemistry (Sm-Nd, Pb-Pb and Rb-Sr) of mafic gneisses from the basement of the Carswell structure (Saskatchewan, Canada), rich both in Mg and incompatible elements (K, Rb, REE) has been investigated. A good Sm-Nd alignment gives a slope corresponding to an age of 3.7 Ga. However, comparison with major elements data strongly suggests that this alignment is a mixing line between Mg-rich, high CaO/Al₂O₃ magmas and the local felsic crust older than 2.9 Ga. The mafic magmas were probably of komatiitic affinity (MgO > 20 percent) but, nevertheless, were extracted from a source with nearly chondritic to slightly enriched light REE distribution. The age of the komatiite emplacement (1.9–2.9 Ga) is only loosely constrained by the oldest crustal residence age in the series and the subsequent metamorphic events. The granulite facies climax is dated at ca. 1.9 Ga by concordant whole rock Pb-Pb and Sm-Nd garnet-whole rock isochrons. The Rb-Sr systematics have been disturbed by later event(s) younger than 1.5–1.7 Ga, but do not permit a more precise assessment of the perturbation age.     

Isotope and trace element geochemistry of Colorado Plateau volcanics

Basalts from the San Francisco Peaks and North Rim of Grand Canyon, nephelinites from the Hopi Buttes and Navajo minettes (Colorado Plateau) have been analyzed for trace element contents and Sr, Nd, Pb isotope compositions. The ages increase eastward from the Quaternary (basalt) to 5 Ma (nephelinite) and 30 Ma (minette) as does the depth of melt generation inferred from xenolith mineralogy and major element geochemistry.

The three rock types present an enrichment of incompatible elements (although minettes present negative concentration spikes for Nb, Zr, Ti, Ba, Sr) relative to other magma types. The chondrite-normalized Ce/Yb ratio changes from 8–22 (basalt) to 25–30 (nephelinite) and 33–60 (minette) and reflects small degrees of partial melting of a mantle source with a garnet/clinopyroxene ratio increasing with depth. The negative Eu anomaly present in minette, the low Sr/Nd and high Pb/Ce suggest the presence of a recycled continental crust component in their mantle source.

The ⁸⁷Sr/⁸⁶Sr ratio varies from 0.7032-0.7045 (basalt and nephelinite) to 0.7052-0.7071 (minette), while ε_Nd is remarkably more constant at +0.8 to +3.7 (nephelinite) and −2.6 to +2.2 (basalt and minette). Good linear correlations are observed in both ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb vs. ²⁰⁶Pb/²⁰⁴Pb diagrams with basalt being the least and nephelinite the most radiogenic and indicate a 2.3 ±0.1 Ga age and a Th/U of 3.4.

Three lithospheric source components are indicated: a) an OIB-type depleted mantle source, b) an end-member with unradiogenic Sr, Nd and Pb for basalt and nephelinite and c) a recycled crustal component for minette.     

Mesozoic and Cenozoic vertical movements in the Atlas system (Algeria, Morocco, Tunisia): An overview

The E-W trending Atlas System of Maghreb consists of weakly shortened, intra-continental fold belts associated with plateau areas (“Mesetas”), extending between the south-westernmost branch of the Mediterranean Alpine Belt (Rif-Tell) and the Sahara Platform. Although the Atlas system has been erected contemporaneously from Morocco to Algeria and Tunisia during the Middle Eocene to Recent, it displays a conspicuous longitudinal asymmetry, with i) Paleozoic outcrops restricted to its western part; ii) highest elevation occurring in the west, both in the Atlas System and its foreland (Anti-Atlas); iii) low elevation corridors (e.g. Hodna) and depressed foreland (Tunisian Chotts and Sahel area) in the east. We analyse the origin of these striking contrasts in relation with i) the Variscan heritage; ii) crustal vertical movements during the Mesozoic; iii) crustal shortening during the Cenozoic and finally, iv) the occurrence of a Miocene-Quaternary hot mantle anomaly in the west. The Maghreb lithosphere was affected by the Variscan orogeny, and thus thickened only in its western part. During the Late Permian-Triassic, a paleo-high formed in the west between the Central Atlantic and Alpine Tethys rift systems, giving birth to the emergent/poorly subsident West Moroccan Arch. During the late Middle Jurassic-Early Cretaceous, Morocco and western Algeria were dominantly emergent whereas rifting lasted on in eastern Algeria and Tunisia. We ascribe the uplift of the western regions to thermal doming, consistent with the Late Jurassic and Barremian gabbroic magmatism observed there. After the widespread transgression of the high stand Cenomanian-Turonian seas, the inversion of the Atlas System began during the Senonian as a consequence of the Africa-Eurasia convergence. Erosion affected three ENE-trending uplifted areas of NW Africa, which we consider as lithospheric anticlines related to the incipient Africa-Europe convergence. In contrast, in eastern Algeria and Tunisia a NW-trending rift system developed contemporaneously (Sirt rifting), normal to the general trend of the Atlas System. The general inversion and orogenesis of the Atlas System occurred during two distinct episodes, Middle-Late Eocene-Oligocene and Late Miocene-Pliocene, respectively, whereas during the intervening period, the Africa-Europe convergence was mainly accommodated in the Rif-Tell system. Inversion tectonics and crustal thickening may account for the moderate uplift of the eastern Atlas System, not for the high elevation of the western mountain ranges (Middle Atlas, High Atlas, Anti-Atlas). In line with previous authors, we ascribe part of the recent uplift of the latter regions to the occurrence of a NE-trending, high-temperature mantle anomaly, here labelled the Moroccan Hot Line (MHL), which is also marked by a strip of late Miocene-Quaternary alkaline magmatism and significant seismicity.     

Etude de l''acquisition d''éléments dissous par les eaux de lessivage des roches granitiques sous climat tempéré

Using chemical potential diagrams and budget calculations, we show that the acquisition of solutes by surface water in granitic rocks under temperate climate corresponds with transformation of primary minerals into kaolinite or halloysite. This mineral controls aluminium solubility.     

Relations entre les concentrations des ions alcalins dans les eaux thermales sulfurées sodiques du Midi de la France

Alkali ion concentrations were studied in hot sulphurated springs in the south of France. Strong correlations between elements (K-Rb, K-Cs and Na-Li) are found. The element concentrations are also closely related with deep temperature as estimated by classical geothermometers. A discussion of the origin of the interelement correlations is presented. Further studies on the behaviour of trace elements during mineral dissolution are needed and can yield interesting methods of investigation in geothermal exploration.

Résumé

L'étude des concentrations des ions alcalins dissous dans les eaux thermales sulfurées du Midi de la France montrent de très nettes corrélations entre éléments (K-Rb, K-Cs et Na-Li) ainsi que des corrélations entre concentrations d'éléments et température profonde estimée à l'aide des géothermomètres classiques. Plusieurs suggestions quant à l'explication des relations observées sont présentées. Une bonne compréhension du comportement des ions en trace lors de la dissolution des minéraux par l'eau aurait certainement des retombées intéressantes en prospection géothermique.     

Chemistry of solutions from the 13°N East Pacific Rise hydrothermal site

Ten samples were recovered by the submersible “Cyana” submersible from two groups of hydrothermal vents located 2600 m deep along the East Pacific Rise at 13°N. The maximum measured temperature was 317°C and minimum pH 3.8. A systematic determination of major and trace elements has been carried out and mixing lines between a high-temperature component (HTC) and seawater are observed. The water chemistry of the HTC slightly differs for several elements at the two sites. This HTC is deprived of SO₄ and Mg and is greatly enriched in most other species. Maximum concentrations are (in units per kg):Cl = 0.72mol; Br = 1.1mmol; Na = 0.55mol; K = 29mmol; Rb = 14 μmol; Ca = 52mmol; Sr = 170 μmol; Mn = 750 μmol; Fe = 1mmol; Al = 15 μmol; Si = 21mmol. For many elements, the magnitude of the anomaly relative to seawater does not compare with the results obtained from the Galapagos or East Pacific Rise 21°N. The enrichment of cations relative to seawater is likely related to the huge Cl excess through charge balance. TheBr/Cl ratio is close to that for seawater. However, it is not clear whether the Cl excess is due to gas release or basalt hydration (formation of amphibole chlorite or epidote).P-T dependence of SiO₂ solubility suggests that water-rock interaction last occurred at a depth in excess of 1 km below the sea floor. A mixing line of⁸⁷Sr/⁸⁶Sr vs. Mg/Sr demonstrates that the HTCs have a nearly identical⁸⁷Sr/⁸⁶Sr ratio of 0.7041 for both sites. A water/rock ratio of about 5 is inferred, which differs from the 1.5 value obtained at 21°N.