Bestimmung polarer Phosphorsäureester in Trink‐ und Oberflächenwasser mittels HPLC‐MS‐MS

Determination of Organophosphorus Pesticides in Water by HPLC‐MS‐MS In the EC Water Framework Directive 2000/60/EG and in CEC 76/464/EEC there are 16 organophosphorus pesticides (insecticides and acaricides) listed which belong to so‐called priority substances. The committed quality aims of these substances frequently require maximum concentrations below 0.1 μg/L. In this paper a HPLC‐MS‐method is described. The reported limits of determination of organophosphorus pesticides are lower than the demanded limits. High analytical sensitivity is reached by solid‐phase extraction (SPE) and by injecting large volumes. For some of these substances no sample enrichment is needed and low detection limits are obtained by direct injection of the original water sample.     

Late Jurassic tectonics and sedimentation: breccias in the Unken syncline,central Northern Calcareous Alps

This study analyses and discusses well preserved examples of Late Jurassic structures in the Northern Calcareous Alps, located at the Loferer Alm, about 35 km southwest of Salzburg. A detailed sedimentary and structural study of the area was carried out for a better understanding of the local Late Jurassic evolution. The Grubhörndl and Schwarzenbergklamm breccias are chaotic, coarse-grained and locally sourced breccias with mountain-sized and hotel-sized clasts, respectively. Both breccias belong to one single body of breccias, the Grubhörndl breccia representing its more proximal and the Schwarzenbergklamm breccia its more distal part, respectively. Breccia deposition occurred during the time of deposition of the Ruhpolding Radiolarite since the Schwarzenbergklamm breccia is underlain and overlain by these radiolarites. Formation of the breccias was related to a major, presumably north-south trending normal fault scarp. It was accompanied and post-dated by west-directed gravitational sliding of the Upper Triassic limestone (“Oberrhätkalk”), which was extended by about 6% on top of a glide plane in underlying marls. The breccia and slide-related structures are sealed and blanketed by Upper Jurassic and Lower Cretaceous sediments. The normal fault scarp, along which the breccia formed, was probably part of a pull-apart basin associated with strike slip movements. On a regional scale, however, we consider this Late Jurassic strike-slip activity in the western part of the Northern Calcareous Alps to be synchronous with gravitational emplacement of “exotic” slides and breccias (Hallstatt mélange), triggered by Late Jurassic shortening in the eastern part of the Northern Calcareous Alps. Hence, two competing processes affected one and the same continental margin.     

Assessment of flood inundation mapping of Surat city by coupled 1D/2D hydrodynamic modeling: a case application of the new HEC-RAS 5

Surat city of India, situated 100 km downstream of Ukai Dam and 19.4 km upstream from the mouth of River Tapi, has experienced the largest flood in 2006. The peak discharge of about 25,770 m³ s^?1 released from the Ukai Dam was responsible for a disaster. To assess the flood and find inundation in low-lying areas, simulation work is carried out under the 1D/2D couple hydrodynamic modeling. Two hundred ninety-nine cross sections, two hydraulic structures and five major bridges across the river are considered for 1D modeling, whereas a topographic map at 0.5 m contour interval was used to produce a 5 m grid, and SRTM (30 and 90 m) grid has been considered for Surat and the Lower Tapi Basin. The tidal level at the river mouth and the release from the Ukai Dam during 2006 flood are considered as the downstream and upstream boundaries, respectively. The model is simulated under the unsteady flow condition and validated for the year 2006. The simulated result shows that 9th August was the worst day in terms of flooding for Surat city and a maximum 75–77% area was under inundation. Out of seven zones, the west zone had the deepest flood and inundated under 4–5 m. Furthermore, inundation is simulated under the bank protection work (i.e., levees, retaining wall) constructed after the 2006 flood. The simulated results show that the major zones are safe against the inundation under 14,430 m³ s^?1 water releases from Ukai Dam except for the west zone. The study shows the 2D capability of new HEC-RAS 5 for flood inundation mapping and management studies.     

Recruitment of shrimp (Pandalus borealis) in the Barents Sea related to spawning stock and environment

The shrimp spawn in autumn, and the females carry their eggs as out roe until spring when the larvae hatch. Within a period of 2 months the shrimp larvae settle to the bottom. It has been claimed that the year-class strength probably is determined during the larval phase. Today's assessment and forecast of the shrimp stock productivity and potential fishing yields are weak. This is partly due to poor knowledge on population dynamics from hatching until the shrimp are caught in the fishery at the age of 3 or 4 years. We, therefore, here identify the most important abiotic and biotic factors that affect recruitment in addition to spawning stock biomass. Since 1995, a net attached to the underbelly of the survey trawl used at the annual cruise in the Barents Sea has caught juvenile shrimp. The abundance of settled shrimp larvae varies in time and space. The recruitment to the fishery has been quite stable with the exception of the 1996 year-class, which was observed as 1-year-olds but has not been registered since. The temporal pattern of the three youngest year-classes is studied in relation to abiotic factors such as sea temperature, ice index and North Atlantic Oscillation, as well as biotic factors such as spawning stock biomass and presence of copepods, euphausiids and predating cod. Recruitment indices and factors identified by the Spearmann correlation to be significantly correlated with recruitment were used as input in a principal component analysis (PCA) and a generalized additive model (GAM) was applied. Abundance of 1-year-old shrimp is positively correlated to spawning stock biomass the previous year and to temperature of the previous winter, and negatively correlated with the number of 1-year-old cod. Two-year-old shrimp show significant correlation with temperature, whereas there is a strong negative correlation with euphausiids. Three-year-old shrimp are significantly correlated with the number of 2-year-old shrimp the previous year but negatively correlated to temperature at sampling time. This is probably due to less overlap with the main predator cod when cold. Ricker functions indicate an increased density-dependent mortality with age. When predicting the recruitment of shrimp to the fishery, the spawning stock biomass, the abundance of cod and euphausiids, as well as the temperature should be included.     

Rainfall uncertainty for extreme events in NWP downscaling model

Limited area numerical weather predication (NWP) models such as MM5 have become a popular method for generating rainfall estimates for hydrological analysis, particularly for catchments where rainfall data are sparse. Although several studies have been undertaken to investigate the appropriateness of MM5 parameterization schemes for hydrological applications, the size of the nested domains and the distance between them have been overlooked as a source of uncertainty in model precipitation estimates for hydrological purposes. This study examines the uncertainty of model rainfall estimates derived from MM5 by varying the domain size and the distance between the domains. The results from this study show that domain size and buffer zone have a significant impact on model rainfall estimates, which should not be overlooked by hydrologists. Copyright © 2010 John Wiley & Sons, Ltd.     

Mineralogy and petrogenesis of a Ba–Ti–Zr-rich peralkaline dyke from Šebkovice (Czech Republic): Recognition of the most lamproitic Variscan intrusion

A peralkaline, ultrapotassic dyke found at ?ebkovice (T?ebí? district, western Moravia) is a mineralogically extreme member of a dyke swarm occurring along the south-eastern border of the Moldanubian Region of the Bohemian Massif. The dyke shows a simple zoning, with a very fine-grained marginal zone grading into a medium-grained central zone. It has a primary mineral assemblage of microcline and potassic amphiboles, with accessory apatite and altered phlogopite. The microcline exhibits an unusual red luminescence colour and pronounced substitution of Fe³⁺ for Al, with measured contents of Fe₂O₃ up to 8.5 wt.% (0.31 apfu Fe³⁺). Amphiboles have very high K (up to 0.99 apfu) and Si contents; their compositions follow an alkaline fractionation trend from potassic-richterite to potassic-magnesio-arfvedsonite, characterized by an increase of Na/K and a decrease of Ca, Mg, Fe²⁺ and Ti via heterovalent substitutions ^[B]Ca + ^[C](Mg,Fe²⁺) → ^[B]Na + ^[C]Fe³⁺ and Ti + Mg → 2Fe³⁺. The most evolved apatite is significantly enriched in SrO (up to 9.7 wt.%; 0.49 apfu Sr). The core of the dyke and late veinlets contain unique late- to post-magmatic Ba–Ti–Zr-bearing mineral assemblages of baotite, henrymeyerite, titanite, rutile, benitoite and bazirite. Anhedral baotite fills interstices distributed inhomogeneously in the dyke centre; it is locally replaced by a Ba-bearing titanite + henrymeyerite + rutile + quartz assemblage. Henrymeyerite (the second record in a lamproite) shows variable Fe/Ti ratios and represents a solid solution of the hepta- and hexatitanate components. Euhedral crystals of benitoite and bazirite are enclosed in the late-stage quartz–titanite–apatite veinlets in the fine-grained margin of the intrusion. In terms of a mineralogical–genetic classification, the ?ebkovice dyke can be considered as a new high-silica (~ 57 wt.% SiO₂) variety of lamproite (variety ?ebkovice), and represents a unique expression of post-collisional potassic magmatism on the south-eastern border of the Bohemian Massif. The peralkaline dykes from this area show mineralogical and geochemical features similar to those of silica-rich orogenic lamproites emplaced at destructive plate margins. In terms of the modern classification of lamproites, the ?ebkovice dyke is the first lamproite recognised in the Variscan orogenic belt.     

Fuzzy logic based melting layer recognition from 3 GHz dual polarization radar: appraisal with NWP model and radio sounding observations

The advent of polarimetry makes it possible to categorize hydrometeor inferences more accurately by providing detailed information of the scattering properties. In light of this, the authors have developed a fuzzy logic based system for the recognition of melting layer in the atmosphere. The fuzzy system is based on characterizing melting layer scatterers from non-melting scatterers using five crisp inputs, namely, horizontal reflectivity (Z _H), differential reflectivity (Z _DR), co-polar correlation coefficient (ρ _HV), linear depolarization ratio (LDR) and height of radar measurements (H). For the implementation of melting layer recognition, the study employs the dual polarized signatures from the 3 GHz Chilbolton Advanced Meteorological Radar (CAMRA). Furthermore, a simple but effective averaging procedure for melting level estimation from a volume RHI scan is proposed. The proposed scheme has been evaluated with Weather Research and Forecasting (WRF) model simulated and radio soundings retrieved melting level height over a total of 84 RHI scan-based bright band cases. The results confirm that the estimated melting level heights from the proposed method are in good agreement with the WRF model and radio sounding observations. The 3 GHz radar melting level height estimates correspond with the R ² and RMSE values of 0.92 and 0.24 km, respectively, when compared to the radio soundings, and 0.93 and 0.21 km, respectively, when compared to the WRF model results. Moreover, the related R ² and RMSE values are reported as 0.93 and 0.22 km respectively between the WRF and radio soundings retrievals. This implies that the downscaled WRF modelled melting level height may also be used for operational or research needs.     

Mineralogy,petrography, geochemistry,and classification of the Košice meteorite

The Ko?ice meteorite was observed to fall on 28 February 2010 at 23:25 UT near the city of Ko?ice in eastern Slovakia and its mineralogy, petrology, and geochemistry are described. The characteristic features of the meteorite fragments are fan‐like, mosaic, lamellar, and granular chondrules, which were up to 1.2 mm in diameter. The fusion crust has a black‐gray color with a thickness up to 0.6 mm. The matrix of the meteorite is formed mainly by forsterite (Fo_80.6); diopside; enstatite (Fs_16.7); albite; troilite; Fe‐Ni metals such as iron and taenite; and some augite, chlorapatite, merrillite, chromite, and tetrataenite. Plagioclase‐like glass was also identified. Relative uniform chemical composition of basic silicates, partially brecciated textures, as well as skeletal taenite crystals into troilite veinlets suggest monomict breccia formed at conditions of rapid cooling. The Ko?ice meteorite is classified as ordinary chondrite of the H5 type which has been slightly weathered, and only short veinlets of Fe hydroxides are present. The textural relationships indicate an S3 degree of shock metamorphism and W0 weathering grade. Some fragments of the meteorite Ko?ice are formed by monomict breccia of the petrological type H5. On the basis of REE content, we suggest the Ko?ice chondrite is probably from the same parent body as H5 chondrite Morávka from Czech Republic. Electron‐microprobe analysis (EMPA) with focused and defocused electron beam, whole‐rock analysis (WRA), inductively coupled plasma mass and optical emission spectroscopy (ICP MS, ICP OES), and calibration‐free laser induced breakdown spectroscopy (CF‐LIBS) were used to characterize the Ko?ice fragments. The results provide further evidence that whole‐rock analysis gives the most accurate analyses, but this method is completely destructive. Two other proposed methods are partially destructive (EMPA) or nondestructive (CF‐LIBS), but only major and minor elements can be evaluated due to the significantly lower sample consumption.     

Female newcomers’ adjustment to life in Toronto,Canada: sources of mental stress and their implications for delivering primary mental health care

Stress disorders and other mental ill health may be brought on by the disruption caused by resettlement. We examine female newcomers’ experiences of adjusting to a new place, metropolitan Toronto, Canada and a new health care system. We consider sources of mental stress experienced during adjustment. We frame this adjustment as a process that happens over place and through time. Thematic findings of interviews (n = 35) with female newcomers from five cultural-linguistic groups are reported. Sources of stress in adjusting to life in Toronto include: navigating a new place, personal safety concerns, adapting to a new lifestyle, and finding employment. Sources of stress in adjusting to a new health care system include: learning how to access care, not having access to specialists, and adapting to a new culture of care. We conclude by considering the implications of what newcomers report for the delivery of primary mental health care (i.e. ‘first contact’ care).