Marine risk assessment: linear alkylbenzenesulponates (LAS) in the North Sea

The fate of linear alkylbenzenesulponates (LAS) in estuaries and coastal areas of the North Sea has been characterized with simple environmental models. The predicted concentration range in the estuaries around the North Sea (0.9-9 microg LAS l(-1)) was validated by monitoring data (1-9 microg LAS l(-1)). In offshore sites of the North Sea, it is estimated--and experimentally verified for a few sites--that the LAS concentration is below analytical detection limit (i.e., 0.5 microg LAS l(-1)). The effects of LAS on marine organisms have been reviewed. For short-term acute tests, there was no significant difference (p = 0.83) between the mean LC50 values of freshwater and marine organisms (mainly pelagic species tested, 4.1 and 4.3 mg LAS l(-1), respectively). For longer-term chronic tests, it appeared that the sensitivity (mean no-observed effect concentration (NOEC) value) of marine and freshwater organisms (0.3 and 2.3 mg LAS l(-1), respectively) was significantly different pt-test = 0.007). The predicted no-effect-concentrations (PNEC) were 360 and 31 microg LAS l(-1), for freshwater and marine pelagic communities, respectively. Given that the maximum expected estuarine and marine concentrations are 3 to > 30 times lower than the PNEC, the risk of LAS to pelagic organisms in these environments is judged to be low.     

CLIMAP SSTs re-revisited

Since the 1976 publication of the CLIMAP ice age sea surface temperature (SST) reconstruction showing a 1–2 ^∘C tropical cooling a substantial debate has arisen as to whether tropical SSTs may instead have been 4–5^∘ colder than present. Herein I review the arguments for large SST variations and question a number of key findings, particularly the validity of ice-age coral SST estimates and “down-projecting” tropical snowline changes to the surface. GCM results indicate that an intermediate solution requiring ∼2.5 ^∘C warm pool cooling is consistent with most quantitative low elevation surface land data and is small enough to allow the persistence of tropical biota in the ocean during glacial times. The proposal reduces estimated ice-age climate sensitivity (for a doubling of CO₂) from a “high-end” sensitivity of about 4.5 ^∘C (for a 5–6 ^∘C tropical cooling) to a “mid-range” sensitivity of about 3.0 ^∘C for a 2.5 ^∘C warm-pool decrease. Received: 28 July 1999 /Accepted: 12 August 1999     

THE KRAMER CREEK,COLORADO METEORITE: A NEW L4 CHONDRITE

The Kramer Creek, Colorado, chondrite was found in 1966 and identified as a meteorite in 1972. Bulk chemical analysis, particularly the total iron content (20.36%) and the ratio of Fe_total/SiO₂ (0.52), as well as the compositions of olivine (Fa_21.7) and orthopyroxene (Fs_18.3) place the meteorite into the L-group of chondrites. The well-defined chondritic texture of the meteorite, the presence of igneous glass in the chondrules and of low-Ca clinopyroxene, as well as the slight variations in FeO contents of olivine (2.4% MD) and orthopyroxene (5.6% MD) indicate that the chondrite belongs to the type 4 petrologic class.     

Spatially resolved spectroscopy of the E+A galaxies in the z= 0.32 cluster AC 114

We present spatially resolved intermediate-resolution spectroscopy of a sample of 12 E+A galaxies in the   z = 0.32  rich galaxy cluster AC 114, obtained with the FLAMES multi-integral field unit system on the Very Large Telescope (VLT) of the European Southern Observatory. Previous integrated spectroscopy of all these galaxies by Couch & Sharples had shown them to have strong Balmer line absorption and an absence of [O  ii ]λ3727 emission – the defining characteristics of the 'E+A' spectral signature, indicative of an abrupt halt to a recent episode of quite vigorous star formation. We have used our spectral data to determine the radial variation in the strength of Hδ absorption in these galaxies and hence map out the distribution of this recently formed stellar population. Such information provides important clues as to what physical event might have been responsible for this quite dramatic change in star formation activity in the recent past of these galaxies. We find a diversity of behaviour amongst these galaxies in terms of the radial variation in Hδ absorption: four galaxies show little Hδ absorption across their entire extent; it would appear they were misidentified as E+A galaxies in the earlier integrated spectroscopic studies. The remainder show strong Hδ absorption, with a gradient that is either negative (Hδ equivalent width decreasing with radius), flat or positive . By comparison with numerical simulations we suggest that the first of these different types of radial behaviour provides evidence for a merger/interaction origin, whereas the latter two types of behaviour are more consistent with the truncation of star formation in normal disc galaxies with the Hδ gradient becoming increasingly positive with time after truncation. It would seem therefore that more than one physical mechanism is responsible for E+A formation in the same environment.     

Phytoplankton diversity and chlorophyll-A in a polluted estuary

The quantity of phytoplankton in Newark Bay, New Jersey as indicated by chlorophyll-a content of the water, is low in the winter and early spring, and fluctuates greatly during the spring and summer. Chlorophyll-a concentrations are generally less than 20 μg/l until April. Between April and August, three phytoplankton blooms were indicated by chlorophyll-a concentrations as high as 81.4 μg/l. Net phytoplankton diversity values indicated generally eutrophic conditions; however, there was no significant correlation between diversity and chlorophyll-a concentrations. A role of nannoplankton in blooms is indicated.     

Anthropogenic-induced changes in twenty-first century summertime hydroclimatology of the Northeastern US

Potential changes in summertime hydroclimatology over the northeastern (NE) region of the USA induced by increases in greenhouse gas (GHG) concentrations are investigated using a state-of-the-art regional climate modeling system. Results for a higher emissions scenario illustrate changes that may occur if dependence on fossil fuels continues over the coming century. Summertime precipitation is projected to decrease across much of the central NE, but increase over the southernmost and northernmost portions of the domain. Evaporation is expected to increase across the entire domain. The balance between these two results in a decrease in soil moisture content across most of the domain (by approximately 10 mm) and an increase in the summertime soil-moisture depletion rate (by approximately 10 mm/month). At the same time, an increase in both atmospheric near-surface specific and saturation specific humidity is projected, resulting in an increase in relative humidity across the southern portion of the domain, with slight decreases over the northern portion. Combined with an average increase in summer temperatures of 3.5°C, the projected increase in relative humidity results in a marked increase in the average daily maximum heat index for the region on the order of 3.9°C, as well as a 350–400% increase in the number of days with heat index values exceeding 32.2°C (90°F)—the level of “extreme caution”. Taken together, these high-resolution, dynamically-generated projections confirm the potential for significant summertime climate change impacts on the NE over the coming century as suggested by previous studies.     

Magnetic properties of the Lower Old Red Sandstone lavas in the Midland Valley,Scotland; palaeomagnetic and tectonic considerations

Thermal demagnetization studies of lavas in the Strathmore area of the Midland Valley, Scotland, support overall palaeomagnetic data found in previous studies of these rocks. Reduced directional scatter as compared to some earlier studies, is attributed to more effective demagnetization, resolving some of the directional complexity of previous studies. Combined magnetic fabric and directional analysis suggest that at least some deviating directions may be explained by local tectonism. The existence of almost antiparallel directional groups and field tests give supporting evidence for a “primary” (deuteric) origin of the main magnetization of these rocks. Additionally, a second remanence component having shallow reverse directions of magnetization, is attributed to later remagnetization in Old Red Sandstone time. The Midland Valley results are seen in conjunction with other Palaeozoic palaeomagnetic results and possible geodynamic implications are discussed.