Dissolution of olivine during natural weathering

Naturally weathered olivine occurring as phenocrysts in Hawai’ian volcanic rocks from several volcanic centers and regolith/outcrop settings, and as tectonized olivines from several metadunite bodies in the southern Appalachian Blue Ridge, are all similarly corroded by natural weathering. Conical (funnel-shaped) etch pits occur as individual pits, base-to-base pairs of cone-shaped pits, or en echelon arrays. Etch-pit shapes and orientations in the smallest etch-pit arrays visible in conventional scanning electron microscopy resemble even smaller features previously reported from transmission electron microscope investigations of olivine weathering. Etch pits occur in samples with chemical and/or mineralogical evidence of weathering, and/or are associated with, or proximal or directly connected to, fractures or exposed outcrop surface, and therefore are formed by weathering and not inherited from pre-weathering aqueous alteration (e.g., serpentinization, iddingsitization) of these parent rocks. Many etch pits are devoid of weathering products. Natural weathering of olivine is surface-reaction-limited. Similarity of corrosion forms from naturally weathered olivine from multiple igneous and metamorphic parent-rock bodies suggests that olivine weathers in the same manner regardless of its specific crystallization/recrystallization history, eruption/weathering/exposure ages of the olivine’s host rock, and the local regolith history.     

Seasonal temperatures for the past ∼400 years reconstructed from diatom and chironomid assemblages in a high-altitude lake (Lej da la Tscheppa,Switzerland)

We analysed a 42 cm long sediment record from Lej da la Tscheppa, a high-altitude lake (2,616 m a.s.l.) in the Upper Engadine valley (Switzerland) for subfossil diatoms, chironomids and pollen. The chronology of the top 21 cm of the record was established using ²¹⁰Pb analysis using a constant-rate-of-supply model, and validated with ¹³⁷Cs measurements and the content of spheroidal carbonaceous particles. A tentative chronology for the lower part of the core was obtained through extrapolation of the sedimentation rates in the uppermost part of the record. Pollen assemblages in the record reflect regional changes in forestation and land-use patterns in the Upper Engadine valley and show no evidence of significant local human activity in the lake’s catchment. Diatom assemblages record a distinct increase in planktonic taxa since the early 19th century, suggesting a decrease in the duration of ice-cover. In contrast, chironomid assemblages remained stable during a large part of the record. We applied an established chironomid-based July air temperature transfer function and a newly developed diatom-based spring air temperature transfer function to reconstruct past seasonal air temperature changes at Lej da la Tscheppa. The reconstructions indicate a diatom-inferred warming trend in spring temperatures during the past ca. 400 years, whereas chironomid-inferred summer temperatures suggest a slight cooling trend. These biota-based reconstructions are in good agreement with the centennial-scale temperature trend in an independent reconstruction of regional temperatures in the Upper Engadine region based on instrumental records and documentary proxy evidence from the Alps. Our results suggest that, in high-altitude lakes, independent chironomid- and diatom-based seasonal temperature reconstruction is possible and can be successfully used to track seasonal temperature trends.     

Evacuees’ information sources and reentry decision making in the aftermath of Hurricane Ike

In the aftermath of a hurricane, local emergency managers need to communicate reentry plans to households that might be scattered over multiple counties or states. To better understand evacuees’ households’ reliance on different information sources at the time they decided to return home, this study collected data on reentry after Hurricane Ike. The results from a survey of 340 evacuating households indicated that there was low compliance with official reentry plans and that none of the information sources produced greater compliance with official reentry plans. Nonetheless, there were significant changes in the utilization of different sources of emergency information over the course of an evacuation but local news media remained the most common sources throughout the event. There also were significant differences in the relative importance of different sources of reentry information, with people relying most on information from peers. In summary, local authorities need to identify more effective ways to communicate with evacuees that have relocated to distant communities and to motivate them to comply with official reentry plans.     

Investigation of NaCl deliquescence in porous substrates using RH-XRD

We report on the use of X-ray diffractometry under controlled conditions of temperature and relative humidity (RH-XRD) for the investigation of NaCl deliquescence in the pore space of glass filter frits, which were used as model substrates. The study confirms that RH-XRD is an appropriate experimental technique for the in situ observation of phase transformation in porous materials. It is used for an investigation of both the deliquescence kinetics and the deliquescence humidity within pores of different median pore diameter. Several major influences affecting deliquescence rates in the pore space close to the surface of a porous material are discussed. It appears that quite short-term variation of ambient relative humidity, e.g., typical daily fluctuations, might induce damaging deliquescence–crystallization cycles within the pore space of building materials. In agreement with theoretical considerations it was found that confinement of NaCl crystals in pores with median diameters in the range 1.4–70 μm does not affect the deliquescence humidity of the salt.     

GIS in the K-12 Curriculum: A Cautionary Note

Two qualitative case studies, one focusing on K-12 teachers and the other on middle school students, explore key factors associated with using Geographic Information Systems in the classroom. In both studies, access to appropriate hardware is a critical barrier. Time is another critical barrier—time to learn the GIS software and time in the curriculum to incorporate GIS as a learning experience. In both case studies, learning the technology at the expense of learning spatial analysis was a danger, suggesting the need for conscious focus on the goal of using GIS to learn how to “do geography.”     

Eruption episodes and magma recharge events in andesitic systems: Mt Taranaki,New Zealand

Eruption episodes, where a series of eruption events are generically related, can include the eruption of a wide spectrum of volcanic activity over decadal periods. This paper concentrates on the opening phases of an eruption episode which occurred approximately 1800 yrs BP from Mt Taranaki, New Zealand. These events spanned the eruption of differing bulk compositions and styles from two distinct vent locations; an andesitic sub-plinian eruption from the summit vent and a scoria cone-building eruption of basaltic magma from a satellite vent. Compositional profiles and zoning textures of plagioclase, amphibole and clinopyroxene phenocrysts from the opening andesitic event show evidence of magma mixing and subsequent crystallisation just prior to the initiation of the eruption episode. Titanomagnetite grain morphology and Ti variation suggest that the magma mixing event occurred within a few days to weeks before the eruption acting as a trigger for it. We present a magmatic model which is constrained by the petrological observations and eruptions of the episode. In this model magma differentiation at depth causes its rise and recharging of a mid-crustal magma storage area at 5–7 km. Although the recharging magma differed slightly in oxygen fugacity and temperature, it was compositionally and physically similar enough to the residing andesitic magma to allow efficient mixing. The petrological characteristics described here can be readily observed and enable identification of mixing events in other recent eruption episodes.     

Trace metals in a tidal Mediterranean embayment

The Euvoikos gulf, and the strait of Euripos therein, is a restricted embayment on the eastern coast of Greece having a significant, unusual tidal phenomenon and receiving some domestic, trade and industrial wastes from the town of Chalkis and several coastal industries. The purpose of the present work was to study the influence of the tidal current and the anthropogenic inputs on the distributions of several trace elements (namely, Pb, Cu, Zn, Cr, Fe, Mn and Ni) in the seawaters (as dissolved and particulate species) and the sea-bottom sediments. Thorough mixing, resuspension and transport of fine particles and direct discharges are the major mechanisms affecting the distribution patterns.     

Effects of polynuclear aromatic hydrocarbons on lysosomal membranes in molluscs

Lysosomal sequestration of polynuclear aromatic hydrocarbons (PNAHs), a major class of environmental contaminant, is a well-established phenomenon;¹ considerably less is known about their pathological effects on lysosomes. Marine molluscs contain a number of lysosome-rich tissues and PNAHs are known to induce deleterious alterations in lysosomal structure and latency of lysosomal enzymes.² The latter are presumed to involve destabilisation of the lysosomal membrane, resulting in increased permeability and reduced enzyme latency. If lysosomal injury involves derangement of membrane-lipid structure due to the interaction of PNAHs then it would be expected that membrane damage would be closely linked to the structural characteristics of the intruding molecule. Our results show that the effects of the isomeric PNAHs phenanthrene and anthracene on digestive cell lysosomal stability were markedly different in the marine mussel (Mytilus edulis) over the same range of tissue concentrations. Lysosomal membrane stability was determined using a cytochemical test for enzyme latency.³