Ecosystem Responses of the Subtropical Kaneohe Bay,Hawaii, to Climate Change: A Nitrogen Cycle Modeling Approach

The global coastal zone is characterized by high biological productivity and serves as an important channel through which materials are transferred from land to the open ocean, yet little is known how it will be affected by climate change. Here, we use Kaneohe Bay, Hawaii, a semi-enclosed subtropical embayment partially surrounded by a mountainous watershed and fed by river runoff as an example to explore the potential impact of climate change on the pelagic and benthic cycling of nitrogen. We employ a nine-compartment nitrogen cycle biogeochemical box model and perturb it with a set of four idealized climate scenarios. We find that hydrological changes play a dominant role in determining the ecosystem structure, while temperature changes are more important for the trophic state and stability of the ecosystem. The ecosystem stability against storm events does not significantly change under any scenario. The system remains autotrophic in the future; however, it becomes significantly less autotrophic under drier climate, while it turns slightly more autotrophic under wetter climate. These findings may have implications for other high island watershed and coastal ecosystems in the tropics and subtropics.     

Pravčice Rock Arch (Bohemian Switzerland National Park, Czech Republic) deterioration due to natural and anthropogenic weathering

The dominant factors affecting the development of weathering forms on the Prav?ice Rock Arch (PRA) (Bohemian Switzerland National Park, Czech Republic) are discussed, based on the in situ monitoring of weathering forms, as well as on laboratory studies of materials taken from this site. The in situ monitoring shows the progressive development of distinct weathering forms (delamination of case-hardened rock surfaces, cyclic efflorescence, and granular disintegration of exposed weakly cemented rock mass) in specific portions of the PRA, whose location is controlled by lithology, jointing/local hydrodynamics, and exposure to climatic factors. From the analysis of efflorescence, the dominance of sulphates is evident; particularly of gypsum and alums. However, the synergistic effects of the several salt species (that also include minor nitrates and chlorides) upon the mechanical disintegration of sandstone can be expected.     

Identification of motion parameters from spatio-temporal atmospheric temperature patterns

In near-calm conditions it is difficult to make direct measurements of atmospheric advection reliably and cheaply, particularly at many points over a large area. An alternative indirect method is examined using time-series measurements of atmospheric temperature (or any other convenient conserved field variable) at points on a spatial grid.System identification methodology is applied to analyze atmospheric temperature data obtained in such near-calm conditions during an experiment with a low-flying helicopter. A three-parameter numerical model of atmospheric advection has been identified in the temperature data, the advection parameters being an eddy diffusion coefficient and horizontal components of the wind velocity. It has been demonstrated by analysis of all the assumptions, and using simulated data, that in this case the standard least-square procedure can be applied to recover sensible parameter estimates, even though the model is of the error-in-variables type and parameters appear to change abruptly at certain moments of time (but by a reasonably small amount). The parameter estimates have been validated against independent data.     

Detailed 1×1° gravimetric Indian Ocean geoid and comparison with GEOS-3 radar altimeter geoid profiles

Summary. A new set of 1×1° mean free-air anomalies in the Indian Ocean is determined on the basis of previously published free-air anomaly maps (Talwani & Kahle) and the most recent Lamont surface ship gravity measurements. The data are then used to compute a (total) 1×1° gravimetric Indian Ocean geoid. The computation is carried out by combining the Goddard Space Flight Center (GSFC) GEM-6 geoid and a difference geoid that corresponds to the differences between the set of 1×1° surface gravity values and the GEM-6 gravity anomalies. The difference geoid is highest over the Madagascar Ridge (+ 20 m) and lowest over the Timor Trough (-30 m). The total geoid is compared with GEOS-3 radar altimeter derived geoid profiles and geophysical implications are discussed.     

A study of intergranular and fissure permeability in Chalk and Permian aquifers,using double-packer injection testing

Double-packer injection tests have been carried out in a borehole in the Chalk of Hampshire and a borehole in the Permian Penrith Sandstone of Cumbria, England. The tests have been supplemented by borehole logging and television inspections and by laboratory measurements on cores. A new mathematical treatment has enabled results to be calculated for injection test intervals containing fissures. In both formations, transmissivity immediately around the borehole is dominated by a few major fissures. In the Penrith Sandstone there is good agreement between intergranular hydraulic conductivity measurements and packer-test results in the portions of the borehole which do not contain major fissures. In the Chalk, the packer-test values are always higher than the intergranular measurements, suggesting that some degree of fissuring is present throughout.     

Hydrodynamic coefficients of a monolithic circular offshore structure

Expressions for both the rectilinear and rotational inertial and damping coefficients for a circular monolithic tower of uniform radius are derived. The analysis matches the fluid velocity, derived from potential theory, with the structural velocity in sway. That is, the motions of the tower are assumed to be in a vertical plane. The analysis is then applied to a tower composed of (lumped-mass) elements, where the expressions for the added-mass and damping coefficients are shown to be functions of wave number. The added-mass is shown to be a product of two wave systems: a travelling wave system, which is responsible for the radiation damping, and a standing wave system, called the evanescent system, which is attached to the structure. The added-mass of the evanescent system is negative for small wave numbers, while that of the travelling waves is positive. The negative sign simply means that the inertial force of the evanescent waves is 180° out of phase with that of the travelling system. Furthermore, it is shown that the contributions of the two wave systems to the total added-mass of the structure counteract each other, resulting in a total added-mass which varies gradually with the wave number. Finally, the analysis is applied to an experiment, and results of the analysis and the experiment are found to agree rather well.     

Quantifying the seasonal variations in fluvial and eolian sources of terrigenous material to Cariaco Basin,Venezuela

The varved sediments that accumulate in the Cariaco Basin provide a detailed archive of the region’s climatic history, including a record of the quantity of fluvial and wind-transported material. In this study, we examine the sedimentological characteristics (clay mineralogy and grain size) of both surface sediments and sinking lithogenic material collected from sediment trap samples over a three-year period from 1997 to 2000. Data from biweekly sediment trap samples show a tri-modal particle size distribution, with prominent peaks at 2, 22 and 80 μm, indicating sediment contributions from both eolian and fluvial sources. The clay mineralogy of the water column samples collected from 1997 to 1999 also shows distinctive characteristics of eolian and fluvial material. An examination of surface sediment samples from the Cariaco Basin indicates that the Unare River is the main source of riverine sediments to the eastern sub-basin. By combining these sedimentological proxies, we estimate that ～10% of the terrigenous material delivered to the Cariaco Basin is eolian, while ～90% is fluvial. This represents an annual dust accumulation rate of ～0.59 mg/cm²/yr. Since aerosols are closely linked to climate variability, the ability to quantify paleo-dust fluxes using sedimentological characteristics will be a useful tool for future paleoclimate studies looking at sub-Saharan aridity and latitudinal migration of the Intertropical Convergence Zone.     

Grain size along two gravel-bed rivers: statistical variation,spatial pattern and sedimentary links

A new set of field data facilitates a detailed analysis of variations in bed material grain size within two confluent gravel-bed rivers in northeastern British Columbia, Canada. A preliminary assessment of grain-size variability establishes a basis for examination of the spatial pattern of grain-size change. Standard ANOVA techniques are inappropriate because individual samples have unequal variances and are not normally distributed. Alternative tests for homoscedasticity and comparison of means are therefore utilized. Within-site, between-sample variability is not significant. The grain-size distributions that were obtained at individual sites are therefore representative of the depositional environments that were sampled. In both rivers mean grain size does vary significantly between sites and there is therefore a basis for examining the data for spatial patterns such as downstream fining. Textural variations along the two rivers studied here are complex and show negligible overall fining (in over 100 km). This is the consequence of a large number of tributary inputs and non-alluvial sediment sources which are the legacy of Late Pleistocene glaciation. The identification of lateral sources like these is fundamental for understanding textural changes within rivers. The sedimentary link (a channel reach between significant lateral sediment inputs) provides a means of isolating fluvial maturation processes (abrasion and sorting) from contingent lateral inputs. Strong fining trends are apparent in most links and classification of grain-size measurements according to their location within particular links greatly improves the statistical explanation of textural variation. Identification of sedimentary links provides a means of applying models of fluvial fining processes, so isolation of link networks will aid the development of basin-scale models of textural variation. © 1998 John Wiley & Sons, Ltd.     

Toxicities of antifouling biocide Irgarol 1051 and its major degraded product to marine primary producers

Irgarol 1051 (2-methythiol-4-tert-butylamino-6-cyclopropylamino-s-triazine) is an algaecide commonly used in antifouling paints. It undergoes photodegradation which yields M1 (2-methylthio-4-tert-butylamino-6-amino-s-triazine) as its major and most stable degradant. Elevated levels of both Irgarol and M1 have been detected in coastal waters worldwide; however, ecotoxicity effects of M1 to various marine autotrophs such as cyanobacteria are still largely unknown. This study firstly examined and compared the 96 h toxicities of Irgarol and M1 to the cyanobacterium Chroococcus minor and two marine diatom species, Skeletonema costatum and Thalassiosira pseudonana. Our results suggested that Irgarol was consistently more toxic to all of the three species than M1 (96 h EC50 values: C. minor, 7.71 microug L(-1) Irgarol vs. > 200 microg L(-1) M1; S. costatum, 0.29 microg L(-1) Irgarol vs. 11.32 microg L(-1)M1; and T. pseudonana, 0.41 microg L(-1) Irgarol vs. 16.50 microg L(-1)M1). Secondly, we conducted a meta-analysis of currently available data on toxicities of Irgarol and M1 to both freshwater and marine primary producers based on species sensitivity distributions (SSDs). Interestingly, freshwater autotrophs are more sensitive to Irgarol than their marine counterparts. For marine autotrophs, microalgae are generally more sensitive to Irgarol than macroalgae and cyanobacteria. With very limited available data on M1 (i.e. five species), M1 might be less toxic than Irgarol; nonetheless this finding warrants further confirmation with additional data on other autotrophic species.