Evaluation of an empirical orthogonal function–based method to downscale soil moisture patterns based on topographical attributes

Soil moisture influences many hydrologic applications including agriculture, land management and flood prediction. Most remote‐sensing methods that estimate soil moisture produce coarse resolution patterns, so methods are required to downscale such patterns to the resolutions required by these applications (e.g. 10‐ to 30‐m grid cells). At such resolutions, topography is known to affect soil moisture patterns. Although methods have been proposed to downscale soil moisture based on topography, they usually require the availability of past high‐resolution soil moisture patterns from the application region. The objective of this article is to determine whether a single topographic‐based downscaling method can be used at multiple locations without relying on detailed local observations. The evaluated downscaling method is developed on the basis of empirical orthogonal function (EOF) analysis of space–time soil moisture data at a reference catchment. The most important EOFs are then estimated from topographic attributes, and the associated expansion coefficients are estimated on the basis of the spatial‐average soil moisture. To test the portability of this EOF‐based method, it is developed separately using four data sets (Tarrawarra, Tarrawarra 2, Cache la Poudre and Satellite Station), and the relationships that are derived from these data sets to estimate the EOFs and expansion coefficients are compared. In addition, each of these downscaling methods is applied not only for the catchment where it was developed but also to the other three catchments. The results suggest that the EOF downscaling method performs well for the location where it is developed, but its performance degrades when applied to other catchments. Copyright © 2011 John Wiley & Sons, Ltd.     

Biological and Geochemical Record of Anthropogenic Impacts in Recent Sediments from Lake Pupuke, Auckland City, New Zealand

Frozen sediment cores from Lake Pupuke in Auckland City, New Zealand, contain a high resolution decadal to annual scale record of changing lake paleoenvironments and geochemistry that reflects changing landuse and hydrology in the catchment over the past c. 190 years. A reliable chronology is available from AMS ¹⁴C and ²¹⁰Pb dating of the sediments, with the timing of the older part of the record supported by the first appearance of pollen of introduced Pinus and Plantago lanceolata associated with European settlement of Auckland in the early 1840s. Diatom stratigraphy, sediment elemental and carbon isotope geochemistry reflect changes in sediment sources and lake conditions commensurate with European development of the Lake Pupuke catchment, in particular enhanced algal productivity controlled by the influx of nutrients after c. 1920 AD. Attempts to prevent nuisance algal blooms in 1933, 1934 and 1939 using CuSO₄ addition produced Cu spikes in the sediment that allowed confirmation of the accuracy of the ²¹⁰Pb chronology. Hence, the elemental and isotopic composition of the Lake Pupuke sediments reflect the timing of significant anthropogenic activities, rather than climatic variations, that have occurred within the watershed over the past c. 190 years. The comparison of records of land use change in the catchment with the multi-proxy record of changes in the sediments usually allowed unambiguous identification of the signatures of change and their causes.     

Upwelling in the Alaskan Beaufort Sea: Atmospheric forcing and local versus non-local response

The spin up and relaxation of an autumn upwelling event on the Beaufort slope is investigated using a combination of oceanic and atmospheric data and numerical models. The event occurred in November 2002 and was driven by an Aleutian low storm. The wind field was strongly influenced by the pack-ice distribution, resulting in enhanced winds over the open water of the Chukchi Sea. Flow distortion due to the Brooks mountain range was also evident. Mooring observations east of Barrow Canyon show that the Beaufort shelfbreak jet reversed to the west under strong easterly winds, followed by upwelling of Atlantic Water onto the shelf. After the winds subsided a deep eastward jet of Atlantic Water developed, centered at 250 m depth. An idealized numerical model reproduces these results and suggests that the oceanic response to the local winds is modulated by a propagating signal from the western edge of the storm. The disparity in wave speeds between the sea surface height signal—traveling at the fast barotropic shelf wave speed—versus the interior density signal—traveling at the slow baroclinic wave speed—leads to the deep eastward jet. The broad-scale response to the storm over the Chukchi Sea is investigated using a regional numerical model. The strong gradient in windspeed at the ice edge results in convergence of the offshore Ekman transport, leading to the establishment of an anti-cyclonic gyre in the northern Chukchi Sea. Accordingly, the Chukchi shelfbreak jet accelerates to the east into the wind during the storm, and no upwelling occurs west of Barrow Canyon. Hence the storm response is fundamentally different on the Beaufort slope (upwelling) versus the Chukchi slope (no upwelling). The regional numerical model results are supported by additional mooring data in the Chukchi Sea.     

Land tenure type as an underrated legal constraint on the conservation management of coastal dunes: examples from Ireland

Legal factors play an underrated but significant role as constraints on conservation management. In this paper, based on observations in both Northern Ireland and the Republic of Ireland, mode of land tenure is assessed to determine its influence on the conservation management of coastal dunes. The tenure types considered are: private ownership, corporate private ownership, tenancy, secured tenancy, leasing, common (joint) ownership, uncertain ownership, public ownership and its subset military ownership. It is suggested that multiple private ownership is least likely to favour effective conservation management. Public ownership by a statutory conservation authority and corporate private ownership by a conservation-orientated NGO are regarded as the optimum tenure types for conservation management of coastal dunes.     

The effect of tidal inlets on open coast storm surge hydrographs

Bridge scour modeling requires storm surge hydrographs as open ocean boundary conditions for coastal waters surrounding tidal inlets. These open coast storm surge hydrographs are used to accurately determine both horizontal and vertical circulation patterns, and thus scour, within the inlet and bay for an extreme event. At present, very little information is available on the effect that tidal inlets have on these open coast storm surge hydrographs. Furthermore, current modeling practice enforces a single design hydrograph along the open coast boundary for bridge scour models. This study expands on these concepts and provides a more fundamental understanding on both of these modeling areas.     

In situ Raman observation of the crystallization in NaNO3–Na2SO4–H2O solution droplets

Several double salts have been detected in building materials and most of these salts are incongruently soluble compounds. In contrast to single salts, however, no systematic investigations of the crystallization behavior and deleterious effects of incongruently soluble double salts exist. To assess the damage potential of these salts, a systematic investigation of their highly complex behavior is desirable. This paper deals with the crystallization behavior of various solids in the ternary mixed NaNO₃–Na₂SO₄ system including the formation of the double salt darapskite, Na₃NO₃SO₄·H₂O. The crystallization sequence during droplet evaporation experiments at room conditions was determined using Raman and polarization microscopy. The basic idea of this research is to use deviations of the crystallization sequence of a salt or a mixed salt solution from the equilibrium pathway as an indicator to detect the degree of supersaturation. The observed crystallization pathway includes the formation of the metastable phases Na₂SO₄(III), Na₂SO₄(V) and darapskite. The experimental observations are discussed on the basis of the NaNO₃–Na₂SO₄–H₂O phase diagram and the results provide evidence for crystal growth from highly supersaturated solutions in both systems. If the crystals growing under these conditions are confined, these supersaturations result in substantial crystallization pressures.     

Sources and sinks for atmospheric H2: A current analysis with projections for the influence of anthropogenic activity

Oxidation of CH₄ provides the major source for atmospheric H₂ which is removed mainly by reaction with OH. Biological activity at the Earth's surface appears to represent at most a minor sink for H₂. Anthropogenic activity is a significant source for both H₂ and CO in the present atmosphere and may be expected to exert a growing influence in the future. Models are presented which suggest a rise in the mixing ratio of H₂ from its present value of 5.6 × 10^?7 to about 1.8 × 10^?6 by the year 2100. The mixing ratio of CO should grow from 9.7 × 10^?8 to 2.3 × 10^?7 over the same time period and there should be a rise in CH₄ by about a factor of 1.5 associated with anthropogenically induced reductions in tropospheric OH.