Rare earth elements in tourmaline and chlorite from tin-bearing assemblages: Factors controlling fractionation of REE in hydrothermal systems

The REE distribution in minerals from tin-bearing ore-magmatic systems of the Russian Far East, including the Komsomolsk, Khingan, and Badzhal districts in the Amur region and the Kavalerovo, Lesozavodsk, Voznesenka, Furmanovo, and other districts in Primorsky krai, has been studied. The main attention was focused on tourmaline and chlorite; in addition, associated biotite, feldspar, apatite, fluorite, and carbonates were examined. The major factors affecting the REE distribution in the studied minerals are the temperature, Eh, and pH of the mineral-forming medium; crystal chemistry; partition coefficients of REE between fluid and minerals; and complexation that disturbs the coherent behavior of REE. Fluid evolution at different stages is characterized.     

Soil-to-dwelling radon isotope ratio in the Baikal region

Relations between indoor and soil gas radon were experimentally studied in villages of the Baikal region. On the basis of the obtained data, the soil-to-indoor radon ratio was calculated, which can be used for prediction of radon pollution in buildings of the same kind.     

Tectonic Evolution and Continental Growth in Altai Orogen, China: Constrained by Geochronology and Nd Isotopic Mapping of Intrusions

The Central Asia Orogenic Belt is the world's largest Phanerozoic accretionary orogen. The Altai orogen was key to understand the orogeny. Voluminous intrusions occur in the Chinese Altai orogen.     

Regional conductance map of Andaman and Nicobar region

To image the electrical conductivity distribution, fluxgate magnetometers are operated at five sites in Andaman and Nicobar region. Transfer functions are estimated for the period range 8–128 min, from nighttime transient geomagnetic variations, using robust regression analysis. The observed induction arrows in Andaman Islands are found to point towards east despite deep sea located towards its west. This indicates that fore-arc basin (Andaman–Nicobar deep) is more conducting than the region of outer non-volcanic Island arc.Thin sheet model requires the conductance of 10,000–35,000 S (with increase conductivity towards the south) for explaining the observed induction pattern. The observed induction pattern at Andaman–Nicobar stations can be explained in terms of high conducting Cretaceous–Tertiary sediments filling the Andaman–Nicobar deep. High conductivity over Invisible bank has been attributed to the partial melts/volatile fluids derived from the subducting Indian plate that are intruding into the eastern margin of fore-arc basin through the West Andaman Fault (WAF).The induction pattern at Great Nicobar station (Campbell Bay) may be related to the highly conducting sediments filling the Mergui basin along with mafic intrusions. Also crustal transition occurs below the Mergui Terrace at the Malayan coast contributing to the enhanced conductivity anomaly.     

Lake bank filtration at Nainital,India: water-quality evaluation

There are different water-supply schemes in Uttarakhand, India to tap the water from streams, rivers and lakes. At Nainital, seven tube-wells (depths 22.6–36.7 m), located at a distance of <100 m from the lake, are being used to abstract (1) lake water after passage through the soil and (2) subsurface water/groundwater flowing towards the lake. Water samples from the lake and tube-wells were analyzed in monsoon and non-monsoon periods from 1997 to 2006. Total dissolved solids, EC, alkalinity and hardness were found to be marginally greater in tube-well waters. The difference in hydrochemistry of tube-well water was mainly due to variation in flow regimes during monsoon and non-monsoon periods. Results clearly indicate that lake water as such is not potable as it contains unacceptable levels of organic matter in terms of COD (~44 mg/L), coliforms (~15.6 × 10⁴ MPN/100 mL) and nutrients. Coliform bacteria and COD have not been detected in any of the tube-well water samples over the years. Lake water, treated by sand filters did not conform to drinking water standards. These investigations have led to the closure of the treatment facility and installation of two tube-wells in addition to the existing five tube-wells.

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Résumé  Il existe divers projets d’alimentation en eau dans l’état d’Uttarakhand, Inde, afin de capter l’eau de ruisseaux, de rivières et de lacs. A Nainital, sept puits tubés (profondeur de 22.6–36.7 m), situés à une distance < à 100 m du lac, sont utilisés pour prélever (1) de l’eau du lac après transit à travers le sol et (2) de l’eau de sub-surface/eau souterraine s’écoulant vers le lac. Des échantillons d’eau du lac et des puits tubés ont été analysés en périodes de mousson et de celles sans mousson 1997 à 2006. Résidu sec, C.E., alcalinité et dureté ont été trouvés marginalement supérieurs dans l’eau des puits tubés. La différence d’hydrochimie de l’eau des puits tubés était surtout due à la variation des régimes d’écoulement pendant les périodes de mousson et de celles sans mousson. Les résultats indiquent clairement que l’eau du lac en tant que telle n’est pas potable car elle contient des teneurs inacceptables de matière organique en termes de COD (~44 mg/L), de coliformes (~15.6 × 10⁴ MPN/100 mL) et d’éléments nutritifs. Des bactéries coliformes et du COD n’ont été détectés dans aucun des échantillons d’eau de puits tubés au fil des années. L’eau du lac traitée par des filtres à sable ne se conformait pas aux normes de l’eau potable. Ces recherches ont conduit à la fermeture de l’installation de traitement et à l’implantation de deux puits tubés en plus des cinq puits existants.

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Resumen  En el estado de Uttarakhand, India, existen diferentes esquemas de abastecimiento de agua que explotan agua de arroyos, ríos y lagos. En Nainital, siete pozos (profundidades entre 22.6–36.7 m), ubicados a una distancia de <100 m del lago, se usan para extraer (1) agua del lago luego de su pasaje a través del suelo y (2) agua superficial y subterránea que fluye hacia el lago. En períodos de monzón y de no monzón de 1997 a 2006 se han analizado muestras de agua del lago y de las captaciones. Se halló que el agua de los pozos es ligeramente mayor en términos del total de sólidos disueltos, la conductividad eléctrica, la alcalinidad y la dureza. La diferencia en la hidroquímica del agua de las perforaciones se debe principalmente a la variación de los regímenes de flujo durante los períodos de monzón y de no monzón. Los resultados claramente indican que el agua del lago no es potable por su contenido inaceptable de materia orgánica medida como demanda de carbono orgánico/oxígeno –DCO- (~44 mg/L), coliformes (~15.6 × 10⁴ NMP/100 mL) y nutrientes. En el período, no se han detectado bacterias coliformes ni DCO en las muestras de agua de las captaciones. El agua del lago, tratada con filtros de arena, no conformó los estándares de agua para bebida. Estas investigaciones han demostrado la necesidad de clausurar las instalaciones de tratamiento y la adición de dos captaciones a las cinco ya existentes.

     

The Meso-Cenozoic thermo-tectonic evolution of the Eastern Pyrenees: an <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar fission track and (U–Th)/He thermochronological study of the Canigou and Mont-Louis massifs

Vertical displacements on the SW–NE Têt fault (Eastern Pyrenees Axial Zone, France), which separates the Variscan Canigou-Carança and Mont-Louis massifs, were constrained using a thermochronologic multi-method approach. ⁴⁰Ar/³⁹Ar data from the granitic Mont-Louis massif record its Variscan cooling history and reveal no ages younger than Early Cretaceous, while the Canigou-Carança gneiss massif records systematically younger ⁴⁰Ar/³⁹Ar ages. These younger ⁴⁰Ar/³⁹Ar ages in the Canigou-Carança gneiss massif are the result of partial to total rejuvenation of argon isotopic systems related to a thermal flow coeval with the Cretaceous HT-BP metamorphism in the North Pyrenean Zone. Only the deepest rocks from the Canigou-Carança suffered this extensive Mid-Cretaceous thermal overprint probably due to differential burial around 4 km at that time. The post Mid-Cretaceous vertical displacements along the Têt fault are recorded by “low” temperature thermochronology using K-feldspar ⁴⁰Ar/³⁹Ar, zircon and apatite fission track and (U–Th)/He datings. The Mont-Louis granite samples experienced a long period of protracted cooling reflecting a lack of thermo-tectonic activity in this area from Late Palaeozoic to Early Cenozoic, followed by cooling from 55–60 Ma to Late Eocene at a mean rate of 15–20°C/Ma in the final stage. This cooling stage corresponds to Têt fault reactivation with a reversed component, promoting exhumation of the Mont-Louis roof zone contemporaneously with the south-vergent Pyrenean thrusting. In the Canigou-Carança massif, the main cooling event occurred from 32 to 18 Ma at a maximum rate of 30°C/Ma during Early Oligocene followed by a more moderate rate of 3°C/Ma from Late Oligocene to Early Burdigalian, coeval with the normal reactivation of the Têt fault in brittle conditions that accommodated the final exhumation of the massif during the opening of the Gulf of Lion.     

The role of overwash in the evolution of mixing zone morphology within barrier islands

Overwash is a major controlling factor in the morphology of the mixing zone of coastal aquifers. Conceptual models of the mixing zone describe an interface controlled by tidal oscillations, wave run-up, and other factors; however, few describe the influence of large storm events. In August 1993, Hatteras Island, North Carolina, USA, experienced a 3-m storm surge due to Hurricane Emily. Sound-side flooding infiltrated a wellfield, causing a dramatic increase in TDS levels that persisted for more than 3 years. Two-dimensional simulations with SUTRA, the USGS finite-element model, are calibrated to the TDS breakthrough data of this storm to infer model dispersivity values. Simulations using the calibrated dispersivity values, predicted flooding levels, and 54 years of hurricane records to determine the influence of the overwash events suggest that it is rare for the mixing zone to approximate the conceptual morphology. Even during quiescent periods such as between 1965 and 1975, TDS levels do not return to theoretical levels before being elevated by a subsequent storm event. Thus, while tidal oscillations and other factors are important to mixing zone development, basic wind events and more severe storm events may have more influence and lasting effect on the morphology of the mixing zone.     

Surface water–groundwater interaction and chemistry in a mineral-armored hydrothermal outflow channel, Yellowstone National Park, USA

Small quantities of groundwater interact with hydrothermal surface water to drive in-stream geochemical processes in a silica-armored hot-spring outflow channel in Yellowstone National Park, USA. The objective of this study was to characterize the hydrology and geochemistry of this unique system in order to (1) learn more about the Yellowstone Plateau’s subsurface water mixing between meteoric and hydrothermal waters and (2) learn more about the chemical and physical processes that lead to accumulation of streambed cements, i.e., streambed armor. A combination of hydrological, geochemical, mineralogical, microscopic, and petrographic techniques were used to identify groundwater and surface-water exchange. Interaction could be identified in winter because of differences in surface water and groundwater composition but interaction at other times of the year cannot be ruled out. Dissolved constituents originating from groundwater (e.g., Fe(II) and Mg) were traced downstream until oxidation and/or subsequent precipitation with silica removed them, particularly where high affinity substrates like cyanobacterial surfaces were present. Because the stream lies in a relatively flat drainage basin and is fed mainly by a seasonally relatively stable hot spring, this system allowed study of the chemical processes along a stream without the obscuring effects of sedimentation.     

High-resolution seismic analysis of the coastal Mecklenburg Bay (North German Basin): the pre-Alpine evolution

The pre-Alpine structural and geological evolution in the northern part of the North German Basin have been revealed on the basis of a very dense reflection seismic profile grid. The study area is situated in the coastal Mecklenburg Bay (Germany), part of the southwestern Baltic Sea. From the central part of the North German Basin to the northern basin margin in the Grimmen High area a series of high-resolution maps show the evolution from the base Zechstein to the Lower Jurassic. We present a map of basement faults affecting the pre-Zechstein. The pre-Alpine structural evolution of the region has been determined from digital mapping of post-Permian key horizons traced on the processed seismic time sections. The geological evolution of the North German Basin can be separated into four distinct periods in the Rerik study area. During Late Permian and Early Triassic evaporites and clastics were deposited. Salt movement was initiated after the deposition of the Middle Triassic Muschelkalk. Salt pillows, which were previously unmapped in the study area, are responsible for the creation of smaller subsidence centers and angular unconformities in the Late Triassic Keuper, especially in the vicinity of the fault-bounded Grimmen High. In this area, partly Lower Jurassic sediments overlie the Keuper unconformably. The change from extension to compression in the regional stress field remobilized the salt, leading to a major unconformity marked at the base of the Late Cretaceous.