Zinc speciation in the Northeastern Atlantic Ocean

Measurements of zinc and zinc complexation by natural organic ligands in the northeastern part of the Atlantic Ocean were made using cathodic stripping voltammetry with ligand competition. Total zinc concentrations ranged from 0.3 nM in surface waters to 2 nM at 2000 m for open-ocean waters, whilst nearer the English coast, zinc concentrations reached 1.5 nM in the upper water column. In open-ocean waters zinc speciation was dominated by complexation to a natural organic ligand with conditional stability constant (log K_ZnL′) ranging between 10.0 and 10.5 and with ligand concentrations ranging between 0.4 and 2.5 nM. The ligand was found to be uniformly distributed throughout the water column even though zinc concentrations increased with depth. Organic ligand concentrations measured in this study are similar to those published for the North Pacific. However the log K_ZnL′ values for the North Atlantic are almost and order of magnitude lower than those reported by Bruland [Bruland, K.W., 1989. Complexation of zinc by natural organic-ligands in the central North Pacific. Limnol. Oceanogr., 34, 269–285.] using anodic stripping voltammetry for the North Pacific. Free zinc ion concentrations were low in open-ocean waters (6–20 pM) but are not low enough to limit growth of a typical oceanic species of phytoplankton.     

Effects of polynuclear aromatic hydrocarbons on lysosomal membranes in molluscs

Lysosomal sequestration of polynuclear aromatic hydrocarbons (PNAHs), a major class of environmental contaminant, is a well-established phenomenon;¹ considerably less is known about their pathological effects on lysosomes. Marine molluscs contain a number of lysosome-rich tissues and PNAHs are known to induce deleterious alterations in lysosomal structure and latency of lysosomal enzymes.² The latter are presumed to involve destabilisation of the lysosomal membrane, resulting in increased permeability and reduced enzyme latency. If lysosomal injury involves derangement of membrane-lipid structure due to the interaction of PNAHs then it would be expected that membrane damage would be closely linked to the structural characteristics of the intruding molecule. Our results show that the effects of the isomeric PNAHs phenanthrene and anthracene on digestive cell lysosomal stability were markedly different in the marine mussel (Mytilus edulis) over the same range of tissue concentrations. Lysosomal membrane stability was determined using a cytochemical test for enzyme latency.³     

A new concept of a hull form to improve wave response characteristics for marine construction barges

The object of the new hull form is to provide a single hull which possesses long natural periods of roll and heave and has substantially reduced motion response amplitudes in very high sea states. Model tests and preliminary estimates indicated that the new hull form can be designed for roll and heave motions nearly equivalent to those of much larger semisubmersible units.All existing conventional marine construction barges have rectangular cross section hull. The new hull form consists of a system of upper side tanks and lower side tanks added onto a rectangular cross section hull. The upper tanks and lower tanks form longitudinal troughs on the port and starboard sides. Structural grillage of any open type is to connect the upper and lower tanks at the side of the vessel. Figure 1 indicates a profile and a typical transverse section of the new hull form. The new hull comprises the concept of reduced water plane area which is turn results in low transverse metacentric height and low tons per in. immersion. The novel features of combining low GM_T and low TPI with extremely heavy damping and added mass of the entrained water characteristics result in very long natural periods of roll and heave and considerably small rolling and heaving amplitudes in high sea states. The open side shell plating on the side of the vessel functions to dissipate wave energy at the side of the vessel which would have otherwise been transmitted to the vessel and caused the vessel to respond. This paper presents the conceptual foundation and outline of the new hull form. Model test results are presented and implemented. Also presented is the design philosophy.