Influence of m-cresol purple indicator additions on the pH of seawater samples: correction factors evaluated from a chemical speciation model

The perturbation of the indicator m-cresol purple on the pH in seawater is illustrated in diagrams, representing measurements in 1-cm and 5-cm cells. The diagrams apply to a measured pH interval of 7.4–8.4 using a 2-mM stock solution of m-cresol purple sodium salt dissolved in seawater. The magnitude of the perturbation is described as correction values, i.e., the change in seawater pH caused by the indicator. The diagrams are based on calculations made by using the equilibrium speciation programme, MARINHALT. From these calculations, and least squares fitting methods, pH correction values are described in terms of the pH difference between each seawater sample and the pH of an indicator stock solution. Calculations are performed for a typical high latitude water and a north Pacific deep water. Diagrams are presented for a salinity of 35 and a temperature of 15°C. Responses to salinities between 32 and 36 and temperatures 15–25°C are illustrated as well. A ±0.05 pH difference between a seawater sample and an indicator stock solution gives a correction of less than 0.001 pH unit for a 1-cm cell. For a 5-cm cell, pH differences between the indicator stock solution and a seawater sample as large as ±0.3 cause corrections smaller than ±0.001 pH unit. Calculations demonstrate that the five-fold lower indicator concentration used with 5-cm cells decreases the perturbation effect by approximately a factor of five relative to 1-cm cells.     

A Long-Term Decrease of the Mid-Size Segmentation Lengths Observed in the He <Emphasis Type="SmallCaps">ii</Emphasis> (30.4 nm) Solar EUV Emission

Power spectra of segmentation-cell length (a dominant length scale of EUV emission in the transition region) from full-disk He?ii extreme ultraviolet (EUV) images observed by the Extreme ultraviolet Imaging Telescope (EIT) onboard the Solar and Heliospheric Observatory (SOHO) and the Atmospheric Imaging Assembly (AIA) onboard the Solar Dynamics Observatory (SDO) during periods of quiet-Sun conditions for a time interval from 1996 to 2015 were analyzed. The spatial power as a function of the spatial frequency from about 0.04 to 0.27 (EIT) or up to 0.48 (AIA) Mm^?1 depends on the distribution of the observed segmentation-cell dimensions – a structure of the solar EUV network. The temporal variations of the spatial power reported by Didkovsky and Gurman (Solar Phys. 289, 153, 2014) were suggested as decreases at the mid-spatial frequencies for the compared spectra when the power curves at the highest spatial frequencies of 0.5 pix^?1 were adjusted to match each other. This approach has been extended in this work to compare spectral ratios at high spatial frequencies expressed in the solar spatial frequency units of Mm^?1. A model of EIT and AIA spatial responses allowed us to directly compare spatial spectral ratios at high spatial frequencies for five years of joint operation of EIT and AIA, from 2010 to 2015. Based on this approach, we represent these ratio changes as a long-term network transformation that may be interpreted as a continuous dissipation of mid-size network structures to the smaller-size structures in the transition region. In contrast to expected cycling of the segmentation-cell dimension structures and associated spatial power in the spectra with the solar cycle, the spectra demonstrate a significant and steady change of the EUV network. The temporal trend across these structural spectra is not critically sensitive to any long-term instrumental changes, e.g. degradation of sensitivity, but to the change of the segmentation-cell dimensions of the EUV network structure.     

Mercury in some granitoid rocks of the yukon and its relation to gold-tungsten mineralization

Data for the mean mercury contents of some granitoid rocks of the Yukon are presented. A correlation of high mercury content with plutons postulated to be the sources, or genetically related to the sources, of the alluvial gold deposits of the McQuesten area is established. In addition a relation is indicated between high mercury content in one intrusion and high content in the Palaeozoic shale host rock. A limited amount of data is presented on the mercury content of the Proterozoic and Palaeozoic rocks of the sampled area.     

Climatic and geographic factors affect ecosystem multifunctionality through biodiversity in the Tibetan alpine grasslands

Ecosystem multifunctionality(EMF), the simultaneous provision of multiple ecosystem functions, is often affected by biodiversity and environmental factors. We know little about how the interactions between biodiversity and environmental factors affect EMF. In this case study, a structural equation model was used to clarify climatic and geographic pathways that affect EMF by varying biodiversity in the Tibetan alpine grasslands. In addition to services related to carbon, nitrogen, and water cycling, forage supply, which is related to plantproductivity and palatability, was included in the EMF index. The results showed that 72% of the variation in EMF could be explained by biodiversity and other environmental factors. The ratio of palatable richness to all species richness explained 8.3% of the EMF variation. We found that air temperature, elevation, and latitude all affected EMF, but in different ways. Air temperature and elevation impacted the aboveground parts of the ecosystem, which included plant height, aboveground biomass, richness of palatable species, and ratio of palatable richness to all species richness. Latitude affected EMF by varying both aboveground and belowground parts of the ecosystem, which included palatable speciesrichness and belowground biomass. Our results indicated that there are still uncertainties in the biodiversity–EMF relationships related to the variable components of EMF, and climatic and geographic factors. Clarification of pathways that affect EMF using structural equation modeling techniques could elucidate the mechanisms by which environmental changes affect EMF.     

Simulation of the full two rigid body problem using polyhedral mutual potential and potential derivatives approach

Herein we investigate the coupled orbital and rotational dynamics of two rigid bodies modelled as polyhedra, under the influence of their mutual gravitational potential. The bodies may possess any arbitrary shape and mass distribution. A method of calculating the mutual potential’s derivatives with respect to relative position and attitude is derived. Relative equations of motion for the two body system are presented and an implementation of the equations of motion with the potential gradients approach is described. Results obtained with this dynamic simulation software package are presented for multiple cases to validate the approach and illustrate its utility. This simulation capability is useful both for addressing questions in dynamical astronomy and for enabling spacecraft missions to binary asteroid systems.     

Evolution of the north flank of Tenerife by recurrent giant landslides

Geomorphologic analysis of submarine and subaerial surface features using a combined topographic/bathymetric digital elevation model coupled with onshore geological and geophysical data constrain the age and geometry of giant landslides affecting the north flank of Tenerife. Shaded relief and contour maps, and topographic profiles of the submarine north flank, permit the identification of two generations of post-shield landslides. Older landslide materials accumulated near the shore (<40-km) and comprise 700 km³ of debris. Thickening towards a prominent axis suggests one major landslide deposit. Younger landslide materials accumulated 40–70 km offshore and comprise the products of three major landslides: the La Orotava landslide complex, the Icod landslide and the East Dorsal landslide complex, each with an onshore scar, a proximal submarine trough, and a distal deposit lobe. Estimated lobe volumes are 80, 80 and 100 km³, respectively. The old post-shield landslide scar is an amphitheatre, 20–25 km wide, partly submarine, now completely filled with younger materials. Age–width relationships for Tenerife's coastal platform plus onshore geological constraints suggest an age of ca. 3 Ma for the old collapse. Young landslides are all less than 560 ka old. The La Orotava and Icod slides involved failures of slabs of subaerial flank to form the subaerial La Orotava and Icod valleys. Offshore, they excavated troughs by sudden loading and basal erosion of older slide debris. The onshore East Dorsal slide also triggered secondary failure of older debris offshore. The slab-like geometry of young failures was controlled by weak layers, deep drainage channels and flank truncation by marine erosion. The (partly) submarine geometry of the older amphitheatre reflects the absence of these features. Relatively low H/L ratios for the young slides are attributed to filling of the slope break at the base of the submarine edifice by old landslide materials, low aspect ratios of the failed slabs and channelling within troughs. Post-shield landslides on Tenerife correlate with major falls in sea level, reflecting increased rates of volcanism and coastal erosion, and reduced support for the flank. Landslide head zones have strongly influenced the pattern of volcanism on Tenerife, providing sites for major volcanic centres.