Ground-air temperature tracking and multi-year cycles in the subsurface temperature time series at geothermal climate-change observatory

Long-term observations of air, near-surface (soil) and ground temperatures, collected between 1994 and 2011, monitored in the Geothermal Climate Change Observatory at Spo?ilov, Prague (GCCO) are analyzed to better understand the relationship between these quantities and to describe the mechanism of heat transport at the land-atmosphere boundary layer. The 17 years long monitoring series provided a surprisingly small mean ground-air temperature offset of only 0.31 K with no clear annual course and with the offset value changing irregularly even on a daily scale. Such value is substantially lower than similar values (1–2 K and more) found elsewhere, but it may be well characteristic for a mild temperate zones, when all so far available information referred rather to more southern locations. As many other observed geophysical data, temperature time series consist of a systematic pattern (usually a set of identifiable components) contaminated by random noise, which makes the identification of the proper pattern difficult. To identify the existing systematic patterns (cycles) of the temperature-time series at several depth levels in the investigated depth interval 0–40 m, the observed data were processed with the help of the Fast Fourier Transform (FFT) and Recurrence Quantification Interval (RQI) analysis. The latter represents recently developed powerful technique to uncover hidden periodicities in a noisy time environment. At low frequency band the RQI may provide far finer resolution than the conventional FFT technique. The results proved considerable similarity for all investigated depth levels. In addition to the annual wave all measured series proved to have a more complex pattern including predominantly 8-year and 11 years long periodicities. The results were compared with similar analysis of the meteorological air temperature series as well as with the results of other similar studies. The potential dynamics explaining the occurrence of the 8-year wave is briefly discussed.     

Distribution of secondary minerals in crusts developed on sandstone exposures

Previous research on rock weathering crusts has revealed their large variability depending on the type of host rocks and development of weathering processes. The composition of crusts developed on natural sandstone exposures is less documented in the literature in comparison to those developed on architectonic stones. In both cases, previous research has focused mainly on the progress of salt weathering. This study considers the surfaces of sandstone tors in the Polish Outer Carpathians. The exposed parts of the rocks in this area are often covered by crust, which is up to several centimetres thick, and differs from the internal part in colour and composition. The crusts were characterized using light and electron microscopy, X‐ray diffractometry, thermal analyses, Mössbauer spectroscopy, bulk chemical analyses and sequential chemical extractions. Porosity was estimated by digital image processing. The following two hardened zones were observed: (1) thin (up to 30 µm), black, external layer, rich in carbon and composed of opal‐type silica, covered in places by sulphate incrustations and numerous spherical particles of anthropogenic origin; (2) thicker (up to several millimetres), internal part composed of a set of laminae of variable colouration, enriched in iron (oxyhydr)oxides (goethite and hematite) in comparison to the rock interior. Development of the crust results from silicon and iron redistribution during the sandstone alteration. The chief source of silica is hydrolysis of aluminosilicates, whilst that of iron is decomposition of aluminosilicates, carbonates and sulphides. Hematite is probably a result of goethite transformation. However, air pollutants may play an important role in the formation of sulphates. Silica and iron compounds affect the properties of the rock, hardening the surface and lowering porosity by formation of secondary cement. Crystallization of sulphate salts, in turn, may contribute to mechanical disintegration of the rock. Copyright © 2013 John Wiley & Sons, Ltd.     

Prediction of seismic collapse risk of steel moment frame mid-rise structures by meta-heuristic algorithms

Different performance levels may be obtained for sideway collapse evaluation of steel moment frames depending on the evaluation procedure used to handle uncertainties. In this article, the process of representing modelling uncertainties, record to record (RTR) variations and cognitive uncertainties for moment resisting steel frames of various heights is discussed in detail. RTR uncertainty is used by incremental dynamic analysis (IDA), modelling uncertainties are considered through backbone curves and hysteresis loops of component, and cognitive uncertainty is presented in three levels of material quality. IDA is used to evaluate RTR uncertainty based on strong ground motion records selected by the k-means algorithm, which is favoured over Monte Carlo selection due to its time saving appeal. Analytical equations of the Response Surface Method are obtained through IDA results by the Cuckoo algorithm, which predicts the mean and standard deviation of the collapse fragility curve. The Takagi-Sugeno-Kang model is used to represent material quality based on the response surface coefficients. Finally, collapse fragility curves with the various sources of uncertainties mentioned are derived through a large number of material quality values and meta variables inferred by the Takagi-Sugeno-Kang fuzzy model based on response surface method coefficients. It is concluded that a better risk management strategy in countries where material quality control is weak, is to account for cognitive uncertainties in fragility curves and the mean annual frequency.     

Frequency-dependent susceptibility and other magnetic properties of Celtic and Mediaeval graphitic pottery from Bohemia: an introductory study

Frequency-dependent magnetic susceptibility, its anisotropy (AMS), its temperature variation, natural remanent magnetization and time-dependent isothermal remanent magnetization as well as M?ssbauer spectroscopy of a small collection of Celtic and Mediaeval graphitic pottery from Southern Bohemia were investigated. The mineral composition of the pottery is dominated by fragments of quartz, accompanied mainly by various silicates from granitoids and paragneisses, or by calcite, within the plastic component being probably illite but also graphite. No ferrimagnetic minerals were found in optical microscope, among Fe-oxides only limonite was observed, even though the bulk susceptibility of the pottery varies in the orders of 10^?4 to 10^?2 [SI]. This may indicate presence of ferromagnetic particles in the ultrafine (superparamagnetic, SP) state, which is confirmed by frequency-dependent susceptibility ranging from 3% to almost 16%. The low temperature susceptibility vs. temperature curves are only moderately sloped, showing the Verwey transition only in one case. The high temperature curves mostly show presence of two magnetic phases, maghemite and magnetite. Cooling curves show distinctly lower susceptibilities than the heating curves indicating instability of the assemblage of ferrimagnetic minerals, particularly in temperatures slightly under 700 °C. M?ssbauer spectroscopy confirmed the results of the frequency-dependent susceptibility, showing the increase of ferrimagnetic sextets in the spectra measured at 4.2K, likely indicating maghemite as the distinct ferrimagnetic phase. The frequency-dependent AMS indicates preferred orientation of SP1,16 particles, coaxiality between SP_1,16 grain AMS and whole specimen AMS indicate that all grains, ultrafine and coarser ones, were oriented by the same process, i.e. copying the pottery structure created during wheel-turning.     

Operational Cost Comparison of Several Pre‐Treatment Techniques for OMW Treatment

Olive mill wastewaters (OMWs), which are known to have deep impacts on the receiving water bodies due to their high‐strength contents of organic materials and color, must be treated before discharge. For this reason; a number of research studies have been available in current literature related to the treatment of OMWs. However, no widely accepted treatment alternatives have been proposed yet. The common results of these studies suggest that OMWs must be pretreated prior to final purification processes. This study focuses on the comparison of alternative pre‐treatment processes in the aspect of chemical oxygen demand (COD) removal and costs of operation. Centrifuging, lime precipitation, acid cracking, and electrocoagulation processes were performed to compare removal efficiencies and operational costs. The COD removal efficiencies for centrifuging, lime precipitation, acid cracking, and electrocoagulation processes were determined to be 30.1, 24.1, 20.0, 53.7%, respectively, with operational costs being $0.30, $0.37, $1.42, and $11.60 per cubic meter of wastewater treated, respectively. The centrifuging process was concluded to be the most appropriate one according to the COD removal efficiency and cost of operation.     

Investigation of the Possibility of Copper Removal from Industrial Leachate by Raw and Calcined Phosphogypsum: D‐Optimal and Taguchi Designs

In the present study, the removal of Cu(II) was evaluated by raw and calcined phosphogypsum (PG) as an industrial product. The role of experimental factors on the removal of Cu(II) was examined by using D‐optimal and Taguchi designs. The experimental factors and their related levels were selected as initial pH of 3–6–8, adsorbent content of 5, 10, and 25 g L^?1, contact time of 5, 10, and 20 min, and temperature of 20, 40, and 60°C. The results are evaluated by ANOVA test to extract important experimental factors and their levels. The performances of the suggested factorial designs were then compared and regression models that took into account the significant main and interaction effects were suggested. Taguchi design was found as a reliable solution with less number of experiments for adsorption studies with the optimized values. The resultant removal efficiency is calculated as 78.34%. The results revealed that calcined PG is an appropriate adsorbent for Cu(II) removal from leachate of industrial waste.     

Stochastic dynamic response of dam–reservoir–foundation systems to spatially varying earthquake ground motions

In this paper, stochastic dynamic responses of dam–reservoir–foundation systems subjected to spatially varying earthquake ground motions are investigated using the displacement-based fluid finite elements. For this purpose, variable-number-node two-dimensional (2D) fluid finite elements based on the Lagrangian approach is programmed in FORTRAN language and incorporated into a computer program SVEM, which is used for stochastic dynamic analysis of solid systems subjected to spatially varying earthquake ground motion. The spatially varying earthquake ground motion model includes incoherence, wave-passage and site-response effects. The incoherence effect is examined by considering the Harichandran and Vanmarcke coherency model. The effect of the wave passage is investigated by using various wave velocities. Homogeneous medium and firm soil types are selected for considering the site-response effect where the foundation supports are constructed. The Sar?yar concrete gravity dam, constructed in Turkey is selected for numerical example. The ground motion is described by filtered white noise and applied to each support point of the 2D finite element model of the dam–reservoir–foundation system. The record of Kocaeli earthquake in 1999 is used in the analyses. Displacements, stresses and hydrodynamic pressures occurring on the upstream face of the dam are calculated for four cases. It is concluded that spatially varying earthquake ground motions have important effects on the stochastic dynamic response of dam–reservoir–foundation systems.     

An experimental study on steel‐encased buckling‐restrained brace hysteretic dampers

This paper describes a seismic test program performed on 12 steel‐encased buckling‐restrained braces (BRBs). The use of rolled or built‐up buckling‐restraining mechanisms with welded or bolted attachments was examined. In addition, the effects of bolt pretension, core‐to‐encasing attachment details, aspect ratio of core segment and imperfections due to manufacturing on the brace response were investigated. All specimens were subjected to a stepwise incremental quasi‐static testing protocol with a maximum axial strain amplitude of 2%. All specimens except one showed satisfactory performance with stable hysteretic response and sustained cumulative inelastic deformations in excess of 200 times the yield deformation. Based on the experimental results, the compression strength adjustment factor, and the strain hardening adjustment factor for each excursion were quantified. Test results revealed that these two factors are significantly influenced by the parameters investigated in the experimental program. BRB details were also found to influence the buckling and the yielding patterns of the core segment. Copyright © 2009 John Wiley & Sons, Ltd.     

Long-lasting Cadomian magmatic activity along an active northern Gondwana margin: U–Pb zircon and Sr–Nd isotopic evidence from the Brunovistulian Domain,eastern Bohemian Massif

International Journal of Earth Sciences - Cadomian magmatic complexes of the Brunovistulian Domain crop out at the eastern termination of the Bohemian Massif. However, the age, nature and...     

Investigating water quality and arsenic contamination in drinking water resources in the Tavşanlı District (Kütahya,Western Turkey)

Arsenic is a natural component of the earth’s crust, and it is transported into surface water and groundwater through the dissolution of rocks, minerals and ores. In addition, arsenic leaching processes contaminate water sources and this geogenic arsenic contamination causes significant water quality problems in many parts of the world. In this study, water quality, arsenic contamination and human health risks of drinking water resources in the Tav?anl? District were determined and the origins were discussed. For this purpose, geological and hydrogeological properties were investigated. In situ measurements and chemical analyses were carried out on water samples taken from drinking water sources such as wells, springs and surface waters for hydrogeochemical studies. According to the obtained results, water resources are Ca–Mg–HCO₃, Mg–HCO₃ and Na–HCO₃ type. Total As (As_T) concentration of the water samples sometimes exceeds the permissible limit given by the TSI-266 (Standards for drinking waters, Turkish Standards Institution, Ankara, 2005) and WHO (Guidelines for drinking-water quality, World Health Organization, Geneva, 2008) for drinking water. H₃AsO ₃ ⁰ and HAsO₄ ^2? are dominant arsenic species in groundwater and surface water, respectively. Typically high total arsenic concentrations can be found in regions characterized by magmatic rocks. In addition, As concentrations in surface waters were found to be higher than in groundwater in the region, due to the anthropogenic influence of mining activities in the region.