Hydrogeology of thermal waters in Viterbo area, central Italy

A conceptual hydrogeological model of the Viterbo thermal area (central Italy) has been developed. Though numerous studies have been conducted on its geological, geochemical and geothermal features, there is no generalized picture defining the origin and yield of the hydrothermal system. These latter aspects have therefore become the objectives of this research, which is based on new hydrogeological and geochemical investigations. The geological setting results in the coexistence of overlapped interacting aquifers. The shallow volcanic aquifer, characterized by fresh waters, is fed from the area around the Cimini Mountains and is limited at its base by the semiconfining marly-calcareous-arenaceous complex and low-permeability clays. To the west of Viterbo, vertical upflows of thermal waters of the sulphate-chloride-alkaline-earth type with higher gas contents, are due to the locally uplifted carbonate reservoir, the reduced thickness of the semiconfining layer and the high local geothermal gradient. The hot waters (30–60°C) are the result of deep circulation within the carbonate rocks (0.5–1.8 km) and have the same recharge area as the volcanic aquifer. The upward flow in the Viterbo thermal area is at least 0.1 m³/s. This flow feeds springs and deep wells, also recharging the volcanic aquifer from below.     

Distribution of cadmium, chromium, copper, lead and zinc in marine sediments in Hong Kong waters

Partitioning of heavy metals (Cd, Cr, Cu, Pb, Zn) in marine sediments collected from various sites in Hong Kong waters were determined using sequential extraction method. Sediments from Kellette Bank, located in Victoria Harbour, had higher metal concentrations especially Cu and Zn than most other sites. Slightly over 20% of total Cu and Cr existed as readily available forms in Peng Chau and Kellette Bank. At most sampling sites, over 15% of the Cu existed as the exchangeable form indicating that Cu could be readily released into the aqueous phase from sediments. A significantly higher percentage of Pb and Zn was associated with the three non-residual fractions. Hence, there is a greater environmental concern for remobilization of Pb and Zn compared with Cr. The high amount of residual Cd (>50%) and the relatively lower Cd content indicate that little environmental concern is warranted for the remobilization of Cd. Distribution of metals in sediments collected from different depth at Kellette Bank shows that metal concentrations decreased with profile depth. The levels of Pb and Zn associated with the two readily available fractions increased sharply in the surface sediment. These metals represented the pollutants, which were introduced into the area in the mid-eighties through early nineties as a result of rapid economic and industrial development in the territory. As significant portions of these metals were bound to the readily available phases in the surface sediments, metal remobilization could be a concern. An erratum to this article can be found at     

The SHAND quaternary system for evaluating the supersilicic or subsilicic crystal-chemistry of eclogite minerals, and potential new UHPM pyroxene and garnet end-members

Summary The stoichiometry of pyroxenes {^viiiX^{2+ vi}Y^{2+ iv}Z⁴⁺ ₂ O₆} and garnets {^xiiX²⁺ ₃ ^viY³⁺ ₂ ^ivZ⁴⁺ ₃ O₁₂} is re-evaluated by a theoretical crystal-chemical approach that takes into account natural phenomena that do not fit with conventional anhydrous stoichiometric mineralogy: the existence in eclogites of microinclusions of other minerals that may have been exsolved from previous supersilicic or subsilicic UHPM pyroxene or garnet. Different definitions of supersilicic and subsilicic are discussed and the one based on the ability to exsolve SiO₂ and leave behind a stoichiometric pyroxene or garnet is recommended for general adoption. The SHAND system (S = Si et al.; H = H; A = Al et al.; N = Na et al.; D = divalents) for projecting multivariate chemical space involving 23 cations and 104 selected natural or potential mineral species on to two essential diagrams (SAND and SHND) is described in full for the first time. Numerous possible chemical exchanges are considered and justified with respect to known mineral phenomena such as cation vacancies, octahedral silicon or protonation. Several new potential end-members are presented, in particular “supersilipyx”, “supersiligar” and “subsiligar”. It is suggested that small quantities of these end-members can be incorporated into UHPM solid-solutions and lead to various exsolution phenomena during eclogite exhumation.     

Strain softening of K0-consolidated Changi sand under plane-strain conditions

Experimental results are presented in this paper to study the strain softening behaviour of a marine dredged sand under plane-strain conditions. K₀ consolidated drained and undrained tests were conducted using a new plane-strain apparatus to characterize the strain softening behaviour of the sand under plane-strain conditions. For medium dense specimens, strain softening and shear bands were observed to occur under both drained and undrained conditions. For very loose specimens, no shear bands were observed and critical states were reached within the homogeneous deformation region in both drained and undrained tests. Strain softening was observed to occur at small strain for very loose specimens under undrained conditions. Two types of strain softening, the homogenous softening and banding softening, were identified and the conditions for strain softening were established. The results obtained from this study were compared with the studies by Han and Vardoulakis (Géotechnique 41(1):49–78, 1991), Finno et al. (J Geotech Eng ASCE 122(6):462–473, 1996, Géotechnique 47(1):149–165, 1997) and Mokni and Desrues (Mech Cohes-Frict Mat 4:419–441, 1998).     

Metal sources of the Navan carbonate-hosted base metal deposit, Ireland: Nd and Sr isotope evidence for deep hydrothermal convection

Nd and Sr isotope analyses are presented for gangue mineral samples from the giant carbonate-hosted Navan Zn–Pb deposit, Ireland, and for rocks from which Navan metals may have been derived. Analysis of gangue minerals spanning the Navan paragenetic sequence reveals systematic evolution in the composition of the mineralising fluid. Early fluid represented by replacive dolomite exhibits the lowest initial ⁸⁷Sr/⁸⁶Sr ratio (0.7083–0.7086), closest to that of the host limestone and to Lower Carboniferous seawater, and the highest ¹⁴³Nd/¹⁴⁴Nd ratio (0.51161–0.51176). Later generations of dolomite, barite and calcite, which encompass sulphide precipitation, have higher initial ⁸⁷Sr/⁸⁶Sr ratios (maximum 0.7105) and lower initial ¹⁴³Nd/¹⁴⁴Nd ratios (minimum 0.51157). All samples have initial Nd isotope ratios that are too low to have been acquired only from the host limestone. Drill core samples of presumed Ordovician volcanic and sedimentary rocks from beneath the Navan orebody have ¹⁴³Nd/¹⁴⁴Nd and ⁸⁷Sr/⁸⁶Sr ratios at the time of mineralisation of 0.51184–0.51217 and 0.7086–0.7138, respectively. The data are interpreted to indicate mixing of sulphide-rich, limestone-buffered brine, with a metal-bearing hydrothermal fluid, which had passed through sub-Carboniferous rocks, consistent with published fluid inclusion and S isotope data. The ¹⁴³Nd/¹⁴⁴Nd ratio of this basement-derived fluid is too low to have been imparted by flow through the Devonian Old Red Sandstone, as required in models of regional fluid flow in response to Hercynian uplift. Irrespective of whether such regional fluid flow occurred, the hydrothermal Nd must have been derived from sub-Devonian rocks. These conclusions broadly support the hydrothermal convection cell model in which brines, ultimately of surface origin, penetrated to a depth of several kilometres, leaching metals from the rocks through which they passed. The data also support increasing depth of penetration of convection cells with time. Metals were subsequently precipitated in carbonate rocks at sites of mixing with cooler, sulphide-rich fluids. However, comparison of the Navan hydrothermal gangue Nd–Sr isotope data with data from Lower Palaeozoic rocks strongly suggests that the latter cannot alone account for the “basement” signature. As the Navan deposit lies immediately north of the Iapetus Suture, this suggests that the Laurentian margin includes Precambrian basement.     

Planning for source water protection in Ontario

Ontario began developing a drinking water source protection planning process in 2000, after a rural community's water supply was contaminated by pathogens from agricultural runoff. An expert committee report has recommended legislating a new source protection “sphere of jurisdiction” for municipalities; however, no specific new municipal tools or authorities have been proposed as yet. This paper reports findings from an evaluation of the extent to which existing institutional arrangements for land use planning and water management facilitate or constrain source protection by municipalities. A case study of the Regional Municipality of Waterloo suggests there is the potential to link land use planning more strongly to water management through creative use of existing tools, forgoing the need for major institutional changes.     

Fan beheading and drainage diversion as evidence of a 3200-2800 BP earthquake event in the Esmeraldas-Tumaco seismic zone: A case study for the effects of great subduction earthquakes

The San Lorenzo area belongs to the Esmeraldas–Tumaco seismic zone where some of the strongest earthquakes of South America occurred during the 20th century. This paper provides evidence for a succession of geomorphic changes characterized by the disruption of the Quaternary drainage network and the reshaping of the Cayapas–Santiago estuary. The rise of the La Boca uplift bordered by the La Boca and San Lorenzo faults is responsible for the southward diversion of the Palabi, Tululbi, Bogotá and Carolina rivers toward the Santiago and Cayapas rivers. The increase of the discharge directed to the Cayapas River generated the change of the channel pattern downstream from the confluence, and the avulsion of a new estuary through the coastal plain. According to the dating of beach ridges the avulsion occurred in the period 3200–2800 BP. This period corresponds also to a faster accretion of the beach ridge margin, interpreted as a response to a small uplift of the shore. The coherency of the three morphologic evidences—diversion of drainage network, avulsion and increase of coastal accretion—suggest a unique morphotectonic event, in relation with the activity of the Esmaraldas–Tumaco seismic zone. The opening of a direct communication through the mangrove margin may have brought favorable conditions for the development of the La Tolita archaeological site after 3000 BP.