Determination of Trace Silver in Polymetallic Ore Samples by Flame Atomic Absorption Spectrometry after Solid‐Phase Extraction Using a Microcolumn Comprising Eggshell Membrane

A rapid and inexpensive method was developed for the determination of trace silver in polymetallic ore samples by use of eggshell membrane (ESM), a natural biomaterial, as the solid‐phase extraction (SPE) adsorbent coupled with flame atomic absorption spectrometry (FAAS). The ESM was used for the separation/pre‐concentration of silver, and the parameters affecting sensitivity, such as pH, sample flow rate, eluent volume and eluent flow rate, were carefully investigated. ESM was found to be an effective solid phase extractant for the adsorption of trace silver over a wide range of acidity from 0.02 to 0.50 mol l^?1 HNO₃. The sample solution in 0.4 mol l^?1 HNO₃ was pumped through an ESM microcolumn at the rate of 1.0 ml min^?1. Silver was absorbed, and then eluted with a solution of 1.0% m/v thiourea–0.5% v/v HCl. Under these optimal conditions, ESM exhibited a good enrichment efficiency for silver with a dynamic adsorption capacity of 1.7 mg g^?1. The proposed method was applied to the FAAS determination of trace silver in polymetallic ores and geological reference materials, GSO‐2, 3 and 5, and GSD‐11, GSD‐12, and the determined values were in good agreement with certified values.     

鲁中碳酸岩中磷灰石同位素地球化学研究

鲁中地区分布着100多个碳酸岩体，微量元素含量及稀土配分等均与世界典型碳酸岩相近。而碳酸岩的碳氧及斑晶磷灰石的锶、钛同位素组成与典型地幔物质有差异，与富集地幔颇为近似，从而证实在山东地区陆壳下存在富集地幔源区。     

塔中古溶洞见证晚奥陶世抬升幅度

塔中隆起区上奥陶统良里塔格组灰岩与桑塔木组砂—粉砂岩之间为不整合接触,昭示着这两个组沉积期之间存在一次历时约百万年的区域性构造抬升事件。中古31井良里塔格组三段的4 125.6～4 133.9 m井段为垮塌型溶洞沉积,洞顶距良里塔格组二段顶部190.6 m,溶洞中角砾状充填物主要来自良里塔格组洞壁本身的礁相灰岩,且见数厘米厚的暗河流水沉积纹层,未发现源于其它时代的颗粒混杂其间。这一事实指证了溶洞的形成和充填时代均为良里塔格组沉积之后、桑塔木组覆盖之前的晚奥陶世凯迪中期。具溶蚀力的淡水潜流带的深度一般不低于周围的海平面,由此可推断出该井区这次抬升出海平面之上的高度,即使忽略良里塔格组顶部可能经地表剥蚀的良里塔格组一段,抬升出水面部分至少也应该有190 m,藉生态地层学恢复洞壁礁灰岩沉积时的海水深度约为30 m±,因此总抬升幅度至少能达到220 m。     

Formation Environment of Main Brown Coal Seam in Xi-2 Minefield of Shengli Coalfield Based on Coal Ash Phase Analysis

The formation environment of the main coal seam in Shengli coal mine is analyzed, and the effect of coal ash parameters on the coal-forming environment is mainly discussed according to gray component parameters combined with other coal quality test analysis data. Results show that the hydrodynamic conditions of the main coal during coal accumulation have a general pattern of strong northeast and weak southwest, and lakeside swamp is generally in the retrograde process from south to north. The No.5 coal seam is a water entry cycle, and the No.5_lower coal is a water withdrawal cycle. The No.6 thick coal seam is formed in the peat swamp environment where the water is shallow and the groundwater activity is weak. The input of terrestrial debris material was most abundant in the formation period of No.5_lower coal, followed by No.5 coal, and that in No.6 coal is the least. Vertically, the peat swamp environment changed from weak reduction to weak oxidation to strong reducing environment. The ash yield was low to high to low from bottom to top. The organic sulfur is the main type of sulfur in the main coal seam. The weaker the hydrodynamic condition, the higher the organic sulfur content in the reduction environment, while lower organic sulfur content in the oxidation environment. The peat swamp water of No.5_lower coal is medium alkaline, and the peat swamp water of No.5 and No. 6 coals is weakly alkaline or acidic.     

河流水质预测中的模型选择和源强估算

论述了在水质规划和预测中水质模型的选择原则及不同模型的功能,指出COD一级降解模型在理论上的明显缺陷。同时探讨了由COD_Cr和COD_Mn法两种测定方法所引起的在源强计算中存在的问题,提出了较为合理和实用的BOD₅的源强估算方法。     

江苏省日照时数的气候特征分析

利用江苏省内66个气象站1960—1999年日照时数实测资料,分析了江苏省日照时数的气候变化趋势。结果表明,就整个江苏省平均而言,尽管在1960—1999年期间,省内年平均温度升高了0.6℃,但日照时数却呈明显的下降趋势;20世纪80—90年代年平均日照时数较60—70年代的平均值下降了164.7 h,下降幅度为7.35%;日照时数的下降主要表现在夏季和冬季,秋季和春季不明显;对日照时数气候变化的空间分析表明,局部地区与整个省域的气候变化趋势并不完全同步,大部分地区是下降的,个别地区则是上升的。     

GRAPES_GFS全球中期预报系统的研发和业务化

该文回顾了中国气象局全球中期数值天气预报系统GRAPES_GFS的研发历程,重点介绍了近年来在GRAPES_GFS研发过程中的重要进展,概要阐述了这些进展对GRAPES_GFS业务:化的贡献。动力框架方面的改进主要包括位温垂直平流的算法、极区滤波方案、标量平流方案、垂直速度衰减（damping）算法、提高模式分辨率等,改善了模式框架的稳定性、计算精度以及质量守恒性。物理过程方面的改进主要包括RRTMG辐射方案、CoLM陆面过程方案、积云对流、边界层过程、双参数云物理方案,以及物理过程的调用计算等,全面提升了模式物理过程的预报能力。全球三维变分同化方面,研发了模式空间三维变分（3DVar）系统、资料质量控制和偏差订正技术、卫星资料同化方面的相关技术等。同时,对目前GRAPES_GFS2.0的预报能力进行了评估,总体来说,该系统各项预报指标全面超越GRAPES_GFS1.0,与T639相比等压面要素预报在对流层也有明显优势,降水、2 m温度等预报也优势明显。     

城市污染对重庆地区雨水酸化影响的观测分析

1987年9月,重庆地区观音桥、江津县城和四面山响水滩雨水样品分析结果表明,三个测点的雨水平均pH都远小于5.60,市区的污染已影响90km外的乡村。雨水酸度、雷达回波移动方向和雨水化学组分浓度分析说明,四面山雨水酸化的污染源为非局地性的。     

9210报文在伍豪"12121"语音答询系统中的应用

近年来,随着气象科技的迅猛发展、9210工程的完善以及各种预报产品的增多,"12121"语音答询系统的人工录入更加繁重。为了有效减轻工作量,保证"12121"语音录入的及时性,使气象信息在第一时间通过"12121"语音答询系统及时传播给广大听众,我们利用现有的9210报文和伍豪"12121"答询系统的定时模板功能,实现了"12121"语音的自动录入。