Limits on the trapping of atmospheric CH4 in martian polar ice analogs

Recent detection of methane (CH₄) on Mars has generated interest in possible biological or geological sources, but the factors responsible for the reported variability are not understood. Here we explore one potential sink that might affect the seasonal cycling of CH₄ on Mars - trapping in ices deposited on the surface. Our apparatus consisted of a high-vacuum chamber in which three different Mars ice analogs (water, carbon dioxide, and carbon dioxide clathrate hydrates) were deposited in the presence of CH₄ gas. The ices were monitored for spectroscopic evidence of CH₄ trapping using transmission Fourier-Transform Infrared (FT-IR) spectroscopy, and during subsequent sublimation of the ice films the vapor composition was measured using mass spectrometry (MS). Trapping of CH₄ in water ice was confirmed at deposition temperatures <100 K which is consistent with previous work, thus validating the experimental methods. However, no trapping of CH₄ was observed in the ice analogs studied at warmer temperatures (140 K for H₂O and CO₂ clathrate, 90 K for CO₂ snow) with approximately 10 mTorr CH₄ in the chamber. From experimental detection limits these results provide an upper limit of 0.02 for the atmosphere/ice trapping ratio of CH₄. If it is assumed that the trapping mechanism is linear with CH₄ partial pressure and can be extrapolated to Mars, this upper limit would indicate that less than 1% is expected to be trapped from the largest reported CH₄ plume, and therefore does not represent a significant sink for CH₄.     

Spectral Irradiance and Phytoplankton Community Composition in a Blackwater-Dominated Estuary,Winyah Bay,South Carolina,USA

We investigated spatial and temporal relationships between spectral irradiance and phytoplankton community composition in the blackwater-influenced estuary Winyah Bay, South Carolina. Upstream, high concentrations of chromophoric dissolved organic matter (CDOM) absorbed blue wavelengths, resulting in a predominantly red light field. Green light prevailed downstream near the lower-CDOM coastal ocean, and phytoplankton community composition was distinct from upstream and mid-estuarine communities. Diatoms were abundant throughout the estuary in January, August, and October, cryptophytes dominated in July, and chlorophytes were abundant in December 2006. Only diatoms and chlorophytes showed significant covariation with the spectral attenuation coefficient (k(λ)): Chlorophytes showed positive relationships with k(442) (blue light) while diatoms were negatively correlated with k(442) and k(490) (violet to blue). Phytoplankton community composition in Winyah Bay appears to be driven by strong horizontal flow rather than gradients in spectral irradiance, but results indicate that water color is likely to play a greater role in blackwater-influenced estuaries with longer residence times.     

Changes in the parkland-boreal forest boundary in northwestern Ontario over the Holocene

Changes in vegetation were tracked from a well-dated sediment core from a boreal lake, Lake 239, at ～200-year resolution over the Holocene. This presently oligotrophic lake is located ～100-km east from the present-day parkland-forest ecotone in northwestern Ontario. Near-shore sediment core transects from Lake 239 have previously shown this lake was at least 8-m lower than present in the mid-Holocene, or ～58% less lake volume in comparison to today. Large shifts were expected in the terrestrial vegetation if the low lake levels were related to climate. The core from Lake 239 shows increases in the relative abundance and concentration of pollen such as Cupressaceae and Ambrosia, indicating a more open boreal forest between ～4500–8000 cal yr BP. Pollen-based inferences of average, summer and winter temperatures suggest that temperatures were on average up to 1–2 °C warmer than today, with winter temperatures up to 4 °C warmer. The pollen inferences also suggest enhanced precipitation, likely in the summer, but with an overall increase in evaporation and evapotranspiration resulting in reduced effective moisture. To assess regional climate changes, pollen-based reconstructions of temperature and precipitation were developed and synthesized from sediment cores from eight previously published lakes, from which pollen sites were available to both the west and east of Lake 239, spanning present-day prairie lakes to forested lakes up to 300 km east of the prairie-boreal ecotone. All sites show shifts in pollen assemblages that indicate a warm mid-Holocene period; prairie sites west of the Experimental Lakes Area (ELA) show mid-Holocene decreases in precipitation relative to today, whereas sites near or east of ELA show consistent increases in precipitation, but with increased temperatures and enhanced evaporation during the mid-Holocene.     

Relocation of Wyoming Mine Production Blasts Using Calibration Explosions

—?An important requirement for a comprehensive seismic monitoring system is the capability to accurately locate small seismic events worldwide. Accurate event location can improve the probability of determining whether or not a small event, recorded predominantly by local and regional stations, is a nuclear explosion. For those portions of the earth where crustal velocities are not well established, reference event calibration techniques offer a method of increased locational accuracy and reduced locational bias.¶In this study, data from a set of mining events with good ground-truth data in the Powder River Basin region of eastern Wyoming are used to investigate the potential of event calibration techniques in the area. Results of this study are compared with locations published in the prototype International Data Center's Reviewed Event Bulletin (REB). A Joint Hypocenter Determination (JHD) method was applied to a s et of 23 events. Four of those events with superior ground-truth control (mining company report or Global Positioning System data) were used as JHD reference events. Nineteen (83%) of the solutions converged and the resulting set of station-phase travel-time corrections from the JHD results was then tested. When those travel-time corrections were applied individually to the four events with good ground-truth control, the average locational error reduced the original REB location error from 16.1?km to 5.7?km (65% improvement). The JHD locations indicated reduced locational bias and all of the individual error ellipses enclosed the actual known event locations.¶Given a set of well-recorded calibration events, it appears that the JHD methodology is a viable technique for improving locational accuracy of future small events where the location depends on arrival times from predominantly local and/or regional stations. In this specific case, the International Associ ation of Seismology and the Physics of the Earth's Interior (IASPEI) travel-time tables, coupled with JHD-derived travel-time corrections, may obviate the need for an accurately known regional velocity structure in the Powder River Basin region.     

A finite element method for the diffusion-convection equation with constant coefficients

Existing numerical methods for the solution of the diffusion-convection equation are unsatisfactory for convection dominated flow problems. A new finite element method incorporating the method of characteristics for the solution of the diffusion-convection equation with constant coefficients in one spatial dimensions is derived. This method is capable of solving diffusion-convection equation without any of the difficulties encountered in the existing numerical methods for the whole spectrum of dispersion from pure diffusion, through mixed dispersion, to pure convection. Several examples for the one-dimensional case are solved and results are compared with the exact solutions. The generalization of the method to variable coefficients and to the diffusion-convection equation in two space dimensions are discussed.     

A one hundred and seventeen year coastal water temperature record from Woods Hole,Massachusetts

We have compiled what we believe is the longest coherent coastal sea surface temperature record in North America. Near-surface water temperature measurements have been made almost daily at Great Harbon, Woods Hole, Massachusetts, since 1886 with remarkably few gaps. The record shows that there was no significant trend in water temperature at this site for the first 60 yr of observation. There was some cooling during the 1960s that was followed by a significant warming from 1970–2002 at a rate of 0.04°C yr^?1. During the 1990s annual mean temperatures averaged approximately 1.2°C warmer than they had been on average between 1890 and 1970; winter (December, January, and February) temperatures were 1.7°C warmer and summer (June, July, and August) temperatures were 1.0°C warmer. There has not been a statistically significant decrease in the annual number of winter days below 1°C or an increase in the annual number of winter days above 5°C. The number of summer days each year with water temperature above 21°C has not increased significantly. The dates of first observations of 10°C and 20°C water in the spring have not changed sufficiently to be statistically significant. There is a weak positive correlation between annual and winter water temperature and the annual and winter North Atlantic Oscillation index, respectively, during the period of record.     

Ellipsoidal vertical deflections and ellipsoidal gravity disturbance: Case studies

First, we present three different definitions of the vertical which relate to (i) astronomical longitude and astronomical latitude as spherical coordinates in gravity space, (ii) Gauss surface normal coordinates (also called geodetic coordinates) of type ellipsoidal longitude and ellipsoidal latitude and (iii) Jacobi ellipsoidal coordinates of type spheroidal longitude and spheroidal latitude in geometry space. Up to terms of second order those vertical deflections agree to each other. Vertical deflections and gravity disturbances relate to a reference gravity potential. In order to refer the horizontal and vertical components of the disturbing gravity field to a reference gravity field, which is physically meaningful, we have chosen the Somigliana-Pizzetti gravity potential as well as its gradient. Second, we give a new closed-form representation of Somigliana-Pizzetti gravity, accurate to the sub Nano Gal level. Third, we represent the gravitational disturbing potential in terms of Jacobi ellipsoidal harmonics. As soon as we take reference to a normal potential of Somigliana-Pizzetti type, the ellipsoidal harmonics of degree/order (0,0), (1,0), (1, − 1), (1,1) and (2,0) are eliminated from the gravitational disturbing potential. Fourth, we compute in all detail the gradient of the gravitational disturbing potential, in particular in orthonormal ellipsoidal vector harmonics. Proper weighting functions for orthonormality on the International Reference Ellipsoid are constructed and tabulated. In this way, we finally arrive at an ellipsoidal harmonic representation of vertical deflections and gravity disturbances. Fifth, for an ellipsoidal harmonic Gravity Earth Model (SEGEN: http://www.uni-stuttgart.de/gi/research/paper/coefficients/coefficients.zip) up to degree/order 360/360 we compute the global maps of ellipsoidal vertical deflections and ellipsoidal gravity disturbances which transfer a great amount of geophysical information in a properly chosen equiareal ellipsoidal map projection.     

Fire Danger Monitoring Using ERS-1 SAR Images in the Case of Northern Boreal Forests

Research was carried out to assess the potential of imaging radar systems formonitoring forest fire danger. In Canada, daily forest fire danger ratings are generated by the Canadian ForestFire Danger Rating System (CFFDRS), based on estimates of fire weather indices (FWI) and measured foliar moisturecontent (FMC). To evaluate the potential of imaging radar, an experiment was conducted using test sitesconsisting of jack pine, black spruce and white spruce stands located in the MacKenzie river basin, NorthwestTerritories, Canada. Radar image intensity values from ERS-1 SAR imagery collected over these stands in 1994 werecompared to FWI indices and FMC data. FWI indices were calculated using data from local weather stations.Seasonal trends in radar backscatter (⁰) were shown to correlate with temperature and precipitation. Significant relationships were found between ⁰ and FWI codes and indices, particularly in thecase of the black spruce stands, with slow-drying fuels, like duff moisture code (DMC), drought code (DC), and build-upindex (BUI). Rates of changes in ⁰were related to rates of changes in FMC, particularly in the case ofthe jack pine stands for old FMC and in the case of white spruce stands for composite FMC.