Dynamics of herbicide transport and partitioning under event flow conditions in the lower Burdekin region, Australia

This study examined the temporal variability in herbicide delivery to the Great Barrier Reef (GBR) lagoon (Australia) from one of the GBR catchment's major sugarcane growing regions. Annual loads of measured herbicides were consistently in the order of 200+kg. Atrazine, it's degradate desethylatrazine, and diuron contributed approximately 90% of annual herbicide load, with early 'first-flush' events accounting for the majority of herbicide loads leaving the catchment. Assessment of herbicide water-sediment partitioning in flood runoff highlighted the majority of herbicides were transported in predominantly dissolved form, although a considerable fraction of diuron was transported in particulate-bound form (ca. 33%). Diuron was also the herbicide demonstrating the highest concentrations and frequency of detection in sediments collected from catchment waterways and adjacent estuarine-marine environments, an outcome aligning with previous research. Herbicide physico-chemical properties appear to play a crucial role in partitioning between water column and sediment habitat types in GBR receiving ecosystems.     

An assessment of residence times of land-sourced contaminants in the Great Barrier Reef lagoon and the implications for management and reef recovery

We argue that the residence times of key pollutants exported to the Great Barrier Reef (GBR) are greater in the GBR lagoon than those of the water itself, in contradiction to some previous assumptions. Adverse effects of the pollutant discharge will be greater and longer lasting than previously considered, in turn requiring stronger or more urgent action to remediate land practices. Residence times of fine sediments, nitrogen and phosphorus, pesticides and trace metals are suggested to be from years to decades in the GBR lagoon and highly likely to be greater than the residence time of water, estimated at around 15-365days. The recovery of corals and seagrass in the central region of the GBR following current land-use remediation in the catchment depends on the residence time of these contaminants. Ecohydrological modeling suggests that this recovery may take decades even with adequate levels of improved land management practices.     

Origin and karst geomorphological significance of the enigmatic Australian Nullarbor Plain ‘blowholes’

The Australian Nullarbor Plain, one of the world's largest limestone platforms (~200 000 km²), has few distinctive surface karst features for its size, but is known for its enigmatic ‘blowholes’, which can display strong barometric draughts. Thousands of these vertical tubes with decimetre–metre (dm–m) scale diameter puncture the largely featureless terrain. The cause and distribution of these has remained unclear, but they have been thought to originate from downward dissolution and/or salt weathering. To elucidate blowhole distribution and mode of formation we (i) correlated existing location data with Shuttle Radar Topography Mission (SRTM) data, which distinguishes the subtle undulations (< 10 m per km) of the landscape, (ii) surveyed blowhole morphology and (iii) determined their rock surface hardness. Over a sampled area of 4200 km², the distribution of 615 known blowholes is not correlated with present topography. Blowholes are often connected to small or, in some cases extensive, but typically shallow cavities, which exhibit numerous ‘cupolas’ (dome‐shaped pockets) in their ceilings. Statistical arguments suggest that cavities with cupolas are common, but in only a few cases do these puncture the surface. Hardness measurements indicate that salt weathering is not their main cause. Our observations suggest that blowholes do not develop downwards, but occur where a cupola breaks through the surface. Lowering of the land surface is suggested to be the main cause for this breakthrough. Although cupolas may undergo some modification under the current climate, they, as well as the shallow caves they are formed in, are likely to be palaeokarst features formed under a shallower water table and wetter conditions in the past. The findings presented have implications for theories of dissolutional forms development in caves worldwide. The environmental history of the Nullarbor platform allows testing of such theories, because many other factors, which complicate karst evolution elsewhere, have not interfered with landform evolution here. Copyright © 2011 John Wiley & Sons, Ltd.     

Landforms and landscape evolution in the Skardu,Shigar and Braldu Valleys,Central Karakoram

The Central Karakoram, which includes K2 in Pakistan, is one of the most rapidly rising areas on Earth and exhibits complex topography and extreme relief. Impressive valley fills and glacial landforms are present throughout the valleys. The dynamics of landscape evolution of the region are currently not well understood. Consequently, the landforms were mapped and assessed in the Skardu, Shigar, and Braldu valleys, to elucidate the spatio-temporal scale dependencies of surface processes active in the region. These valleys were examined using geomorphic field methods, remote sensing, geomorphometry, and terrestrial cosmogenic nuclides (TCNs) surface exposure dating. The glaciers in this region have oscillated considerably throughout the Late Quaternary, and four glacial stages have been recognized including at least six glacial advances. Surface processes readjusted after glacier retreat, and ubiquitous mass movements and catastrophic landsliding transported material from steep slopes to valley bottoms, while glaciofluvial meltwater and glacier outburst floods redistributed sediment down valley. Glacier geochronology and late Holocene ages of the outburst flood deposits indicate that landscape evolution has been dominated by glaciation and paraglaciation during the late Quaternary.     

Limnological and sedimentary processes at Sawtooth Lake,Canadian High Arctic,and their influence on varve formation

This paper synthesizes data collected to document the modern limnological and sedimentary processes in South Sawtooth Lake located on northern Ellesmere Island, Nunavut, Canada. Field observations show that the finely laminated sediments deposited in the distal basin are formed by the settling of overflows and interflows, and in rare occasions, by non-erosive hyperconcentrated density flows. Thin-sections of these sediments allowed for the classification of the sedimentary fabrics into six facies, each representing different limnological processes. The sediments in this distal basin are considered to be continuous and annually laminated (varved) based on radioisotope analyses, and both limnological and sedimentological evidence.     

Analysis of groundwater exchange for a large plains river in Colorado (USA)

Complete daily water budget information was assembled for a 105 km segment of the South Platte River in the plains region below Denver, CO, for the period 1983–1993. The data were used in testing the possibility that dependence of alluvial exchange mechanisms on stage height, as shown by models of alluvial exchange, allows alluvial exchange to be predicted continuously over a given reach through use of statistical information on river discharge. The study segment was divided into an upper and a lower reach; daily alluvial exchanges for each reach were estimated by the method of residuals. The two reaches show small (15%) but statistically significant annual differences in rates of exchange. For each reach, there is a seasonal pattern (2·5‐fold oscillation) in alluvial discharge to the channel, reflecting seasonality in recharge of the alluvium by irrigation. At discharges up to 40 m³/s (82nd percentile), alluvial discharge to the channel occurs at a rate independent of river discharge. Above 40 m³/s, net alluvial discharge into the channel is progressively reduced; at 60 m³/s (92nd percentile) there is no net alluvial exchange. At still higher river discharges, water is lost to the alluvium through bank storage at a rate that is linearly related to the logarithm of discharge. Annually, alluvial discharge accounts for 15–18% of water entering the study segment, and alluvial recharge through bank storage accounts for 2–4% of water leaving the segment. Alluvial recharge through bank storage at the highest discharges can, however, exceed low‐flow alluvial discharge rates by five‐fold over short intervals. Even though daily alluvial exchanges vary widely, they can be estimated at r² values above 80% on the basis of reach, season, and river discharge. Copyright © 2001 John Wiley & Sons, Ltd.     

Trace-element concentrations in single circumstellar silicon carbide grains from the Murchison meteorite

Abstract— Concentrations of the trace elements Mg, Al, Ca, Ti, V, Fe, Sr, Y, Zr, Ba and Ce were determined by ion microprobe mass spectrometry in 60 individual silicon carbide (SiC) grains (in addition, Nb and Nd were determined in 20 of them), from separate KJH (size range 3.4–5.9 μm) of the Murchison carbonaceous meteorite, whose C-, N- and Si-isotopic compositions have been measured before (Hoppe et al., 1994) and provide evidence that these grains are of stellar origin. The selected SiC grains represent all previously recognized subgroups: mainstream (20 < ¹²C/¹³C < 120; 200 < ¹⁴N/¹⁵N; Si isotopes on slope 1.34 line), grains A (¹²C/¹³C < 3.5), grains B (3.5 < ¹²C/¹³C < 10), grains X (¹⁵N excesses, large ²⁸Si excesses) and grains Y (150 < ¹²C/¹³C < 260; Si isotopes on slope 0.35 line). Data on these grains are compared with measurements on fine-grained SiC fractions. Trace-element patterns reflect both the condensation behavior of individual elements and the source composition of the stellar atmospheres. A detailed discussion of the condensation of trace elements in SiC from C-rich stellar atmospheres is given in a companion paper by Lodders and Fegley (1995). Elements such as Mg, Al, Ca, Fe and Sr are depleted because their compounds are more volatile than SiC. Elements whose compounds are believed to be more refractory than SiC can also be depleted due to condensation and removal prior to SiC condensation. Among the refractory elements, however, the heavy elements from Y to Ce (and Nd) are systematically enriched relative to Ti and V, indicating enrichments by up to a factor of 14 of the s-process elements relative to elements lighter than Fe. Such enrichments are expected if N-type carbon stars (thermally pulsing AGB stars) are the main source of circumstellar SiC grains. Large grains are less enriched than small grains, possibly because they are from different AGB stars. The trace-element patterns of subgroups such as groups A and B and grains X can at least qualitatively be understood if grains A and B come from J-type carbon stars (known to be lacking in s-process enhancements shown by N-type carbon stars) or carbon stars that had not experienced much dredge-up of He-shell material and if grains X come from supernovae. However, a remaining puzzle is how stars become carbon stars without much accompanying dredge-up of s-process elements.     

Interstellar graphite in meteorites: Isotopic compositions and structural properties of single graphite grains from Murchison

Abstract— One hundred forty-three carbon grains, ranging in size from 2 to 8 μm, from two chemical and physical separates from the Murchison CM2 chondrite, were analyzed by ion microprobe mass spectrometry for their C- and N-isotopic compositions. Both separates are enriched in the exotic noble gas component Ne-E(L). Ninety grains were also analyzed for their H and O contents and 118, for Si. Thirteen grains were analyzed by micro-sampling laser Raman spectroscopy. Round grains have large C-isotopic anomalies with ¹²C/¹³C ratios ranging from 7 to 4500 (terrestrial ratio = 89). Nitrogen in these grains is also anomalous but shows much smaller deviations from the terrestrial composition, ¹⁴N/¹⁵N ratios ranging from 193 to 680 (terrestrial ratio = 272). Spherulitic aggregates and non-round compact grains have normal C-isotopic ratios but ¹⁵N excesses (up to 35%). Raman spectra of the analyzed grains indicate varying degrees of crystalline disorder of graphite with estimated in-plane crystallite dimensions varying from 18 Å (highly disordered, similar to terrestrial kerogen) to ～750 Å (well-crystallized graphite). Element contents of H, O, and Si are correlated with one another, and H and O are probably present in the form of organic molecules. On the basis of morphology, the round grains fall into two groups: grains with smooth, shell-like surfaces (“onions”) and grains that appear to be dense aggregates of small scales (“cauliflowers”). “Onions” tend to have lower trace element contents, isotopically light C (¹²C/¹³C > 89) and a high degree of crystalline order, whereas “cauliflowers” have a larger spread in trace element contents and C-isotopic ratios (they range from isotopically light to heavy) but tend to have a low degree of crystalline order. However, these differences exist only on average, and no clear distinction can be made for individual grains. A few limited conclusions can be drawn about the astrophysical origin of the carbon grains of this study. The ¹⁵N excesses in spherulitic aggregates and non-round grains can be explained as the result of ion-molecule reactions in molecular clouds. The round grains, on the other hand, must have formed in stellar atmospheres (circumstellar grains). Grains with isotopically light C must have formed in stellar environments characterized by He-burning, either in the atmosphere of Wolf-Rayet stars during the WC phase or in the He-burning, ¹²C-rich zone of a massive star, ejected by a supernova explosion. Isotopically heavy C is produced by H-burning in the CNO cycle. Possible sources for grains with heavy C are carbon stars (AGB stars during the thermally pulsing phase) or novae, but the detailed distribution of ¹²C/¹³C ratios agree neither with the distribution observed in carbon stars nor with theoretical predictions for these two types of stellar sources.