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61.
A number of processes may modify the noble gas composition of silicate liquids so that the composition of noble gases observed in glassy margins of deep-sea basalts is not that of the upper mantle. Differential solubility enhances the light noble gases relative to the heavier gases; however, we demonstrate that the observed abundance pattern cannot be attributed to solubility of noble gases with atmospheric proportions. Partial melting and fractional crystallization increase the noble gas content of all species relative to mantle concentrations, but do not fractionate their relative abundances. Noble gases may be lost from an ascending magma in various ways, the most important, however, may be exclusion of gas from crystals forming at the time of solidification, which is shown to result in marked loss of gas from the basalt. Small amounts of low-temperature alteration of solidified basalt can produce dramatic changes in the noble gas abundance pattern, since the adsorption coefficients for the different noble gas favor uptake of heavy species relative to the light species. Atmospheric contamination can account for observed variations in the 40Ar/36Ar ratio of oceanic basalts. The degree of crystallinity of glassy margins of deep-sea basalts may control the helium abundance of these samples; however, the uniform 3He/4He values reported apparently reflect a relatively constant proportion of radiogenic and primordial helium in the mantle. 相似文献
62.
A rapid thin-layer chromatographic technique for estimating the relative concentration of crude oil in sediments has been developed. The limit of detection on the chromatogram is 2 μg of Empire Mix or Saudi Arabian crude oil. The technique has been tested on 335 sediment samples collected from 67 stations in the Gulf of Mexico and has been utilized in assessing the location of oil entering the sediments from the Argo Merchant spill incident. 相似文献
63.
Detailed analysis is presented of a conformable succession of Early Miocene conglomerates and sandstones lying between massive marine mudstones. The coarse sediments reflect deposition by a spectrum of subaqueous debris-flow mechanisms during an early pulse of tectonism that ultimately resulted in Plio-Pleistocene eversion of the Kaikoura Mountains.Sparse pebbly mudstones and rare sandy conglomerates show disoriented clasts and reflect high-viscosity flows and slurry-creep flow mechanisms. Other deposits have little mud matrix, hence appear to reflect low-viscosity flow processes. The largest clasts in these have a preferred planar orientation, probably reflecting dispersive grain pressure, and a preferred long-axis orientation parallel to flow direction. Common sorted sandstones and some conglomeratic sandstones show diffuse parallel lamination; with rare exceptions neither grading nor traction structures are present. Other conglomeratic sandstones show trough cross-bedding which we attribute to entrained bedload movement during intersurge episodes of debris flow.Microfossil data from the mudstones indicate sedimentation in an environment of outer neritic to upper bathyal aspect. Most detritus is abraded, suggesting derivation from terrestrial or inner neritic sources, but angular calcilutitic clasts and irregular sandstone and mudstone clasts and rafts were probably derived from submarine erosion between the emergent source area and the site of accumulation. Deposits generally appear to infill broad shallow channels. Paleocurrent and fabric analysis indicate a markedly uniform flow direction throughout succession, and suggest that the locus of channeling remained relatively fixed in space throughout accumulation of hundreds of metres of superimposed, commonly amalgamated debris-flow deposits. Although lateral control away from the measured sequence is limited, we infer that the locus of deposition lay shoreward of any submarine canyon or fan. 相似文献
64.
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66.
A finite-element model of a viscous layer contained in a viscous matrix and undergoing layer-parallel compression is used to examine the hypothesis that a long chain of folds, as found in real rocks, can originate from one initial perturbation to the layer geometry. This hypothesis is tested by determining the velocity with which a perturbation spreads along layers of various viscosities.An insight is gained into the roles played by local strain and local layer strength in the folding mechanism. The results show that for layers with viscosity ratios comparable with those of real rocks it is impossible for long chains of folds to originate from one perturbation. The authors conclude that rock layers contain many initial perturbations and folding originates at all perturbation sites simultaneously. The growth of such folds depends on the amplitude and shape of the initial perturbation and on subsequent interference between folds. 相似文献
67.
Dale M Lewis 《Geochimica et cosmochimica acta》1977,41(11):1557-1564
Analysis of soil profiles and shallow ground water in the Susquehanna River basin, northeastern U.S.A., indicates that the atmospheric flux of 210Pb is efficiently scavenged by the organic-rich horizons of the soils. This atmospherically supplied 210Pb in soil profiles can only be lost from the system by soil erosion. Based on the annual sediment yield of the Susquehanna River and the excess 210Pb concentration in particulate matter, a mean residence time of 2000 yr is calculated for metals similar to Pb in soil profiles.The West Branch of the Susquehanna River (WBSR) is strongly affected by acid mine drainage and is low in pH and high in dissolved ( <0.4 μm) 210Pb, Fe and Mn. Along its course iron hydroxide is precipitating at a pH of between 4 and 4.5 and the 210Pb supplied by the acid mine water is diminished by about 25% as a result of dilution. As the WBSR enters the Valley and Ridge Province of the Appalachians it has a 210Pb concentration of ~ 0.2 dpm/l. At this juncture it receives a considerable influx of alkalinity from tributaries draining carbonate terranes, resulting in neutralization of the sulfuric acid and increase of the river pH to around 6.5–7. This pH adjustment is accompanied by the precipitation of Fe and Mn. Due to the slow rate of Mn removal from solution, the Mn precipitation extends a considerable distance down river from the point of acid neutralization. Analyses for 210Pb in the river at points in or below the region of Mn precipitation show that 210Pb is rapidly scavenged from solution onto suspended particles. From the data it is possible to calculate the removal rate of Pb from water in the presence of Fe and Mn hydroxides and other particles. At a pH of 4–4.5 Pb removal is nonexistent relative to the river flow rate, but at a pH of 6.5–7 the 210Pb data indicate a residence time of <0.7 day for dissolved Pb. 相似文献
68.
The voltage induced in a horizontal loop on a layered ground has been calculated for the case where the loop is excited by a step current and measurements are made during the off-cycle. The expressions derived for a uniform ground show that for large time t the induced voltage E(t) is approximately given by E(t)?— (Ibαμ/20t) (σμ2/t)3/2 where σ is the conductivity of the ground, μ the permeability, b the loop radius, and I the amplitude of the current step. For small times the corresponding result is E(t)?—Ibμ/2t. When the ground is composed of a number of layers a numerical procedure for calculating the induced voltage is described. The calculated responses of various multilayered structures show that at short times the induced voltage is asymptotic to that produced in the case of a uniform ground of conductivity equal to the top layer. Interference effects in the top layer can lead to anomalous decay curves which may result in the underestimation of the conductivity of a buried layer. 相似文献
69.
The distribution equilibrium of Au and Re between nickel-iron and basaltic melts was studied at 1400–1600°C, using radioactive tracers. Metal/silicate distribution coefficients were 1–3 orders of magnitude higher than earlier estimates, as follows. Mauna Loa basalt—Fe10Ni90: DAu = 3.3 × 104, DRe = (2.4?89) × 104. Gorda Ridge basalt—Fe10Ni90: DAu = (18?75) × 104. Synthetic lunar basalt—Fe70 Ni30: DAu≥ 2 × 104, DRe ≥ 2 × 103. The experimental ΔG1800° for the distribution of Au between nickel-iron and Mauna Loa basalt is ?40 kcal/mole, compared to a calculated value of about ?110 kcal/mole for a reaction involving simple Au3+ ions. Presumably the difference represents stabilization of Au(III) by complex formation with ligands such as Cl?, H2O, etc.Gold abundances in lunar basalts are roughly consistent with the measured DAu, but those in terrestrial basalts are two orders of magnitude too high. This discrepancy may reflect complexing by volatiles in the Earth's upper lithosphere, as well as oxidative destruction of metal in the final stages of accretion. In the absence of a metal phase, siderophile trace elements would remain trapped in the upper mantle and crust. 相似文献
70.
Sedimentary and igneous rocks of the Swaziland Sequence of South Africa (>3,200 my. old) contain total carbon (0.09–8.28%), organic carbon (0.04–1.95%) and sulfur (9–53,000 ppm). Amounts of organic carbon are generally high in the lower part of the Sequence (based on two samples from the Theespruit Formation). Sulfur content varies widely with no obvious correlations or trends. These rocks may contain clues to the early carbon and sulfur cycles on earth. 相似文献