Relationships among remotely sensed soil moisture,precipitation and landslide events

Landslides are triggered by earthquakes, volcanoes, floods, and heavy continuous rainfall. For most types of slope failure, soil moisture plays a critical role because increased pore water pressure reduces the soil strength and increases stress. However, in-situ soil moisture profiles are rarely measured. To establish the soil moisture and landslide relationship, a qualitative comparison among soil moisture derived from AMSR-E, precipitation from TRMM and major landslide events was conducted. This study shows that it is possible to estimate antecedent soil moisture conditions using AMSR-E and TRMM satellite data in landslide prone areas. AMSR-E data show distinct annual patterns of soil moisture that reflect observed rainfall patterns from TRMM. Results also show enhanced AMSR-E soil moisture and TRMM rainfall prior to major landslide events in landslide prone regions of California, U.S.; Leyte, Philippines; and Dhading, Nepal.     

Inadvertent alkalization of a Florida lake caused by increased ionic and nutrient loading to its watershed

We evaluate the effects of land-use change since c.1890 on Little Lake Jackson in south-central Florida, USA. The lake currently is alkaline despite the prevalence of acidic lakes in the region. Watershed soils are acidic and poorly drained, but are underlain by limestone bedrock. Limnetic pH inferences, based on weighted-averaging tolerance regression of sedimented diatoms, indicate that Little Lake Jackson became significantly alkalized during the 1900s. Two driving forces that appear to be responsible for water-quality change are increased ionic loading and increased nutrient loading. Golf courses and residential lawns in the watershed receive substantial applications of lime, fertilizer, and irrigation with alkaline waters from deep wells, some of which reaches the lake in channelized runoff. Stormwater runoff and septic leachate also contribute to nutrient and solute loading. Sedimentary total P accumulation increased 5-fold and total N accumulation increased 3-fold since c. 1890. δ¹⁵N values suggest agricultural and septic sources for N loading. Sedimented pigments, inferred limnetic chlorophyll a values, and δ¹³C values of organic matter indicate that increased primary productivity occurred. Surface and subsurface inflow is nutrient-rich but low in hardness. Increased cation deposition in sediments indicates that ionic input might have reduced the lake’s natural resistance to alkalization. Lake waters remain low in ionic content, which suggests that the addition of base from carbonate sources is not responsible for all of the observed alkalization. Acid neutralization might have been facilitated by phosphate loading that led to increased base generation through greater nitrate assimilation. Inadvertent alkalization might occur commonly in regions where poorly buffered lakes are subject to significant ionic and nutrient loading from agriculture, turfgrass, and septic sources in their watersheds.     

Trace metal solubility in an anoxic fjord

Intermittent anoxia in the Saanich Inlet water column provides an easily accessible marine O₂/H₂S interface to study the response of metals to both a steep redox gradient and the availability of reactive reduced sulfur species. Our study indicates a strong anoxic zone sink for copper and cadmium and the characteristically enhanced solubility of manganese and iron. Thiosulfate and sulfite are below detection limits (1 μM and 0.1 μM, respectively) and thus not important in metal complexation. Elemental sulfur concentrations are high at the oxic/anoxic interface and throughout the anoxic zone, indicating the potential for metal complexation by polysulfides. A thermodynamic approach employing metal sulfide formation and class specific sulfidic ligand complexation to generate equilibrium profiles adequately describes the solubility of iron, copper, and cadmium. The extension of this scheme to other transition and class B metals in other marine environments with redox fronts is suggested.     

Longitudinal Social Science Research in Natural Resource Communities: Lessons and Considerations

The majority of social science research is cross-sectional in nature, with data collected at a single point in time. However, social systems are dynamic and many of the variables of interest to social scientists may change over time. Longitudinal research methods enable data collection at two or more points in time among a population of interest to examine change in measured variables and influencing factors. Despite the opportunities it affords, longitudinal research is relatively uncommon in natural-resource-based social science research as compared to other fields (e.g., medical, criminal, education). We feel that the field of natural resource social science is ripe for a proliferation of longitudinal studies, now that a substantial body of cross-sectional data has been built. In the spirit of encouraging more of this type of research, we draw on our collective experiences in longitudinal studies to share lessons learned in research design, sampling, and data management.     

Exchange of Nitrogen and Phosphorus Between a Shallow Lagoon and Coastal Waters

West Falmouth Harbor, a shallow lagoon on Cape Cod, has experienced a threefold increase in nitrogen load since the mid- to late 1990s due to input from a groundwater plume contaminated by a municipal wastewater treatment plant. We measured the exchange of nitrogen and phosphorus between the harbor and the coastal waters of Buzzards Bay over several years when the harbor was experiencing this elevated nitrogen load. During summer months, the harbor not only retained the entire watershed nitrogen load but also had a net import of nitrogen from Buzzards Bay. During the spring and fall, the harbor had a net export of nitrogen to Buzzards Bay. We did not measure the export in winter, but assuming the winter net export was less than 112 % of the load, the harbor exported less than half of the watershed nitrogen load on an annual basis. For phosphorus, the harbor had a net import from coastal waters in the spring and summer months and a net export in the fall. Despite the large increase in nitrogen load to the harbor, the summertime import of phosphorus from Buzzards Bay was sufficient to maintain nitrogen limitation of primary productivity during the summer. Our findings illustrate that shallow systems dominated by benthic producers have the potential to retain large terrestrial nitrogen loads when there is sufficient supply of phosphorus from exchange with coastal waters.     

Topographic and stratification effects on shelf edge flows

Results are presented from two sets of laboratory model experiments on the effects of an isolated seamount upon the flow of an intermediate-water slope current along a continental shelf. The experimental results for initial ambient conditions of respectively two-layer and linearly stratified fluids show that the structure of such a boundary current depends primarily on the values of the appropriate set of dimensionless dynamical parameters (namely the Burger (Bu), Ekman (Ek) and Rossby (Ro) numbers), as well as the dimensionless lateral separation of the seamount and shelf and the proportional height of the seamount relative to the distance from the bottom at which the intermediate-water flows. Comparisons of the present results with those from a previous two-layer fluid study with no obstacle present reveals that the presence of the obstacle does not alter significantly the stability of the current even when situated close to the shelf. However, for such configurations, the density, velocity and vorticity fields in the local zone of interaction between the current and the obstacle are distorted significantly by the presence of the obstacle, provided that the summit of the obstacle penetrates the level of current flow. Measurements of density, velocity and vorticity fields show no significant dependence of the flow interaction upon the detailed bathymetry of the shelf-slope. For stable intermediate-water slope currents, the nature of the interaction with the obstacle is determined primarily by (i) the lateral separation of the obstacle and the shelf edge and (ii) the Ro of the flow. For sufficiently low values of the former and high values of the latter, the interaction results in a splitting of the incident flow around the obstacle, with cyclonic and anticyclonic eddy pairs being generated in the lee. Geostrophic equilibrium is seen to be maintained in the current, even in the near wake of the obstacle. For cases in which the summit of the seamount is below the initially-undisturbed intermediate water level, no Taylor column-like division of the slope current occurs and no significant distortion of the current structure (velocity and density) occurs for the parameter ranges investigated. For linearly stratified cases, measurements show that no significant local elevation or depression of the density interfaces is observed in the interaction zone. The distributions of the local buoyancy frequencies calculated from the density profiles reveal that the minimum value of the frequency upstream of the obstacle is smaller than that downstream, indicating that the flow interactions generate local mixing downstream, with consequent erosion of the density interfaces.     

New Reference Materials,Analytical Procedures and Data Reduction Strategies for Sr Isotope Measurements in Geological Materials by LA-MC-ICP-MS

Laser ablation multi-collector mass spectrometry (LA-MC-ICP-MS) has emerged as the technique of choice for in situ measurements of Sr isotopes in geological minerals. However, the method poses analytical challenges and there is no widely adopted standardised approach to collecting these data or correcting the numerous potential isobaric inferences. Here, we outline practical analytical procedures and data reduction strategies to help establish a consistent framework for collecting and correcting Sr isotope measurements in geological materials by LA-MC-ICP-MS. We characterise a new set of plagioclase reference materials, which are available for distribution to the community, and present a new data reduction scheme for the Iolite software package to correct isobaric interferences for different materials and analytical conditions. Our tests show that a combination of Kr-baseline subtraction, Rb-peak-stripping using βRb derived from a bracketing glass reference material, and a CaCa or CaAr correction for plagioclase and CaCa or CaAr + REE²⁺ correction for rock glasses, yields the most accurate and precise ⁸⁷Sr/⁸⁶Sr measurements for these materials. Using the analytical and correction procedures outlined herein, spot analyses using a beam diameter of 100 μm or rastering with a 50–65 μm diameter beam can readily achieve < 100 ppm 2SE repeatability ("internal") precision for ⁸⁷Sr/⁸⁶Sr measurements for materials with < 1000 μg g^-1 Sr.     

Twinned calcite as an indicator of high differential stresses and low shock pressure conditions during impact cratering

Shock-related calcite twins are characterized in calcite-bearing metagranite cataclasites within crystalline megablocks of the Ries impact structure, Germany, as well as in cores from the FBN1973 research drilling. The calcite likely originates from pre-impact veins within the Variscan metagranites and gneisses, while the cataclasis is due to the Miocene impact. Quartz in the metagranite components does not contain planar deformation features, indicating low shock pressures (<7 GPa). Calcite, however, shows a high density (>1/μm) of twins with widths <100 nm. Different types of twins (e-, f-, and r-twins) crosscutting each other can occur in one grain. Interaction of r- and f-twins results in a-type domains characterized by a misorientation relative to the host with a misorientation angle of 35°–40° and a misorientation axis parallel to an a-axis. Such a-type domains have not been recorded from deformed rocks in nature before. The high twin density and activation of different twin systems in one grain require high differential stresses (on the order of 1 GPa). Twinning of calcite at high differential stresses is consistent with deformation during impact cratering at relatively low shock pressure conditions. The twinned calcite microstructure can serve as a valuable low shock barometer.