Bulk organic δ13C and C/N ratios as palaeosalinity indicators within a Scottish isolation basin

Microfossils in isolation basin sediments are frequently used to reconstruct sea‐level change, but preservation problems and non‐analogue situations can limit their usefulness. Here we investigate the potential of stable carbon isotopes (δ¹³C) and C/N ratios from bulk organic matter, as an alternative proxy of salinity within isolation basin sediments from a basin in northwest Scotland. Within the Holocene sediment δ¹³C and C/N are determined largely by the mean weighted values of the predominant source of the organic material. Analysis of modern materials and comparison with the diatom record shows that the marine parts of the sequence are dominated by high δ¹³C and variable C/N. In the fresh water sequences the organic material is a mixture of both freshwater aquatic and terrestrial plant input that have relatively low δ¹³C and high C/N. The application of δ¹³C and C/N ratios in the studied basin in general follow the environmental change recorded by the diatoms and shows the potential of bulk organic matter in the investigation of salinity change in isolation basins. Copyright © 2005 John Wiley & Sons, Ltd.     

The Qso Hosts I Zw 1 and 3C 48: Prototypes of a Merger-Driven Quasar Evolution?

I Zw 1 and 3C 48 are two neighboring template objects at a later stage of the hypothesized merger-driven evolutionary sequence from ultra-luminous infrared galaxies (ULIRGs) to quasi-stellar objects (QSOs). Since galaxy mergers are assumed to trigger the evolution, it is important to confirm the merger properties of transitionary objects. Using multi-wavelength observations and N-body simulations, the merger histories of I Zw 1 and 3C 48 have been investigated in two separate case studies. Here, the results from both studies are compared and their relevance for the evolutionary hypothesis is discussed.This research is partly based on observations with ISAAC at the Very Large Telescope (VLT) of the European Southern Observatory (ESO) under projects 67.B-0009 and 67.B-0019.     

Stabilization of Bottom Hole Temperature With Finite Circulation Time and Fluid Flow

As an alternative to finite element or finite difference modelling, analytical solutions are derived by the method of Laplace transformation and numerical results obtained for several models of the bottom hole temperature stabilization. Included in the models are the finite circulation time, the thermal property contrast between the borehole mud and the surrounding formation, and the presence of radial or lateral fluid flow in the formation, all of which are found to have significant effects on the dissipation of the thermal disturbance induced by drilling.
The mud circulation is considered to have the effect of either maintaining the borehole mud at a constant temperature or supplying a constant amount of heat per unit length per unit time to the borehole. For small circulation times, the former reduces to the 'zero circulation' model in which the mud circulation creates an instantaneous temperature anomaly at the hole bottom; for small borehole radii, the latter reduces to the line source model and the traditional 'Homer plot'.
For typical drilling operations in which the bottom hole temperatures are measured several hours to several tens of hours after the hole is shut in, the new models generally predict higher equilibrium formation temperatures than does the Horner plot. However, predictions from the various models converge if the BHTs are taken after the hole has been shut in for a period which is greater than about five times the circulation period.     

Preliminary evaluation of the occurrence of herbicides and PAHs in the Wet Tropics region of the Great Barrier Reef, Australia, using passive samplers

The proximity of the Great Barrier Reef (GBR) Marine Park to areas of intensive agriculture and increasing urbanisation places the park under potential threat of contamination by land-based pollutants. Passive samplers were deployed at inshore reef and river mouth sites in the Wet Tropics region of the GBR during a dry and a wet season to measure levels of land-based organic pollutants in this environment. Two types of passive sampling devices were deployed: (i) a polar sampler, which can be used to monitor polar herbicides and (ii) semipermeable membrane devices (SPMDs) which sequester more hydrophobic compounds (e.g. PAHs, chlorpyrifos). Herbicides (diuron, simazine, atrazine, hexazinone and/or flumeturon) were detected at low concentrations (ng L⁻¹) at all sites sampled and in both seasons. Chlorpyrifos was not detected while PAHs were present in SPMDs at levels below limits of detection. The results show that the GBR environment does contain low levels of organic pollutants and that passive sampling provides a sensitive monitoring tool for measuring waterborne organic pollutants.     

Experimental studies of oxygen isotope fractionation in the carbonic acid system at 15°, 25°, and 40°C

In light of recent studies that show oxygen isotope fractionation in carbonate minerals to be a function of HCO₃⁻ and CO₃²⁻ concentrations, the oxygen isotope fractionation and exchange between water and components of the carbonic acid system (HCO₃⁻, CO₃²⁻, and CO_2(aq)) were investigated at 15°, 25°, and 40°C. To investigate oxygen isotope exchange between HCO₃⁻, CO₃²⁻, and H₂O, NaHCO₃ solutions were prepared and the pH was adjusted over a range of 2 to 12 by the addition of small amounts of HCl or NaOH. After thermal, chemical, and isotopic equilibrium was attained, BaCl₂ was added to the NaHCO₃ solutions. This resulted in immediate BaCO₃ precipitation; thus, recording the isotopic composition of the dissolved inorganic carbon (DIC). Data from experiments at 15°, 25°, and 40°C (1 atm) show that the oxygen isotope fractionation between HCO₃⁻ and H₂O as a function of temperature is governed by the equation:

     

Feeding Monsters – A Study of Active Galaxies

We present new interferometric observations of the molecular gas distribution and kinematics in the nuclei of different active galaxies at high angular resolution and high sensitivity carried out with the IRAM Plateau de Bure interferometer (PdBI). The observations cover galaxies in a redshift range of 0.03–1.4. We have so far observed five different active galaxies: NGC3718, NGC1068, HE1029–1831, 3C48 and Q0957+561. The first two objects belong to the NUGA (NUclei of GAlaxies) project – an international collaboration mainly between Spain, France and Germany – containing about 30 Seyfert and LINER galaxies. Both are at the same distance of 14Mpc and show a warped gas and dust disk. The new mosaic map of NGC3718 corrected for short-spacing effects with IRAM 30 m observations well demonstrates the existence of the warped gas disk with several secondary maxima in the projected gas distribution caused by orbit crowding effects. Based on these new data we have improved recent simulations of the warped disk in NGC3718. HE1029–1831 and 3C48 are nearby QSOs. HE1029–1831 is taken out of the Cologne nearby QSO sample. The maps of the integrated CO(1–0) and CO(2–1) emission clearly show that the molecular gas is mostly related to the central bulge with a non-negligible fraction distributed along the bar known from optical observations. Our new CO data of 3C48 unveil new information about the kinematics of its molecular gas complementing and improving further studies based on previous infrared observations and detailed multi-particle simulations. Finally, new measurements of the CO(1–0) line in Q0957+561 – a highly-red-shifted, gravitationally lensed quasar – will be presented as a link to earlier evolutionary stages of active galaxies and their hosts.     

Water sorption on martian regolith analogs: Thermodynamics and near-infrared reflectance spectroscopy

The near-infrared reflectance spectra of the martian surface present strong absorption features attributed to hydration water present in the regolith. In order to characterize the relationships between this water and atmospheric vapor and decipher the physical state of water molecules in martian regolith analogs, we designed and built an experimental setup to measure near-IR reflectance spectra under martian atmospheric conditions. Six samples were studied that cover part of the diversity of Mars surface mineralogy: a hydrated ferric oxide (ferrihydrite), two igneous samples (volcanic tuff, and dunite sand), and three potential water rich soil materials (Mg-sulfate, smectite powder and a palagonitic soil, the JSC Mars-1 regolith stimulant). Sorption and desorption isotherms were measured at 243 K for water vapor pressure varying from 10⁻⁵ to ∼0.3 mbar (relative humidity: 10⁻⁴ to 75%). These measurements reveal a large diversity of behavior among the sample suite in terms of absolute amount of water adsorbed, shape of the isotherm and hysteresis between the adsorption and desorption branches. Simultaneous in situ spectroscopic observations permit a detailed analysis of the spectral signature of adsorbed water and also point to clear differences between the samples. Ferric (oxy)hydroxides like ferrihydrite or other phases present in palagonitic soils are very strong water adsorbent and may play an important role in the current martian water cycle by allowing large exchange of water between dust-covered regions and atmosphere at diurnal and seasonal scales.     

Field reconnaissance of the Anti-Atlas coastline, Morocco: Fluvial and marine evidence for Late Cenozoic uplift

The available evidence regarding the disposition and chronology of Pliocene–Pleistocene fluvial terraces, coastal rock flats, raised beaches and lacustrine sediments adjoining the Anti-Atlas coastline of Morocco has been reviewed and supplemented by additional information from our own field reconnaissance. It is thus suggested that the study region has experienced uplift by  130 m since the Mid-Pliocene climatic optimum ( 3.1 Ma), by  90 m since the latest Pliocene ( 2 Ma), and by  45 m since the Mid-Pleistocene Revolution ( 0.9 Ma). Each of these phases of uplift correlates with a phase of global climate change known independently, and it is thus inferred that the observed uplift is being driven by climate through mechanisms such as erosional isostasy and the associated induced lower-crustal flow. Numerical modelling of the observed uplift history indicates that the mobile lower-crustal layer in the study region is  9 km thick, with a temperature at its base of  500 °C. The base of this mobile layer is inferred to be at  24 km depth, the deepest crust consisting of a layer of mafic underplating that does not flow under ambient conditions. The principal landform in the study region, the coastal rock platform at  60 m a.s.l., thus formed during a succession of interglacial marine highstands in the late Early Pleistocene when uplift rates were low. Although control on the ages of young sediments and landforms is currently extremely limited, being dependent on regional correlation schemes rather than on absolute dating, the study region fits the pattern, emerging worldwide, that climate change is driving the systematic growth of topographic relief evident during the Late Cenozoic.