A 500 yr speleothem-derived reconstruction of late autumn–winter precipitation, northeast Turkey

A verified instrumental calibration of annually resolved δ¹⁸O for a stalagmite from Gümü?hane in northeast Turkey is presented and cross-validated using a ‘leave-one-out’ technique. The amount of late autumn to winter precipitation is negatively correlated with stalagmite δ¹⁸O between AD 1938 and 2004. The observed relationship is extrapolated back to ~ AD 1500 leading to the first long winter precipitation reconstruction for this region. Modern day October to January precipitation is linked to pressure fields in Western Russia. Anomalously lower reconstructed rainfall is recorded in AD 1540–1560 at which time higher pressure over the Caspian Sea region is inferred.     

Geochemical and biological consequences of groundwater augmentation in lakes of west-central Florida (USA)

We studied sediment cores from four Florida (USA) lakes that have received groundwater hydrologic supplements (augmentation) for >30 years to maintain lake stage. Top samples (0–4 cm) from sediment cores taken in Lakes Charles, Saddleback, Little Hobbs, and Crystal had ²²⁶Ra activities of 44.9, 17.5, 7.6, and 8.5 dpm g⁻¹, respectively, about an order of magnitude greater than values in deeper, older deposits. The surface sample from Lake Charles yielded the highest ²²⁶Ra activity yet reported from a Florida lake core. Several lines of evidence suggest that groundwater augmentation is responsible for the high ²²⁶Ra activities in recent sediments: (1) ²²⁶Ra activity in cores increased recently, (2) the Charles, Crystal, and Saddleback cores display ²²⁶Ra/²¹⁰Pb disequilibrium at several shallow depths, suggesting ²²⁶Ra entered the lakes in dissolved form, (3) cores show recent increases in Ca, which, like ²²⁶Ra, is abundant in augmentation groundwater, and (4) greater Sr concentrations are associated with higher ²²⁶Ra activities in recent Charles and Saddleback sediments. Sr concentrations in Eocene limestones of the deep Floridan Aquifer are high relative to Sr concentrations in surficial quartz sands around the lakes. Historical water quality inferences for the lakes were based on diatom assemblages in sediments. Recent alkalization in Lakes Charles, Saddleback, Little Hobbs, and Crystal was inferred from weighted-averaging calibration (WACALIB). The lakes also show recent trophic state increases based on WACALIB-derived estimates for limnetic total P. Although residential and agricultural sources might contribute to increased P loading, P in augmentation waters probably has had significant influence on eutrophication. Dystrophic diatoms were abundant in the early history of Lakes Saddleback, Little Hobbs, and Crystal, which suggests that these lakes contained more tannic waters during the past than at present, perhaps as a consequence of greater inflows from surrounding wetlands. Ionic content of lake waters increased, as indicated by diatom autecological analysis. Recent geochemical and biological changes detected in cores from these lakes probably are a result of deliberate groundwater augmentation, although inputs of groundwater pumped for agricultural and residential development in the watersheds also might have contributed to limnological changes.     

Diatom-inferred late Pleistocene and Holocene palaeolimnological changes in the Ioannina basin, northwest Greece

The character and impact of climate change since the last glacial maximum (LGM) in the eastern Mediterranean region remain poorly understood. Here, two new diatom records from the Ioannina basin in northwest Greece are presented alongside a pre-existing record and used to infer past changes in lake level, a proxy for the balance between precipitation and evaporation. Comparison of the three records indicates that lake-level fluctuations were the dominant driver of diatom assemblage composition change, whereas productivity variations had a secondary role. The reconstruction indicates low lake levels during the LGM. Late glacial lake deepening was underway by 15.0 cal kyr BP, implying that the climate was becoming wetter. During the Younger Dryas stadial, a lake-level decline is recorded, indicating arid climatic conditions. Lake Ioannina deepened rapidly in the early Holocene, but long-term lake-level decline commenced around 7.0 cal kyr BP. The pattern of lake-level change is broadly consistent with an existing lake-level reconstruction at Lake Xinias, central Greece. The timing of the apparent change, however, is different, with delayed early Holocene deepening at Xinias. This offset is attributed to uncertainties in the age models, and the position of Xinias in the rain shadow of the Pindus Mountains.     

Geomicrobial transformation of manganese in Gorda Ridge event plumes

Event plumes form as episodic discharges of large volumes of hydrothermal solutions in response to magmatic diking/eruptive events. In consequence, event plumes represent the sudden injection of exploitable reduced chemical substrates, as well as inhibitory constituents, and likely induce successional changes in the microbial community structure and activity within event plume waters. In response to a major seismic event detected beginning 28 February 1996 at the northern Gorda Ridge, a series of three rapid response and follow-up cruises (GREAT 1, 2 and 3) were mounted over a period of three months. This report focuses on time-series measurements of manganese geomicrobial parameters in the two event plumes found in association with this seismic event.Scanning transmission electron microscopy, elemental microanalysis, and radioisotope (⁵⁴Mn) uptake experiments were employed on samples collected from vertical and tow-yo casts from the three cruises. Numbers of bacteria and ratios of metal precipitating capsuled bacteria to total bacteria were greatest in the youngest (days old) plume, EP96A, found during GREAT 1; however, when normalized to the hydrothermal temperature anomaly, the greatest values were found in a second event plume, EP96B, discovered during GREAT 2 (up to 1 month old). Early capsule bacteria and particulate Mn distributions may have been influenced by entrainment of resuspended sediment, while those of the oldest (2–3 months) plume sample may have been subjected to preferential aggregation and particle settling.     

Deglaciation and catchment ontogeny in coastal south‐west Greenland: implications for terrestrial and aquatic carbon cycling

Here we present Holocene organic carbon, nitrogen, sulphur, carbon isotope ratio and macrofossil data from a small freshwater lake near Sisimiut in south‐west Greenland. The lake was formed c. 11 cal ka BP following retreat of the ice sheet margin and is located above the marine limit in this area. The elemental and isotope data suggest a complex deglaciation history of interactions between the lake and its catchment, reflecting glacial retreat and post‐glacial hydrological flushing probably due to periodic melting of local remnant glacial ice and firn areas between 11 and 8.5 cal ka BP. After 8.5 cal ka BP, soil development and associated vegetation processes began to exert a greater control on terrestrial–aquatic carbon cycling. By 5.5 cal ka BP, in the early Neoglacial cooling, the sediment record indicates a change in catchment–lake interactions with consistent δ¹³C while C/N exhibits greater variability. The period after 5.5 cal ka BP is also characterized by higher organic C accumulation in the lake. These changes (total organic carbon, C/N, δ¹³C) are most likely the result of increasing contribution (and burial) of terrestrial organic matter as a result of enhanced soil instability, as indicated by an increase in Cenococcum remains, but also Sphagnum and Empetrum. The impact of glacial retreat and relatively subdued mid‐ to late Holocene climate variation at the coast is in marked contrast to the greater environmental variability seen in inland lakes closer to the present‐day ice sheet margin. Copyright © 2012 John Wiley & Sons, Ltd.     

Volatiles in a peralkaline system: Abiogenic hydrocarbons and F–Cl–Br systematics in the naujaite of the Ilímaussaq intrusion, South Greenland

Agpaitic rocks comprise most of the exposed part of the 1.16 Ga old, 8 × 17 km large and about 1700 m thick Ilímaussaq intrusion in South Greenland. Within these, more than 600 m thick sequence of sodalite-rich “naujaites” (mainly sodalite + arfvedsonite + alkali feldspar + nepheline + eudialyte + aenigmatite) are interpreted as a sodalite flotation cumulate. Sodalites show two to three different zones in cathodoluminescence (CL) and at least two zones in thin sections. The CL zones can be related to chemical differences detectable by electron microprobe, whereas relations with optical zonations are less obvious. Compositional trends in sodalite reflect trends in the evolution of volatile contents in the melt. The sodalite at Ilímaussaq is almost free of Ca and closely corresponds to the pure Na–Cl sodalite endmember with about 7 wt.% of Cl; S contents reach up to 0.9 wt.%. Cl/Br ratios range from 500 to 1700. Raman spectroscopy shows that S is present as [SO₄]²⁻ in sodalite, although sphalerite (ZnS) is a stable phase in naujaites. Peralkalinity and fO₂ conditions allow S²⁻ and [SO₄]²⁻ to be present contemporaneously.

The whole naujaite sequence is divided into two parts, an upper part with low, homogeneous S contents and Cl/Br ratios in the sodalite cores, and a lower part with strongly variable and higher S contents and with Cl/Br ratios, which are decreasing downwards. The details of the S content and the Cl/Br ratio evolution show that sodalite strongly influences the halogen contents of the melt by scavenging Cl and Br.

The naujaites were formed from a highly reduced, halogen-rich magma in equilibrium with magmatic methane at about 800 °C, which, upon ascent, cooling and fractionation, exsolved an aqueous fluid phase. Both fluids were trapped in separate inclusions indicating their immiscibility.

Micrometer-sized aegirine crystals and primary hydrocarbon-bearing inclusions are abundant in the crystal cores. The inclusions were trapped at pressures up to 4 kbar, although the emplacement pressure of the intrusion is about 1 kbar. This indicates growth of the sodalite during melt ascent and a very effective mechanism of trace element scavenging during sodalite growth. Sodalite rims are devoid of aegirine or primary hydrocarbon inclusions and probably reflect the emplacement stage.     

Modelling surface‐water depression storage in a Prairie Pothole Region

In this study, the Precipitation‐Runoff Modelling System (PRMS) was used to simulate changes in surface‐water depression storage in the 1,126‐km² Upper Pipestem Creek basin located within the Prairie Pothole Region of North Dakota, USA. The Prairie Pothole Region is characterized by millions of small water bodies (or surface‐water depressions) that provide numerous ecosystem services and are considered an important contribution to the hydrologic cycle. The Upper Pipestem PRMS model was extracted from the U.S. Geological Survey's (USGS) National Hydrologic Model (NHM), developed to support consistent hydrologic modelling across the conterminous United States. The Geospatial Fabric database, created for the USGS NHM, contains hydrologic model parameter values derived from datasets that characterize the physical features of the entire conterminous United States for 109,951 hydrologic response units. Each hydrologic response unit in the Geospatial Fabric was parameterized using aggregated surface‐water depression area derived from the National Hydrography Dataset Plus, an integrated suite of application‐ready geospatial datasets. This paper presents a calibration strategy for the Upper Pipestem PRMS model that uses normalized lake elevation measurements to calibrate the parameters influencing simulated fractional surface‐water depression storage. Results indicate that inclusion of measurements that give an indication of the change in surface‐water depression storage in the calibration procedure resulted in accurate changes in surface‐water depression storage in the water balance. Regionalized parameterization of the USGS NHM will require a proxy for change in surface‐storage to accurately parameterize surface‐water depression storage within the USGS NHM.     

Tidal and Groundwater Fluxes to a Shallow, Microtidal Estuary: Constraining Inputs Through Field Observations and Hydrodynamic Modeling

Increased nutrient loading to estuaries has led to eutrophication, degraded water quality, and ecological transformations. Quantifying nutrient loads in systems with significant groundwater input can be difficult due to the challenge of measuring groundwater fluxes. We quantified tidal and freshwater fluxes over an 8-week period at the entrance of West Falmouth Harbor, Massachusetts, a eutrophic, groundwater-fed estuary. Fluxes were estimated from velocity and salinity measurements and a total exchange flow (TEF) methodology. Intermittent cross-sectional measurements of velocity and salinity were used to convert point measurements to cross-sectionally averaged values over the entire deployment (index relationships). The estimated mean freshwater flux (0.19?m³/s) for the 8-week period was mainly due to groundwater input (0.21?m³/s) with contributions from precipitation to the estuary surface (0.026?m³/s) and removal by evaporation (0.048?m³/s). Spring?Cneap variations in freshwater export that appeared in shorter-term averages were mostly artifacts of the index relationships. Hydrodynamic modeling with steady groundwater input demonstrated that while the TEF methodology resolves the freshwater flux signal, calibration of the index?Csalinity relationships during spring tide conditions only was responsible for most of the spring?Cneap signal. The mean freshwater flux over the entire period estimated from the combination of the index-velocity, index?Csalinity, and TEF calculations were consistent with the model, suggesting that this methodology is a reliable way of estimating freshwater fluxes in the estuary over timescales greater than the spring?Cneap cycle. Combining this type of field campaign with hydrodynamic modeling provides guidance for estimating both magnitude of groundwater input and estuarine storage of freshwater and sets the stage for robust estimation of the nutrient load in groundwater.     

Bacterial and viral abundances in hydrothermal event plumes over northern Gorda Ridge

This study presents first-time observations of bacterial and viral abundances in hydrothermal event plumes. Two water-column event plumes were formed in conjunction with seismic events and seafloor volcanic eruptions on the northern Gorda Ridge in February–March 1996. Epifluorescence counts of bacteria and viruses were performed on water samples from 3 successive cruises staged in the 10–90 days that followed the onset of seismicity. Relative to background seawater at these 1800–3200 m depths, bacterial abundance was enhanced by 2–3 fold within both event plumes. In contrast, viral numbers were below background seawater values in the younger and more intense of the two event plumes (EP96A), and enhanced in the other (EP96B). Changes in viral abundance may be a secondary response to that of plume bacteria as well as being influenced by particle formation and precipitation within the plumes. Lower bacteria/heat, virus/heat and virus/bacteria ratios in EP96A versus EP96B confirm distinct differences in the microbial response to event plume formation, possibly related to observed differences in plume chemistry.     

Lake evolution in a semi-arid montane environment: response to catchment change and hydroclimatic variation

Pollen, geochemical and sedimentological data from Sidi Ali, a montane Moroccan lake, provide a 7000 yr record of changes in climate, catchment vegetation and soil erosion intensity. Diatoms, non-silicious algae, macrophyte fossils and ostracods from the same core record the dynamics of the lake ecosystem. Oxygen isotope and trace-element ratios of benthic ostracods appear to be relatively insensitive to climatic variation in this open lake with low water-residence time, but diatom plankton / periphyton (P/L) ratios show lake-level variations that are probably climate controlled. At least two superimposed processes are recorded, but at different timescales: catchment vegetation and soils show long-term changes due to climate and human impact, whereas P/L ratios suggest century-scale oscillations in lake depth. The timing of changes in algal and macrophyte productivity and carbon cycling within the lake broadly corresponds to changes in terrestrial vegetation, suggesting either that lake nutrient status is linked to catchment vegetation and soils, or that both were influenced by climate. The lack of a sensitive and independent (non-biological) climate proxy makes it more difficult to assess the lake's ecological response to short-term climate variation. Overall, the lake's evolution has been influenced both by catchment-mediated nutrient flux and by changes in water balance, thus having characteristics in common with both temperate and arid zone lakes.