Granitoids of the Pozdnestanovoy Complex of the Dzhugdzhur–Stanovoy Superterrane,Central Asia Fold Belt: Age,Tectonic Setting,and Sources

The geochemistry, geochronology, and isotope geochemical systematics (Nd, Sr, Hf, and Pb) of the granitoids of the Pozdnestanovoy complex of the Dzhugdzhur–Stanovoy superterrane of the Central Asia fold belt were investigated. It was shown that their age is Mesozoic (142–138 Ma) rather than Early Precambrian, as was previously supposed. The main sources of parental melts for these granitoids were the Neoarchean and Paleoproterozoic rocks of the lower continental crust of the Dzhugdzhur–Stanovoy superterrane and the rocks of the Late Paleozoic–Early Mesozoic continental crust of the Amur microplate. They were formed at depths of >40 km and temperatures of 700–800°C, most likely through the melting of mafic feldspar granulites under the conditions of aqueous fluid infiltration without any significant contribution from a juvenile heat source. The granitoids of the Pozdnestanovoy complex were emplaced during the closure of the eastern segment of the Mongolia–Okhotsk Ocean owing to the collision of the Siberian and Sino-Korean continents.     

Vertical Distribution of Brine and Volume Structure of Thin Annual Ice in Amursky Bay Based on the Methods of Nuclear Magnetic Resonance and Magnetic Resonance Imaging

Oceanology - Spatial distribution of the liquid and solid phases in the pores of first-year sea ice in Amursky Bay was studied using the method of nuclear magnetic resonance and magnetic resonance...     

Orientation of Figures of Small Planetary Satellites During Chaotic Rotation

Solar System Research - The effect of the preferred orientation of the largest axis of the satellite’s figure toward the planet during chaotic rotation is considered by means of numerical...     

The structure of the incoherent sediments in the Ita Mai Tai Guyot (Pacific Ocean) based on geoacoustic profiling data

The results of geoacoustic studies carried out by the acoustic MAK-1M system in the southeastern Ita Mai Tai Guyot (Magellan Seamounts, Pacific Ocean) are discussed. The obtained geoacoustic sections characterize the incoherent part of the sedimentary sequence with high resolution. The geoacoustic stratification is well correlative with the deep-sea drilling data: the acoustic units are reliably correlated with the lithostratigraphic units defined in the cores of DSDP holes 200 and 202. Three geoacoustic units are distinguished in the sedimentary section (from the top downward): unit I corresponding in age to the terminal Miocene (Messinian)-Quaternary; unit II correlated with the Late Miocene (Tortonian); unit III accumulated in the Early Eocene-Early Miocene. The acoustic basement is composed of reefogenic limestones that were formed at different stages of the guyot’s development through the Aptian-Turonian to Late Paleocene-Eocene. The sonar images allow the distribution of the incoherent carbonate sediments to be contoured along the periphery of the summit’s plateau.     

Ionic gold in calcrete revealed by LA-ICP-MS, SXRF and XANES

Highly anomalous Au concentrations in calcrete were discovered in 1987 at the Bounty Gold Deposit, Western Australia. A strong correlation was noted between the Ca, Mg, Sr and Au in soil profiles which have not only attracted the interest of mineral explorers but also chemists, soil scientists, metallurgists and climatologists. Gold has been considered an inert element and so its strong association with the alkaline earth group of relatively mobile elements is both remarkable and intriguing. Despite widespread interest, there have been few published papers on the Au-calcrete phenomenon. Here, we present work conducted on calcareous soil samples from above the Bounty mineralisation in Western Australia, prior to mining.Using SXRF (synchrotron X-ray fluorescence) and XANES (micro-X-ray absorption near-edge structure), we have shown for the first time the distribution of Au in calcrete and that it occurs in both particulate and ionic form. Much of the ionic Au associated with Br is found in a root tubule. The observations are consistent with an evapotranspiration model for the formation of Au in the calcrete; Au has been mobilised then precipitated as vadose water has been removed from the soil by trees and shrubs. While the association between Au and Ca is very strong in bulk sample analyses down the soil profile, other detailed analyses on sub-samples using wet chemical, LA-ICP-MS (laser ablation inductively coupled mass spectrometry) and SXRF techniques show that it is not apparent at the sub-millimetre scale. This suggests that the Au and Ca are behaving similarly but independently and they do not (at the μm scale) co-precipitate with carbonate minerals.These results corroborate other studies that suggest biotic influences can affect the mobilisation and distribution of Au in surficial materials. Water-extractable Au in calcrete has been reported previously and the ionic Au described in this study likely represents that soluble component. The presence of easily solubilised Au in soils has been widely discussed and exploited for mineral exploration.     

Cancrinite and cancrisilite in the Khibina-Lovozero alkaline complex: Thermochemical and thermal data

The paper presents the results of a thermochemical and thermal study of cancrinite, (Na_6.93Ca_0.545K_0.01)_Σ7.485[(Si_6.47Al_5.48Fe_0.05)_Σ12O₂₄](CO₃)_1.25 · 2.30 H₂O, and cancrisilite, (Na_7.17 Ca_0.01)_Σ7.18[(Si_7.26Al_4.70Fe_0.04)_Σ12O₂₄][(CO₃)_1.05(OH)_0.21(PO₄)_0.04(SO₄)_0.01] · 2.635 H₂O, from the Khibina-Lovozero Complex, Kola Peninsula, Russia. Stages of the thermal decomposition of these minerals were studied using IR spectroscopy. The enthalpies of formation of the minerals from elements were determined by melt drop solution calorimetry: Δ _f H _el ⁰ (298.15 K) = ?14 490 ± 16 kJ/mol for cancrinite and ?14302 ± 17 kJ/mol for cancrisilite. The values of Δ _f H _el ⁰ (298.15 K), S ^o(298.15 K), and Δ _f H _el ⁰ (298.15 K) are determined for cancrinite and cancrisilite of theoretical composition.     

New data on the morphology and geological structure of the Gramberg Guyot (Magellan Seamounts, Pacific Ocean)

The geological-geophysical studies carried out in the western part of the Pacific Ocean by the State Research Center “Yuzhmorgeologiya“ during cruises of the R/V “Gelendzhik” in 2002–2004 yielded new data on the relief of the Gramberg Guyot and its constituting rocks, which appeared to be Early Cretaceous to Pleistocene in age. The analysis of macro- and microfaunal remains in sedimentary rocks made it possible to define the transgressive phases in the development of seamounts (the Cenomanian-Turonian, Late Campanian-Maastrichtian, and Late Cenozoic). The geological development of the Gramberg Guyot is compared with that of other similar structures of the Magellan Seamounts.