Vertical distribution and water solubility of phosphorus and heavy metals in sediments of the St. Lucie Estuary, South Florida, USA

Accumulation and distribution of heavy metals and phosphorus in sediments impact water quality. There has been an increasing concern regarding fish health in the St. Lucie Estuary, which is related to increased inputs of nutrients and metals in recent decades. To investigate vertical changes of contaminants (P, Cd, Cr, Co, Cu, Ni, Pb, Zn, and Mn) in sediments of the St. Lucie Estuary in South Florida, 117 layer samples from six of the 210 to 420 cm depth cores were analyzed for their total and water-soluble P and heavy metals, clay, total Fe, Al, K, Ca, Mg, Na, and pH. Principal component analysis (PCA) was used in two sets of analytical data (total and water-soluble contaminant concentrations) to document changes of contaminants in each core of sediments. The PCA of total contaminants and minerals resulted in two factors (principal components). The first and second factors accounted for 61.7 and 17.2 % of the total variation in all variables, and contrast indicators associated with contaminants of P, Cd, Co, Cr, Ni, Pb, Zn, and Mn and accumulation of Fe and Al oxides, respectively. The first factor could be used for overall assessment of P and heavy metal contamination, and was higher in the upper 45–90 cm than the lower depths of each core. The concentrations of P and heavy metals in the surface layers of sediments significantly increased, as compared with those in the sediments deeper than 45–90 cm. The PCA of water-soluble contaminants developed two factors. The second factor (Cu–P) was higher in the upper than the lower depths of the sediment, whereas the highest score of the first factor (Cd–Co–Cr–Ni–Pb–Zn–Mn) occurred below 100 cm. The water-soluble Cu and P concentrations were mainly dependent on their total concentrations in the sediments, whereas the water-soluble Cd, Co, Cr, Ni, Pb, Zn, and Mn concentrations were mainly controlled by pH.     

An objective classification system of air mass types for Szeged, Hungary, with special interest in air pollution levels

Summary This paper determines the characteristic air mass types over the Carpathian Basin for the winter (December, January, and February) and summer (June, July and August) months dependant on levels of the main air pollutants. Based on the ECMWF data set, daily sea-level pressure fields analysed at 00 UTC were prepared for each air mass type (cluster) in order to relate sea-level pressure patterns with the level of air pollutants in Szeged. The data comprise daily values of twelve meteorological and eight pollutant parameters for the period 1997–2001. Objective definition of the characteristic air mass types is achieved by using the methods of Factor Analysis and Cluster Analysis. According to the results, during the winter months five air mass types (clusters) were detected based on higher concentrations of primary pollutants that occur with high irradiance and low wind speed. This is the case when an anticyclone is found over the Carpathian Basin and over the region south of Hungary, influencing the weather of the country. Low levels of pollutants occur when zonal currents exert influence over Hungary. During the summer months anticyclones and anticyclone ridge situations are found over the Carpathian Basin. (During the prevalence of anticyclone ridge situations, the Carpathian Basin is found at the edge of a high pressure centre.) As a result of high irradiance and very low NO levels, secondary pollutants are highly enriched.     

Petrology of the tin-bearing granite-leucogranites of the Piaoak Massif, Northern Vietnam

The Piaoak tin-bearing granite-leucogranites located in the Caobang Province of Northern Vietnam compose a stock-like hypabyssal body. Host rocks are represented by Early Devonian carbonate sequences and Early Triassic ??black?? shales. The geochronological age of the Piaoak granite-leucogranites corresponds to the Late Cretaceous: T = 83.5 ± 6.2 Ma, ⁸⁷Rb/⁸⁶Sr method; T = 89.7 ± 1.0 Ma, ³⁹Ar/⁴⁰Ar method. The massif has a simple basic to acid order: two-mica and muscovite granite-leucogranite ?? raremetal aplites, pegmatites ?? tin-bearing greisens and hydrothermal veins. The petrographic and microstructural studies revealed a sharp change in crystallization conditions of the granite-leucogranite magma at the late magmatic stage and formation of muscovite via incongruent melting of protolithionite. The study of melt and coexisting fluid inclusions showed that solidus crystallization occurred under fluid-saturated conditions at 635?C600°C. In composition, the granite-leucogranites of the Piaoak Massif correspond to the raremetal-plumasite geochemical type (according to L.V. Tauson), and reach Li-F facies in terms of their rare-element composition. The composition of aplites and pegmatites demonstrates that granite-leucogranite magma did not accumulate lithophile and volatile components in the residual melt during differentiation, but was initially enriched in rare-metals. It is most probable that the melt was generated from Proterozoic lithotectonic complexes and overlaying Lower Triassic ??black?? shales.     

Cosmological implications of BL Lac objects

It has become clear in recent years that relativistic beaming is a good explanation for the BL Lac phenomenon. Of studies based on the relativistic beaming model of BL Lac objects, we note that the orientation of jet's axis to the line-of-sight is very small and, therefore, the observed flux emitted from a rapidly moving source is orders of magnitude higher than the flux in its rest-frame:F _obs = ^{3 +} F _intr, where is the bulk relativistic Doppler factor. Then the observed apparent magnitudem _v must be corrected for this effect. For our 39 samples, the corrected apparent magnitudem _v ^corr and logZ have a good correlation.     

Short period internal waves over the Huanghe (Yellow River) delta front

Internal waves with periods of about 5 minutes and trough to crest heights of up to 6.2 m were observed acoustically over the actively accreting delta front of the Huanghe (Yellow River) in the western portion of the Gulf of Bohai, Peoples Republic of China. The radian frequency of the internal waves was close to the locally-observed Brunt-Vaisala frequency. Through the relatively short (one hour) duration of an internal wave train, the amplitude was observed to decrease progressively with time. These internal waves may cause resuspension of delta-front sediments.     

Deterministic sliding block methods for estimating seismic displacements of earth structures

A review and quantitative comparison of existing deterministic sliding block methods for predicting permanent displacements of earth structures subjected to seismic loading is presented. The reviewed sliding block methods are divided into two main groups based on the characteristic earthquake parameters referenced in each method. One group uses the maximum horizontal ground acceleration and velocity, and the other uses the maximum horizontal ground acceleration and the predominant period of the acceleration spectrum. Displacement functions published by previous authors are reformulated to give common non-dimensionalized displacement functions of the critical acceleration ratio which are then used to compare the different methods for the estimate of permanent seismic displacement of soil structures. The results show that despite the fact that the different methods were formulated using a wide range of earthquake records and different characteristic seismic parameters, permanent displacement values predicted using these methods fall within a reasonably narrow band. Selected acceleration data from three recent earthquakes that occurred in California are used to evaluate and compare the accuracy of the reviewed displacement methods for practical applications.     

Zircon U-Pb geochronology of Early Jurassic-Late cretaceous volcanic rocks in North Yellow Sea BasinEI北大核心CSCD

The X-drilling cores of the North Yellow Sea basin reveal two sets of Mesozoic clastic rocks, which are the dark rocks in lower part and the red rocks in upper part, respectively. There are two layers of volcanic rocks at the bottom and the upper part of the dark rock unit. The volcanic rocks at the bottom part are trachytic dacite while rocks at the upper part are clastic dacite. The zircon grains from the upper and lower units of volcanic rocks are euhedral-subhedral columnar crystals and show oscillatory zoning on cathodoluminescence images. 22 tests of zircons in the trachytic dacite from the bottom part yield an age of 141-151 Ma, with weighted mean 206Pb/238U age of 145±2 Ma. Whereas 18 tests of zircons from the sample at the upper part give 206Pb/238U ages around 139-149 Ma with weighted mean 206Pb/238U age of 141±2 Ma, which implies that the X well volcanic rocks belong to Late Jurassic-Early Cretaceous. Comparing with the age and geochemical characteristics of the Mesozoic igneous rocks in Shandong peninsula, we suggest that the igneous rocks from both the North Yellow Sea basin and Jiaolai basin were formed under same dynamic setting, i.e., the subduction related volcano arc and back-arc extension. ©, 2015, Science Press. All right reserved.     

Direct detection of the secondary spectrum of the interacting eclipsing binary TX UMa

Eclipsing binary TX UMa was observed with the D.A.O. high-dispersion spectrographs in 1969–1970, with emphasis on the detailed coverage of the primary minimum. One spectrum was taken exclusively within totality, thus exhibiting an uncontaminated spectrum of the secondary component. This leads to spectral reclassification of the secondary (F6 IV). The narrowing of the line profile of the H-line in totality is interpreted in terms of synchronous rotation of the secondary (v sini80 km s^–1) while the primary rotates faster (v sini130 km s^–1) than synchronously (v sini50 km s^–1). Although the secondary does not fill in its Roche lobe fully, the system exhibits pronounced indications of rather strong physical interaction. This is now supported also by the profound changes of the line profiles of the H-line with phase.     

The Hα-cyclonic spectra of a flare loop system on 1981 April 27

The data such as the H-spectrum-spectroheliographic (SSHG) observations, the H-chromospheric observations, etc., of a flare loop prominence which occurred on the western solar limb on 1981 April 27 have been obtained at Yunnan Observatory. The distribution of the internal motions and the macroscopical motion of the flare loop prominence with time and space in the course of its eruption and ascension is derived from the comprehensive analysis of the data. The possible physical pictures and the instability of the motions of the loop are inferred and discussed.