Petrology and geochemistry of post-collisional Middle Eocene volcanic units in North-Central Turkey: Evidence for magma generation by slab breakoff following the closure of the Northern Neotethys Ocean

The Eocene volcano-sedimentary units of Northern Anatolia are confined into a narrow zone trending parallel to the Intra Pontide and İzmir–Ankara–Erzincan sutures, along which the northern branch of the Neotethys Ocean was closed during a period between Late Maastrichtian and Paleocene. The Middle Eocene formations overlie both the imbricated and highly deformed units of the suture zone, which are Paleocene or older in age, as well as the formations of adjacent continental blocks with a regional disconformity. Therefore, they can be regarded to be post-collisional. These units are composed of subaerial to shallow marine sedimentary beds (i.e. the Örencik formation) at the base and a subaerial volcanic unit (i.e. the Hamamözü formation) in the middle and at the top. This sudden facies change from marine to subaerial environment in the Middle Eocene is a common phenomenon across northern Turkey, implying that a regional uplift event occurred possibly across the suture zone before the initiation of the volcanism during Lutetian. The Middle Eocene lavas span the whole compositional range from basalts to rhyolites and display a calc-alkaline character except for alkaline to mildly-alkaline lavas from the top of the sequence. All lavas display a distinct subduction signature. Our geochemical data indicate that calc-alkaline lavas were derived from a subduction-modified source, whereas alkaline to mildly-alkaline lavas of the late stage were possibly sourced by an enriched mantle domain. Magmas evolved in magma chambers emplaced possibly at two different crustal levels. Magmas in deeper (> 13 km) and possibly larger chambers fractionated hydrous mafic minerals (e.g. amphibole and biotite), two pyroxenes and plagioclase and assimilated a significant amount of crustal material. Intermediate to acid calc-alkaline lavas and pyroclastics were derived from these chambers. Magmas in the shallower chambers, on the other hand (~ < 12 km), crystallized anhydrous mineral assemblages, assimilated little or no crustal material and fed basic to intermediate lavas in the region. Both deep and shallow chambers were periodically replenished by mafic magmas. We argue that a slab breakoff model explains better than any alternative model (i) why the volcanism during the Middle Eocene was confined into a rather narrow belt along the suture zone, (ii) why it initiated almost contemporaneous with a regional uplift after the continental collision event, (iii) why it postdated arc volcanism along the Pontides in the north by 15–20 My, (iv) why it assimilated significant amount of crustal material, and (v) why alkalinity of lavas increased in time.     

Seismic risk assessment of buildings in urban areas: a case study for Denizli,Turkey

This study aims to carry out a seismic risk assessment for a typical mid-size city based on building inventory from a field study. Contributions were made to existing loss estimation methods for buildings. In particular, a procedure was introduced to estimate the seismic quality of buildings using a scoring scheme for the effective parameters in seismic behavior. Denizli, a typical mid-size city in Turkey, was used as a case study. The building inventory was conducted by trained observers in a selected region of Denizli that had the potential to be damaged from expected future earthquakes according to geological and geotechnical studies. Parameters that are known to have some effect on the seismic performance of the buildings during past earthquakes were collected during the inventory studies. The inventory includes data of about 3,466 buildings on 4,226 parcels. The evaluation of inventory data provided information about the distribution of building stock according to structural system, construction year, and vertical and plan irregularities. The inventory data and the proposed procedure were used to assess the building damage, and to determine casualty and shelter needs during the M6.3 and 7.0 scenario earthquakes, representing the most probable and maximum earthquakes in Denizli, respectively. The damage assessment and loss studies showed that significant casualties and economic losses can be expected in future earthquakes. Seismic risk assessment of reinforced concrete buildings also revealed the priorities among building groups. The vulnerability in decreasing order is: (1) buildings with 6 or more stories, (2) pre-1975 constructed buildings, and (3) buildings with 3–5 stories. The future studies for evaluating and reducing seismic risk for buildings should follow this priority order. All data of inventory, damage, and loss estimates were assembled in a Geographical Information System (GIS) database.     

Biodegradation effects over different types of coastal rocks

Modern coastal areas have natural and transported rocks (armourstone) on which various types of organisms live. Burrowing, boring and feeding by these organisms can destroy or modify the coastal rocks and hence change the coastal morphology. Two rock types and three dominant types of organisms have been studied in Mersin Bay, Eastern Mediterranean of southern Turkey. In this study area, Plio-Quaternary conglomerates and variously aged limestone armourplates have been affected by Phoronida worms, bivalve Brachidontes pharaonis (Fischer P. 1870) and the limpet Patella sp. Phoronida colonies were found covering the hard substratum as a mat and form tubular endolithes of 35.0 mm depth and 1.5 mm diameter, whilst Brachidontes pharaonis (Fischer P. 1870) form 44 mm deep vase-shaped gastrochaenolites. The bioerosive activity of Limpet Patella sp., found intertidal and within the spray zone, cannot be significantly observed on the rocks over short time periods. The soft sandy matrix of the conglomerates present were found to disintegrate by bioerosional processes, with the released gravels being transported and deposited onto the beach. Within the armourstone limestone blocks, a maximum of 44.0 mm deep holes developed after 50–60 years. However, these biological activities do not threaten the stability of the blocks due to their hard and homogeneous internal structure. Furthermore, the organism colonies that cover these rocks as a strong mat (maximum 29.0 mm) act to protect their surfaces from further biological attack and wave action.     

A New Mathematical Formulation for Underground Cut-off Grade Determination in the Presence of Pre-concentration Systems

Natural Resources Research - The mining industry is facing increasingly lower grades, which intensifies the need to reduce costs. The depletion of orebodies close to the surface has pushed the...     

Assessment of the impact of anthropogenic activities on the groundwater hydrology and chemistry in Tarsus coastal plain (Mersin,SE Turkey) using fuzzy clustering,multivariate statistics and GIS techniques

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Highlights? Four distinct groundwater classes resulted from the fuzzy c-means clustering method. ? Both geogenic and anthropogenic processes affect the groundwater quality in the area. ? Salinization in the area is due to seawater intrusion and dissolution of evaporites. ? Near the coastal zone, the groundwater level is lowered 2–5 m below the sea level. ? Ancient subsurface hydrological features act as conduits for groundwater flow.     

Chromatographic Separation and Analytic Procedure for Priority Organic Pollutants in Urban Air

A separation procedure was developed for analysis of polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) in urban air, while simultaneously eliminating the interfering compounds. This was carried out by optimization of a column chromatograph with regard to the eluent type (n‐hexane and n‐pentane), volume of eluent, type of sorbent material (silica gel and florisil) and activation level of the sorbent material. The determination of the level of PCBs and PAHs was carried out using gas chromatography (GC) equipped with a mass selective detector (MSD), while determination of the OCPs was carried out by GC equipped with an electron capture detector (μ‐ECD). The use of a silica gel column (10 g, 5% deactivated with H₂O) with 70 mL of n‐hexane gave satisfactory separation of PCBs from PAHs and OCPs. After collecting the PCBs with 70 mL of n‐hexane, 3·20 mL of n‐hexane:ethyl acetate, (1:1, v:v) was adequate for elution of the PAHs and OCPs from the column. The primary aim of this study was to develop a multimethod for analyses of PCBs, PAHs, and OCPs in urban air as well as reducing solvent and sorbent consumption and analysis time during the clean‐up procedure compared to the US EPA standard methods (EPA methods TO‐13A for PAHs and TO‐4A for both PCBs and OCPs).     

Fast segmentation algorithms for long hydrometeorological time series

A time series with natural or artificially created inhomogeneities can be segmented into parts with different statistical characteristics. In this study, three algorithms are presented for time series segmentation; the first is based on dynamic programming and the second and the third—the latter being an improved version of the former—are based on the branch‐and‐bound approach. The algorithms divide the time series into segments using the first order statistical moment (average). Tested on real world time series of several hundred or even over a thousand terms the algorithms perform segmentation satisfactorily and fast. Copyright © 2008 John Wiley & Sons, Ltd.     

Modeling Monthly Mean Flow in a Poorly Gauged Basin by Fuzzy Logic

The estimation of the monthly mean flow is a critical issue in many water resource development projects. However, in practice the mean flow is not easily determined in ungauged and poorly gauged basins. Therefore, in the literature, various flow estimation methods have been developed recently for mountainous regions which are generally ungauged or poorly gauged basins. In this study a fuzzy logic model based on the Mamdani approach was developed to estimate the flow for poorly gauged mountainous basins. This model was applied to the Solakli Basin which is located in the Eastern Black Sea Region of Turkey. Limited rainfall and flow data are available for this basin. In addition to these variables, the stream and time coefficients were introduced and used as variables for modeling. The data was divided into training and testing phases. The model results were compared with the measured data. The comparison depends on seven statistical characteristics, four different error modes and the contour map method. It was observed that the fuzzy model developed in this study yielded reliable results.     

An experimental study on steel‐encased buckling‐restrained brace hysteretic dampers

This paper describes a seismic test program performed on 12 steel‐encased buckling‐restrained braces (BRBs). The use of rolled or built‐up buckling‐restraining mechanisms with welded or bolted attachments was examined. In addition, the effects of bolt pretension, core‐to‐encasing attachment details, aspect ratio of core segment and imperfections due to manufacturing on the brace response were investigated. All specimens were subjected to a stepwise incremental quasi‐static testing protocol with a maximum axial strain amplitude of 2%. All specimens except one showed satisfactory performance with stable hysteretic response and sustained cumulative inelastic deformations in excess of 200 times the yield deformation. Based on the experimental results, the compression strength adjustment factor, and the strain hardening adjustment factor for each excursion were quantified. Test results revealed that these two factors are significantly influenced by the parameters investigated in the experimental program. BRB details were also found to influence the buckling and the yielding patterns of the core segment. Copyright © 2009 John Wiley & Sons, Ltd.     

Correlation between Cerchar abrasivity index,rock properties,and drill bit lifetime

The Cerchar abrasivity index (CAI) is one of the most widely known index method for identification of rock abrasivity. It is a simple and fast testing method providing reliable information on rock abrasiveness. In this study, the relationships between the CAI and some rock properties such as uniaxial compressive strength (UCS), point load strength, Brazilian tensile strength and Schmidt rebound hardness, and equivalent quartz content (EQC) are examined. The relationships between the CAI and drill bit lifetime is also investigated and the type of drill bit wear observed is mentioned. Additionally, the CAI is modeled using simple and multiple linear regression analysis based on the rock properties. Drill bit lifetime is also modeled based on the CAI. The results show that the CAI increases with the increase of the UCS, point load strength, Brazilian tensile strength, L-type and N-type Schmidt rebound hardness, and the EQC. It is concluded that the higher and the lower bit lifetime are obtained for marl and andesitic-basaltic formation, respectively. Moreover, flushing holes, inserted button, button removal, and failures of button on the bits are determined as the type of drill bit wear. The modeling results show that the models based on the UCS and the EQC give the better forecasting performances for the CAI.