Levels of Organohalogenated Pollutants in Human Milk Samples from Konya City,Turkey

This study reports the levels of organochlorine pesticides (OCPs, α‐, β‐, γ‐ and Δ‐HCHs, p,p′‐DDE, p,p′‐DDD and p,p′‐DDT), polychlorinated biphenyls (PCBs, PCB 28, 52, 101, 153, 138 and 180 congeners) and polybrominated diphenyl ethers (PBDEs, PBDE 47, 99, 100, 153 and 154 congeners) in 45 individual human milk samples collected from Konya City, Turkey. Average concentrations of ΣHCHs, ΣDDTs, ΣPCBs and ΣPBDEs were 22.62, 37.10, 104.95 and 67.34 ng/g lipid wt., respectively. No significant differences in investigated pollutants were found between primiparous and multiparous mothers. There was no correlation between levels of each group of pollutants in human milk and the age of mothers. Moreover, there was no significant difference in the levels of ΣDDTs, between mothers who have eaten fish more than once a week and those who consumed fish less than once. An analysis of the infant exposure to DDTs, HCHs and PCBs via mother's milk indicated that the estimated daily intakes of these pollutants were below the guideline proposed by the World Health Organization (WHO) and the Health Canada which means that there is definitely no concern on children health.     

Distribution Study of U,V, Mo,and Zr in Different Sites of Lakes Van and Hazar,River and Seawater Samples by ICP‐MS

The aim of this study is to investigate the concentrations of U, Th, V, Mo, and Zr in natural waters taken from Turkey. Among these water species, Lake Van is the largest soda lake and the fourth largest closed basin on Earth. The water samples were collected from 51 locations between 2008 and 2009. The inductively coupled plasma‐MS was used for determinations. The obtained U and Zr concentrations are in the range of 37–110 µg L^?1 and 17–78 µg L^?1 in Lake Van and 0.53–0.81 µg L^?1 and 0.15–0.19 µg L^?1 in Lake Hazar, respectively. The concentration of uranium in other studied waters varies from the lowest 0.09 µg L^?1 in Tigris (Dicle) river to the highest 4.0 µg L^?1 in Mediterranean Sea water. Mean Mo and V concentrations in the studied water samples were found to be in ranges of 0.1–17 and 2.7–113 µg L^?1, respectively. The obtained highest U concentration in Lake Van correlates with the highest Mo and Zr levels compared to the Lake Hazar and river waters. These results imply that there is a young occurrence of uranium minerals around Lake Van. It is concluded that there is about 50.000 ton of uranium in Lake Van water.     

How does the Red Sea outflow water interact with Gulf of Aden Eddies?

As the Red Sea overflow water (RSOW) enters the Gulf of Aden (GOA), it interacts with a sequence of nearly barotropic, mesoscale eddies originating in the Indian Ocean. To investigate how these eddies impact the dispersal and eastward transport of the RSOW toward the Indian Ocean, a high resolution 3D regional model is employed to explore systematically the interaction between the RSOW and mesoscale eddies. Two types of experiments are conducted. In the first set, we simulate the behavior of RSOW in the presence of an idealized cyclone and an idealized anticyclone. The second type of simulation involves nesting of the regional model (ROMS) within a data-assimilating global model (HYCOM), in which a sequence of mesoscale eddies entering the Gulf of Aden is realistically captured. This simulation is integrated for one year, and includes a simple representation of the seasonality of the RSOW.Bower et al. (2002) suggest that the Red Sea overflow might be a western boundary undercurrent. Consistent with these expectations, the idealized simulations show that the preferred pathway of the RSOW in the absence of eddies is along the coast of Somalia (southern continental shelf) as a western boundary undercurrent. Simultaneously, a cyclonic circulation is generated in the far western GOA due to vortex stretching by the descending outflow. The presence of a cyclone in the western GOA increases the peak RSOW transport, but the cyclone itself rapidly loses its coherence after interacting with the rough topography in the western GOA. The presence of an anticyclone tends to block the preferred boundary pathway and inhibits the eastward transport of the RSOW. The eddies also result in substantially increased mixing of the RSOW in the western GOA.On the basis of the more realistic ROMS experiment, it is found that the modeled RSOW leaves the western part of the Gulf of Aden in short episodic bursts with transports that are an order of magnitude greater than that associated with the quasi-steady RSOW inflow into GOA. Such enhancement in RSOW transport is shown to be induced by cyclonic eddies that cause a rapid discharge of RSOW from the western part of the GOA. We conclude that mesoscale eddies play a key role in the transport and mixing of the RSOW within GOA.     

40Ar–39Ar dating, whole-rock and Sr–Nd–Pb isotope geochemistry of post-collisional Eocene volcanic rocks in the southern part of the Eastern Pontides (NE Turkey): implications for magma evolution in extension-induced origin

The Eocene volcano-sedimentary units in the southern part of the Eastern Pontides (NE Turkey) are confined within a narrow zone of east–west trending, semi-isolated basins in Bayburt, Gümü?hane, ?iran and Alucra areas. The volcanic rocks in these areas are mainly basalt and andesite through dacite, with a dominant calc-alkaline to rare tholeiitic tendency. ⁴⁰Ar–³⁹Ar dating of these volcanic rocks places them between 37.7 ± 0.2 and 44.5 ± 0.2 Ma (Middle Eocene). Differences in the major and trace element variations can be explained by the fractionation of clinopyroxene ± magnetite in basaltic rocks and that of hornblende + plagioclase ± magnetite ± apatite in andesitic rocks. Primitive mantle-normalized multi-element variations exhibit enrichment of large-ion lithophile elements and to a lesser extent, of light rare earth elements, as well as depletion of high field strength elements, thus revealing that volcanic rocks evolved from a parental magma derived from an enriched mantle source. Chondrite-normalized rare earth element patterns of the aforementioned volcanic rocks resemble each other and are spoon-shaped with low-to-medium enrichment (La_N/Lu_N = 2–14), indicating similar spinel lherzolitic mantle source(s). Sr, Nd and Pb isotopic systematics imply that the volcanic rocks are derived from a subduction-modified subcontinental lithospheric mantle. Furthermore, post-collisional thickened continental crust, lithospheric delamination and a subduction-imposed thermal structure are very important in generating Tertiary magma(s). The predominantly calc-alkaline nature of Eocene volcanic rocks is associated with increasing geodynamic regime-extension, whereas tholeiitic volcanism results from local variations in the stress regime of the ongoing extension and the thermal structure, as well as the thickness of the crust and the mantle-crust source regions. Based on volcanic variety and distribution, as well as on petrological data, Tertiary magmatic activity in Eastern Pontides is closely related to post-collisional thinning of the young lithosphere, which, in turn, is caused by extension and lithospheric delamination after collisional events between the Tauride–Anatolide Platform and the Eurasian Plate.     

Post-collisional adakitic volcanism in the eastern part of the Sakarya Zone, Turkey: evidence for slab and crustal melting

New geochemical and isotopic data for post-collisional Early Eocene and Late Miocene adakitic rocks from the eastern part of the Sakarya Zone, Turkey, indicate that slab and lower crustal melting, respectively, played key roles in the petrogenesis of these rocks. The Early Eocene Yoncal?k dacite (54.4 Ma) exhibits high Sr/Y and La/Yb ratios, low Y and HREE concentrations, moderate Mg# (44–65), and relatively high εNd and low ISr values, similar to adakites formed by slab melting associated with subduction. Geochemical composition of the Yoncal?k dacite cannot be explained by simple crystal fractionation and/or crustal contamination of andesitic parent magma, but is consistent with the participation of different proportions of melts derived from subducted basalt and sediments. Sr/Y correlates horizontally with Rb/Y, and Pb/Nd correlates vertically with Nd isotopic composition, indicating that Sr and Pb budgets are strongly controlled by melt addition from the subducting slab, whereas positive correlations between Th/Nd and Pb/Nd, and Rb/Y and Nb/Y point to some contribution of sediment melt. In addition to low concentrations of heavy rare earth elements (~2–3 times chondrite), a systematic decrease in their concentrations and Nb/Ta ratios with increasing SiO₂ contents suggests that slab partial melting occurred in the garnet stability field and that these elements were mobilized by fluid flux. These geochemical and isotopic signatures are best explained by slab breakoff and fusion shortly after the initiation of collision. Although the Late Micone Tavda?? rhyolite (8.75 Ma) has some geochemical features identical to adakites, such as high Sr/Y and La/Yb ratios, low Y and HREE concentrations, other requirements, such as sodic andesite and/or dacite with relatively high MgO and Mg# (>50), relatively high Ni and Cr, low K₂O/Na₂O (<0.4), high Sr (>400 ppm), for slab-derived adakites are not provided. It is sodic in composition and shows no traces of fractionation from dacitic parent magma. Low Nd and high Sr isotope ratios suggest derivation by partial fusion of calc-alkaline, juvenile crust with high Sr/Y and La/Yb ratios.     

The Taraklı Flysch in the Boyali area (Sakarya Terrane,northern Turkey): Implications for the tectonic history of the IntraPontide suture zone

In the Boyal? area, northern Turkey, the tectonic units of the ?stanbul–Zonguldak Terrane and the IntraPontide suture zone are thrust over the deposits at the top of the Sakarya Terrane, known as Tarakl? Flysch. It consists of Early Maastrichtian–Middle Paleocene turbidite and mass-gravity deposits, whose source mainly corresponds to the ?stanbul–Zonguldak Terrane, and, with a lesser extent, to the IntraPontide suture zone. These deposits were sedimented in a foredeep basin developed during the convergence between Sakarya and Eurasian continental microplates. In the Late Paleocene–Early Eocene time span, the Tarakl? Flysch was deformed (D1 phase) during the closure of the foredeep basin. In the Miocene time, the strike-slip tectonics (D2 phase) related to the North-Anatolian fault produced further deformations of the Tarakl? Flysch.     

Detecting the footprint of a longwall mine panel claimed to infringe on a permit boundary at the Soma–Darkale coalfield (Manisa, Turkey) using surface fractures and microgravity measurements

A coal mine panel claimed to infringe on a permit boundary, or to create an hazard after subsidence has been the subject of lawsuits. We study at the Soma–Darkale coalfield (Manisa, Turkey), the footprint of a lignite coal mine panel at a depth of about 150–200 m by mapping all of the surface fractures we could observe, and by developing a post-subsidence density model that we verified through gravity measurements with positive Bouguer anomaly. With the analysis of the fracture map and the gravity data, we were able to identify the footprint of a mine panel from the effect of the anomalous mass due to denser overburden material filling up the space after the extraction of less-dense lignite. Whereas, using empirical methods like the so-called “limit line approach” to evaluate the extent of the area where mining can have subsidence-induced surface fracturing, one could not recognize for certain infringement of permit boundaries. The orientations of the fractures we mapped at the ground surface, the Bouguer gravity map, and a test borehole indicated the presence and dimensions of a coal panel in dispute. The presented approach based on gravity method and fracture observations may be an example to help settle conflicts related to the position of the longwall mine panel.     

Diagenetic and very low-grade metamorphic characteristics of the Paleozoic series of the Istanbul Terrane (NW Turkey)

The Istanbul Terrane along the Black Sea coast in NW Anatolia, is a Gondwana-derived continental microplate, comprising a well-developed Paleozoic succession. Petrographic and X-ray diffraction studies were performed on rock samples from measured sections throughout Ordovician?CCarboniferous sedimentary units. Diagenetic-very low-grade metamorphic clastic (shale/mudstone, siltstone, sandstone) and calcareous rocks (limestone, dolomite) mainly contain phyllosilicates, quartz, feldspar, calcite, dolomite, hematite and goethite minerals. Phyllosilicates are primarily represented by illite, chlorite, mixed-layered chlorite?Cvermiculite (C?CV), chlorite?Csmectite (C?CS) and illite?Cchlorite (I?CC). Feldspar is commonly present in the Ordovician and Carboniferous units, whereas calcite and dolomite are abundant in the Silurian and Devonian sediments. The most important phyllosilicate assemblage is illite?+?chlorite?+?I?CC?+?C?CV?+?C?CS. Illite and chlorite-bearing mixed layer clays are found in all units. The amounts of illites increase in the upper parts of the Silurian series and the lower parts of the Devonian series, whereas chlorite and chlorite-bearing mixed-layers are dominant in the Ordovician and Carboniferous units. Kübler index values of illites reflect high-grade anchimetamorphism for the Early Ordovician rocks, low-grade metamorphism to high-grade diagenesis for the Middle Ordovician?CEarly Silurian rocks and high-grade diagenesis for the Late Silurian?CDevonian units. The K-white micas b cell dimensions indicate intermediate pressure conditions in the Early Ordovician?CEarly Silurian units, but lower pressure conditions in the Middle Silurian?CDevonian units. Illites are composed of 2M ₁?±?1M _d polytypes in all units, except for Upper Ordovician?CLower Silurian units which involve 1M polytype in addition to 2M ₁ and 1M _d polytypes. The 2M ₁/(2M ₁?+?1Md) ratios rise from Devonian to Ordovician together with the increasing diagenetic-metamorphic grade. Chlorites have IIb polytype. In general, crystal-chemical data of clay minerals in the Istanbul Terrane show a gradual increase in the diagenetic/metamorphic grade together with increasing depth. The new data presented in this work indicate that the diagenetic/metamorphic grade of the Paleozoic of the Istanbul Terrane is higher than that of the neighboring Zonguldak Terrane and generated by a single metamorphic phase developed at the end of Carboniferous. This finding contrasts with the metamorphic history of the neighboring Zonguldak Terrane that displays a distinct Early Devonian unconformity and a thermal event.     

Nonlinear baseflow recession analysis in watersheds with intermittent streamflow

Abstract

Discharge in most rivers consists mainly of baseflow exfiltrating from shallow groundwater reservoirs, while surface or other direct flows cease soon after rain storms or snowmelt. Analysis of observed baseflow recessions of two rivers in Turkey with intermittent flows and different geographical and climatic characteristics yielded nonlinear storage–outflow relationships of the highly seasonal aquifers. Baseflow separation was carried out using a nonlinear reservoir algorithm. Baseflow seasonality is related to the hydro-climatic conditions influencing groundwater recharge and evapotranspiration of groundwater. As intermittent streams generally have zero flows in the dry season, calibration of recession parameters is in many cases a complicated task.

Citation Aksoy, H. & Wittenberg, H. (2011) Nonlinear baseflow recession analysis in watersheds with intermittent streamflow. Hydrol. Sci. J. 56(2), 226–237.     

Seasonality of low flows and dominant processes in the Rhine River

Low flow forecasting is crucial for sustainable cooling water supply and planning of river navigation in the Rhine River. The first step in reliable low flow forecasting is to understand the characteristics of low flow. In this study, several methods are applied to understand the low flow characteristics of Rhine River basin. In 108 catchments of the Rhine River, winter and summer low flow regions are determined with the seasonality ratio (SR) index. To understand whether different numbers of processes are acting in generating different low flow regimes in seven major sub-basins (namely, East Alpine, West Alpine, Middle Rhine, Neckar, Main, Mosel and Lower Rhine) aggregated from the 108 catchments, the dominant variable concept is adopted from chaos theory. The number of dominant processes within the seven major sub-basins is determined with the correlation dimension analysis. Results of the correlation dimension analysis show that the minimum and maximum required number of variables to represent the low flow dynamics of the seven major sub-basins, except the Middle Rhine and Mosel, is 4 and 9, respectively. For the Mosel and Middle Rhine, the required minimum number of variables is 2 and 6, and the maximum number of variables is 5 and 13, respectively. These results show that the low flow processes of the major sub-basins of the Rhine could be considered as non-stochastic or chaotic processes. To confirm this conclusion, the rescaled range analysis is applied to verify persistency (i.e. non-randomness) in the processes. The estimated rescaled range statistics (i.e. Hurst exponents) are all above 0.5, indicating that persistent long-term memory characteristics exist in the runoff processes. Finally, the mean values of SR indices are compared with the nonlinear analyses results to find significant relationships. The results show that the minimum and maximum numbers of required variables (i.e. processes) to model the dynamic characteristics for five out of the seven major sub-basins are the same, but the observed low flow regimes are different (winter low flow regime and summer low flow regime). These results support the conclusion that a few interrelated nonlinear variables could yield completely different behaviour (i.e. dominant low flow regime).