Iron isotope fractionation in subduction-related high-pressure metabasites (Ile de Groix,France)

Characterisation of mass transfer during subduction is fundamental to understand the origin of compositional heterogeneities in the upper mantle. Fe isotopes were measured in high-pressure/low-temperature metabasites (blueschists, eclogites and retrograde greenschists) from the Ile de Groix (France), a Variscan high-pressure terrane, to determine if the subducted oceanic crust contributes to mantle Fe isotope heterogeneities. The metabasites have δ⁵⁶Fe values of +0.16 to +0.33‰, which are heavier than typical values of MORB and OIB, indicating that their basaltic protolith derives from a heavy-Fe mantle source. The δ⁵⁶Fe correlates well with Y/Nb and (La/Sm)_PM ratios, which commonly fractionate during magmatic processes, highlighting variations in the magmatic protolith composition. In addition, the shift of δ⁵⁶Fe by +0.06 to 0.10‰ compared to basalts may reflect hydrothermal alteration prior to subduction. The δ⁵⁶Fe decrease from blueschists (+0.19 ± 0.03 to +0.33 ± 0.01‰) to eclogites (+0.16 ± 0.02 to +0.18 ± 0.03‰) reflects small variations in the protolith composition, rather than Fe fractionation during metamorphism: newly-formed Fe-rich minerals allowed preserving bulk rock Fe compositions during metamorphic reactions and hampered any Fe isotope fractionation. Greenschists have δ⁵⁶Fe values (+0.17 ± 0.01 to +0.27 ± 0.02‰) similar to high-pressure rocks. Hence, metasomatism related to fluids derived from the subducted hydrothermally altered metabasites might only have a limited effect on mantle Fe isotope composition under subsolidus conditions, owing to the large stability of Fe-rich minerals and low mobility of Fe. Subsequent melting of the heavy-Fe metabasites at deeper levels is expected to generate mantle Fe isotope heterogeneities.     

Titanium- and water-rich metamorphic olivine in high-pressure serpentinites from the Voltri Massif (Ligurian Alps,Italy): evidence for deep subduction of high-field strength and fluid-mobile elements

Titanium- and water-rich metamorphic olivine (Fo 86–88) is reported from partially dehydrated serpentinites from the Voltri complex, Ligurian Alps. The rocks are composed of mostly antigorite and olivine in addition to magnetite, chlorite, clinopyroxene and Ti-clinohumite. In situ secondary ion mass spectrometry (SIMS) data show that metamorphic olivine has very high and strongly correlated H₂O (up to 0.7 wt%) and TiO₂ contents (up to 0.85 wt%). Ti-rich olivine shows colourless to yellow pleochroism. Olivine associated with Ti-clinohumite contains low Ti, suggesting that Ti-rich olivine is not the breakdown product of Ti-clinohumite. Fourier transform infrared spectroscopy (FTIR) absorption spectra show peaks of serpentine, Ti-clinohumite and OH-related Si vacancies. Combining FTIR and SIMS data, we suggest the presence of clustered planar defects or nanoscale exsolutions of Ti-clinohumite in olivine. These defects or exsolutions contain more H₂O (x ~ 0.1 in the formula 4Mg₂SiO₄·(1?x)Mg(OH,F)₂·xTiO₂) than Ti-clinohumite in the sample matrix (x = 0.34–0.46). In addition to TiO₂ and H₂O, secondary olivine contains significant Li (2–60 ppm), B (10–20 ppm), F (10–130 ppm) and Zr (0.9–2.1 ppm). It is enriched in ¹¹B (δ¹¹B = +17 to +23 ‰). Our data indicate that secondary olivine may play a significant role in transporting water, high-field strength and fluid-mobile elements into the deeper mantle as well as introduce significant B isotope anomalies. Release of hydrogen from H₂O-rich olivine subducted into the deep mantle may result in strongly reduced mantle domains.     

High- and low-Cr chromitite and dunite in a Tibetan ophiolite: evolution from mature subduction system to incipient forearc in the Neo-Tethyan Ocean

The microstructures, major- and trace-element compositions of minerals and electron backscattered diffraction (EBSD) maps of high- and low-Cr# [spinel Cr# = Cr³⁺/(Cr³⁺ + Al³⁺)] chromitites and dunites from the Zedang ophiolite in the Yarlung Zangbo Suture (South Tibet) have been used to reveal their genesis and the related geodynamic processes in the Neo-Tethyan Ocean. The high-Cr# (0.77–0.80) chromitites (with or without diopside exsolution) have chromite compositions consistent with initial crystallization by interaction between boninitic magmas, harzburgite and reaction-produced magmas in a shallow, mature mantle wedge. Some high-Cr# chromitites show crystal-plastic deformation and grain growth on previous chromite relics that have exsolved needles of diopside. These features are similar to those of the Luobusa high-Cr# chromitites, possibly recycled from the deep upper mantle in a mature subduction system. In contrast, mineralogical, chemical and EBSD features of the Zedang low-Cr# (0.49–0.67) chromitites and dunites and the silicate inclusions in chromite indicate that they formed by rapid interaction between forearc basaltic magmas (MORB-like but with rare subduction input) and the Zedang harzburgites in a dynamically extended, incipient forearc lithosphere. The evidence implies that the high-Cr# chromitites were produced or emplaced in an earlier mature arc (possibly Jurassic), while the low-Cr# associations formed in an incipient forearc during the initiation of a new episode of Neo-Tethyan subduction at ~130–120 Ma. This two-episode subduction model can provide a new explanation for the coexistence of high- and low-Cr# chromitites in the same volume of ophiolitic mantle.     

准噶尔盆地玛湖凹陷西斜坡三叠系百口泉组扇三角洲优质储集层预测

针对准噶尔盆地玛湖凹陷西斜坡风南地区三叠系百口泉组扇三角洲砂岩物性空间变化大、优质储集层(孔隙度大于7.4%,渗透率大于0.05×10^-3μm²)预测难的问题,在沉积岩石学、地震沉积学以及地震反演和解释理论指导下,综合利用测井、岩心和三维地震等资料开展了高精度层序地层划分、沉积微相描述和优质储集层地震反演研究。建立了风南井区四级层序地层格架,明确了扇三角洲多期水进水退的充填过程,指出SSQ3和SSQ5是优质储集层的发育层系;识别出扇三角洲平原分流河道、河道间和扇三角洲前缘水下分流水道、河口坝、席状砂等沉积微相,指出扇三角洲平原是优质储集层发育相带;通过应用高分辨层序地层纵向边界和沉积相横向边界约束,进行分层相控叠后地震波阻抗反演,提升储集层预测精度,在SSQ3和SSQ5预测5个优质储集层发育区,提出3口井的井位建议,钻探均获工业油流。     

藏南沉错湖泊沉积多指标揭示的2万年以来环境变化

通过对藏南沉错湖芯TC1孔的研究,分析了TC1孔的粒度、TOC、TN、C/N、Fe/Mn、Sr/Ba以及环境磁学参数等环境代用指标,基本上获得了这一地区2万年以来的环境变化记录。结果显示约19 800~18 000 Cal aBP的温度下降在各指标中具有明显的反映;约16 000 Cal aBP左右,温度在一次跃动上升之后,随即出现急剧下降;约15 200~12 000 Cal aBP,是降温之后的缓慢回升过程;约12 000~9 500 Cal aBP,各种指标均显示湖区环境处于不适宜阶段,特别是11 600~10 400 Cal aBP,湖区环境显著恶化。进入全新世后,湖区环境经历了3次明显的暖期(约9 500~7 600 Cal aBP、约6 800~5 800 Cal aBP、约4 800~3 800 Cal aBP) 和2次冷期(约7 600~6 800 Cal aBP、约5 800~4 800 Cal aBP),呈现出暖干/冷湿的交替规律,具有南亚季风(西南季风) 区气候变化的特征。沉错湖区2万年来的气候环境变化序列中的某些特征时段与格陵兰冰芯记录和青藏高原其他记录相比具有较好的一致性,反映了湖区及藏南地区的气候环境演变特征具有全球性特征。     

Trends in the frequency of synoptic types in central-southern Chile in the period 1961–2012 using the Jenkinson and Collison synoptic classification

Atmospheric circulation patterns in southern Chile (42° 30′ S) were studied in order to determine and analyse the most characteristic synoptic types and their recent trends, as well as to gain an understanding of how they are associated with low-frequency variability patterns. According to the Jenkinson and Collison (J&C) classification method, a 16-point grid of sea-level pressure data was employed. The findings reveal that some synoptic types show statistically significant trends with a 95% confidence level, positively for anticyclonic westerly hybrids (AW) and advective types for third and fourth quadrant wind flows (W, NW, and N) and negatively for SW and cyclonic hybrids (CS and CSW). A model has been constructed of the linear regression of some weather types with teleconnections that most affect Chile: the undetermined types (U), AW were associated with El Niño or the warm phase of the Pacific Decadal Oscillation (PDO), whereas the cyclonic northerly and cyclonic northeasterly types (CN and CNE) were associated with La Niña or cool phase of the PDO. The weather types associated with Antarctic Oscillation (AAO) in its positive phase are anticyclonic northerly and northeasterly and northerly advection types, while in its negative phase are cyclonic southwesterly and advection types.     

Climate Change Impacts for the Conterminous USA: An Integrated Assessment

Here we simulate dryland agriculture in the United States in order to assess potential future agricultural production under a set of general circulation model (GCM)-based climate change scenarios. The total national production of three major grain crops—corn, soybeans, and winter wheat—and two forage crops—alfalfa and clover hay—is calculated for the actual present day core production area (CPA) of each of these crops. In general, higher global mean temperature (GMT) reduces production and higher atmospheric carbon dioxide concentration ([CO₂]) increases production. Depending on the climatic change scenarios employed overall national production of the crops studied changes by up to plus or minus 25% from present-day levels. Impacts are more significant regionally, with crop production varying by greater than ±50% from baseline levels. Analysis of currently possible production areas (CPPAs) for each crop indicates that the regions most likely to be affected by climate change are those on the margins of the areas in which they are currently grown. Crop yield variability was found to be primarily influenced by local weather and geographic features rather than by large-scale changes in climate patterns and atmospheric composition. Future US agronomic potential will be significantly affected by the changes in climate projected here. The nature of the crop response will depend primarily on to what extent precipitation patterns change and also on the degree of warming experienced.     

Atmospheric boundary-layer structure observed during a haze event due to forest-fire smoke

During a haze event in Baltimore, U.S.A. from July 6 to 8, 2002, smoke from forest fires in the Québec region (Canada), degraded air quality and impacted upon local climate, decreasing solar radiation and air temperature. The smoke particles in and above the atmospheric boundary layer (ABL) served as a tracer and provided a unique opportunity to investigate the ABL structure, especially entrainment. Elastic backscatter lidar measurements taken during the haze event distinctly reveal the downward sweeps (or wisps) of smoke-laden air from the free atmosphere into the ABL. Visualisations of mechanisms such as dry convection, the entrainment process, detrainment, coherent entrainment structures, and mixing inside the ABL, are presented. Thermals overshooting at the ABL top are shown to create disturbances in the form of gravity waves in the free atmosphere aloft, as evidenced by a corresponding ripple structure at the bottom of the smoke layer. Lidar data, aerosol ground-based measurements and supporting meteorological data are used to link free atmosphere, mixed-layer and ground-level aerosols. During the peak period of the haze event (July 7, 2002), the correlation between time series of elastic backscatter lidar data within the mixed layer and the scattering coefficient from a nephelometer at ground level was found to be high (R=0.96 for z =324 m, and R=0.89 for z=504 m). Ground-level aerosol concentration was at a maximum about 2 h after the smoke layer intersected with the growing ABL, confirming that the wisps do not initially reach the ground.     

Sensitivity of ENSO characteristics to a new interactive flux correction scheme in a coupled GCM

A fast coupled global climate model (CGCM) is used to study the sensitivity of El Ni?o Southern Oscillation (ENSO) characteristics to a new interactive flux correction scheme. With no flux correction applied our CGCM reveals typical bias in the background state: for instance, the cold tongue in the tropical east Pacific becomes too cold, thus degrading atmospheric sensitivity to variations of sea surface temperature (SST). Sufficient atmospheric sensitivity is essential to ENSO. Our adjustment scheme aims to sustain atmospheric sensitivity by counteracting the SST drift in the model. With reduced bias in the forcing of the atmosphere, the CGCM displays ENSO-type variability that otherwise is absent. The adjustment approach employs a one-way anomaly coupling from the ocean to the atmosphere: heat fluxes seen by the ocean are based on full SST, while heat fluxes seen by the atmosphere are based on anomalies of SST. The latter requires knowledge of the model??s climatological SST field, which is accumulated interactively in the spin-up phase (??training??). Applying the flux correction already during the training period (by utilizing the evolving SST climatology) is necessary for efficiently reducing the bias. The combination of corrected fluxes seen by the atmosphere and uncorrected fluxes seen by the ocean implies a restoring mechanism that counteracts the bias and allows for long stable integrations in our CGCM. A suite of sensitivity runs with varying training periods is utilized to study the effect of different levels of bias in the background state on important ENSO properties. Increased duration of training amplifies the coupled sensitivity in our model and leads to stronger amplitudes and longer periods of the Nino3.4 index, increased emphasis of warm events that is reflected in enhanced skewness, and more pronounced teleconnections in the Pacific. Furthermore, with longer training durations we observe a mode switch of ENSO in our model that closely resembles the observed mode switch related to the mid-1970s ??climate shift??.     

Climate Suitability for Stable Malaria Transmission in Zimbabwe Under Different Climate Change Scenarios

Climate is one factor that determines the potential range of malaria. As such, climate change may work with or against efforts to bring malaria under control. We developed a model of future climate suitability for stable Plasmodium falciparum malaria transmission in Zimbabwe. Current climate suitability for stable malaria transmission was based on the MARA/ARMA model of climatic constraints on the survival and development of the Anopheles vector and the Plasmodium falciparum malaria parasite. We explored potential future geographic distributions of malaria using 16 projections of climate in 2100. The results suggest that, assuming no future human-imposed constraints on malaria transmission, changes in temperature and precipitation could alter the geographic distribution of malaria in Zimbabwe, with previously unsuitable areas of dense human population becoming suitable for transmission. Among all scenarios, the highlands become more suitable for transmission, while the lowveld and areas with low precipitation show varying degrees of change, depending on climate sensitivity and greenhouse gas emission stabilization scenarios, and depending on the general circulation model used. The methods employed can be used within or across other African countries.