Mass Balance Measurements on the Lemon Creek Glacier, Juneau Icefield, Alaska 1953–1998

Annual balance measurements on the Lemon Creek Glacier, Alaska conducted by the Juneau Icefield Research Program (JIRP) from 1953 through 1998 provide a continuous 46 year record. This is one of the nine American glaciers selected in a global monitoring network during the International Geophysical year, 1957/58. These data have been acquired primarily by employing consistent ground methods, conducted on similar annual dates and calculated using comparable methodology. The results have been until now fairly precise, but of uncertain accuracy. An adjunct comparison of topographic surface maps of the glacier made in 1957 and 32 years later in 1989 provides a rough determination of glacier surface elevation changes which are clearly of less precision than the compilation of annual ground data. Airborne surface profiling in 1995, and global positioning system leveling transects in 1996–1998 update the record of surface elevation changes over the past decade. The mean glacier ice thickness reductions suggested by these methods from 1957–1989, from 1957–1995 and from 1957–1998 are ?13.2 m, ?16.4 m, and ?21.7 m, respectively. It is of interest that the geodetic interpretations agree fairly well with the trend of sequential balances from ground-level stratigraphic measurements. To date, however, the infrequent mapping methods in this study have yielded specific balances averaging between 5 and 11% less than those resulting from our annual on-site glaciological monitoring. For future studies this can be an important factor. The ground data are, therefore, the ones in which we have most confidence. These show cumulative ice losses of ?13.9 m (12.7 m water equivalent w.e.) from 1957–1989, of ?19.0 m (?17.1 m w.e.) from 1957–1995, of ?24.4 m (22 m w.e.) from 1957–1998, and ?24.7 m (22.2 m w.e.) for the total cumulative loss over the full 46 years between 1953 and 1998. Although the balance trend has been increasingly negative it averages ?0.48 m/a in w.e. or 0.52 m of ice loss per year. To refine the reliability of density determinations in this data set the effects of internal accumulation from refrozen meltwater producing diagenetic ice structures in the annual firnpack have been taken into account. An unusual dearth of such structures within the 1997/98 firnpack provided a unique opportunity to facilitate application of the probing technique over broad areas of the nv. This added to our ground truth and verified accuracy of the test-pit measurements used in these long-term mass balance computations. The glacier's continuing negative mass balance has fueled a terminal retreat of 800 m during the 1953–1998 period. The annual balance trend indicates that despite a higher mean elevation and a higher elevation terminus from thinning and retreat, mean annual balance has been strongly negative since 1977 (?0.78 m/a w.e.). Dramatically increased negative mass balances have occurred in the 1990s, with 1996 and 1997 being the only years on record with no retained accumulation since field observations were initiated in the glacier source areas in 1948.     

Early oxidation of organic matter in pelagic sediments of the eastern equatorial Atlantic: suboxic diagenesis

Pore water profiles of total-CO₂, pH, PO^3?₄, NO^?₃ plus NO^?₂, SO^2?₄, S^2?, Fe²⁺ and Mn²⁺ have been obtained in cores from pelagic sediments of the eastern equatorial Atlantic under waters of moderate to high productivity. These profiles reveal that oxidants are consumed in order of decreasing energy production per mole of organic carbon oxidized (O₂ > manganese oxides ~ nitrate > iron oxides > sulfate). Total CO₂ concentrations reflect organic regeneration and calcite dissolution. Phosphate profiles are consistent with organic regeneration and with the effects of release and uptake during inorganic reactions. Nitrate profiles reflect organic regeneration and nitrate reduction, while dissolved iron and manganese profiles suggest reduction of the solid oxide phases, upward fluxes of dissolved metals and subsequent entrapment in the sediment column. Sulfate values are constant and sulfide is absent, reflecting the absence of strongly anoxic conditions.     

Coincident observations of ionospheric troughs and the equatorial plasmapause

Explorer 45 traversed the plasmapause (determined approximately via the saturation of the d.c. electric field experiment) at near-equatorial latitudes on field lines which were crossed by Ariel 4 (~600km altitude) near dusk in May 1972 and on field lines which were crossed by Isis II (~1400km altitude) near midnight in December 1971 and January 1972. Many examples were found in which the field line through the near-equatorial plasmapause was traversed by Explorer 45 within one hour local time and one hour universal time of Ariel and Isis crossings of the same L coordinate. For the coincident passes near dusk, the RF electron density probe on Ariel detected electron density depletions near the plasmapause L coordinates when Ariel was in darkness. When the Ariel passes were in sunlight, however, electron depletions were not discernable near the plasmapause field line. On the selected near-midnight passes of Isis II, electron density depressions were typically detected (via the topside sounder) near the plasmapause L coordinate. The dusk Ariel electron density profiles are observed to reflect O⁺ density variations. Even at the high altitude of Isis near midnight, O⁺ is found to be the dominant ion in the trough region whereas H⁺ is dominant at lower latitudes as is evident from the measured electron density scale heights. In neither local time sector was it possible to single out a distinctive topside ionosphere feature as an indicator of the plasmapause field line as identified near the equator. At both local times the equator-determined plasmapause L coordinate showed a tendency to lay equatorward of the trough minimum.     

Spatial scale dependency issues in the application of the Modified Universal Soil Loss Equation (MUSLE)

ABSTRACT

The MUSLE is used within hydrological models to estimate sediment yields from catchments of various sizes, but the spatial scale dependency issues associated with estimating the MUSLE parameters have not been adequately addressed. In the absence of detailed observed data on both hydrological response and sediment yield, some analytical approaches and hypothetical examples are presented to identify the key issues. The results suggest that methods used to estimate both the erosivity and topographic factors are scale dependent, particularly if a lumped or semi-distributed modelling approach is used. The conclusion is that spatial scale dependencies will add to the uncertainties inherent in the use of the MUSLE if not carefully understood and appropriately addressed. One suggested approach is to apply the erosivity equation to a fixed (small) representative area and then scale up to the total catchment, an approach that recognizes the variability of averaged parameters across different spatial scales.     

Coupling the Solar-Wind/IMF to the Ionosphere Through the High Latitude CUSPS

Magnetic merging is a primary means for coupling energy from the solar wind into the magnetosphere–ionosphere system. The location and nature of the process remain as open questions. By correlating measurements from diverse locations and using large-scale MHD models to put the measurements in context, it is possible to constrain our interpretations of the global and meso-scale dynamics of magnetic merging. Recent evidence demonstrates that merging often occurs at high latitudes in the vicinity of the cusps. The location is in part controlled by the clock angle in the interplanetary magnetic field (IMF) Y–Z plane. In fact, B_Y bifurcates the cusp relative to source regions. The newly opened field lines may couple to the ionosphere at MLT locations of as much as 3 hr away from local noon. On the other side of noon the cusp may be connected to merging sites in the opposite hemisphere. In fact, the small convection cell is generally driven by opposite hemisphere merging. B_X controls the timing of the interaction and merging sites in each hemisphere, which may respond to planar features in the IMF at different times. Correlation times are variable and are controlled by the dynamics of the tilt of the interplanetary electric field phase plane. The orientation of the phase plane may change significantly on time scales of tens of minutes. Merging is temporally variable and may be occurring at multiple sites simultaneously. Accelerated electrons from the merging process excite optical signatures at the foot of the newly opened field lines. All-sky photometer observations of 557.7 nm emissions in the cusp region provide a “television picture” of the merging process and may be used to infer the temporal and spatial variability of merging, tied to variations in the IMF.     

Solar limb darkening

The coefficients of several polynomial representations of the limb darkening at 62 wavelengths in the UV and visible portions of the solar spectrum obtained at the McMath Solar Telescope are presented in tabular form. Full corrections for scattered light and seeing have been included in the reductions.Operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation.     

Processes controlling Fe,Mn and Zn in sediments of northern Chesapeake Bay

The dominant physical and chemical processes that control Fe, Mn and Zn are explored by comparing the compositions of sediments and their sources. The $\text{Mn}\text{Fe}$ and $\text{Zn}\text{Fe}$ ratios in sediment are found to be largely unaffected by local hydraulic sorting (unlike the actual concentrations of Fe, Mn and Zn) and thus are useful indicators of origin. The sediments in northern Chesapeake Bay have markedly lower $\text{Mn}\text{Fe}$ and $\text{Zn}\text{Fe}$ ratios than those found in the Susquehanna River (dissolved plus suspended) under ordinary flow, but not under high flow conditions. Since high flow conditions dominate sediment transport, seaward loss of a major fraction of the river-derived Mn and Zn need not be invoked to reconcile sediment and river compositions. Sediments in the seaward end of the northern bay have higher $\text{Mn}\text{Fe}$ and $\text{Zn}\text{Fe}$ ratios than their principal external source, the eroding shore deposits. The excess Zn appears to be derived from the atmosphere; the required depositional flux of Zn is consistent with measurements of the total atmospheric flux. The excess Mn can be explained by remobilization of roughly 5% of the river-borne Mn from sediments in the landward part of the northern bay. Because rare floods influence sediment composition markedly, comparing suspended particles in the river at ordinary stages with resuspended sediment in the estuary would lead to the false interpretation that Mn and Zn were being desorbed in the saltwater.     

The concept of a equilibrium surface applied to particle sources and contaminant distributions in estuarine sediments

Studies have shown that many chemically-reactive contaminants become associated with fine particles in coastal waters and that the rate, patterns, and extent of contaminant accumulation within estuarine systems are extremely variable. In this paper, we briefly review our findings concerning the accumulation patterns of contaminants in several estuarine systems along the eastern coastline of the United States, and have applied a well-established concept in geology, that is “an equilibrium profile,” to explain the observed large variations in these patterns. We show that fine-particle deposition is the most important factor affecting contaminant accumulation in estuarine areas, and that accumulation patterns are governed by physical processes acting to establish or maintain a sediment surface in dynamic equilibrium with respect to sea level, river discharge, tidal currents, and wave activity. Net long-term particle and particle-associated contaminant accumulations are negliglible in areas where the sediment surface has attained “dynamic equilibrium” with the hydraulic regime. Contaminant, accumulation in these areas primarily occurs by the exchange of contaminant-poor sedimentary particles with contaminant-rich suspended particles during physical or biological mixing of the surface sediment. Virtually the entire estuarine particulate and contaminant load bypasses these “equilibrium” areas to accumulate at extremely rapid in relatively small areas that are temporally out of equilibriums as a result of natural processes or human activities. These relatively small areas serve as major sinks for particles from riverine and marine sources, and for biogenic carbon formed in situ within estuaries or on the inner shelf.     

APL computer programs for thermodynamic calculations of equilibria in P-T-X CO 2 space

APL computer programs for the thermodynamic calculation of devolatilization and solid-solid equilibria operate using stored values for the molar volume and entropy of solids, the free energies of H₂O and CO₂, and the free energies of formation for 110 geologically-important phases. P-T-X _{CO 2} calculations of devolatilization equilibria can be made at pressures from 0.2 through 10 kb, and temperatures from 200 through 1,000° C. P-T-X calculations of solid-solid equilibria may be accomplished at pressures to 30 kb and temperatures to 1,000° C. Calculations can be extrapolations from experimental points, or direct calculations from thermochemical data alone. Options are available in these programs to consider effects of: real vs. ideal gas mixing, thermal expansion and compressibility, solid solution, fluid pressure differing from solid pressure, and uncertainties in high-temperature entropies.A collection of thermodynamic data programs accompanies the programs for calculating P-T-X _{CO 2} equilibria. Over a wide range of physical conditions, the data functions report free energies, entropies, fugacities of H₂O and CO₂, high temperature entropies of solids, and activities of components in H₂O-CO₂ mixtures.List of Symbols Activity of H₂O and CO₂ - G_f Free energy of formation of a phase from elements - G_r Free energy change of reaction - G _r ^o Standard state free energy change of a reaction - Free energies of pure H₂O and CO₂ - H _r ^o Standard state enthalpy change for a reaction - K Equilibrium constant - R Gas constant - S _r ^o Standard state entropy change of reaction - S _s ^o Standard state entropy change of solids in a reaction - V_s ^o Standard state volume change of a reaction - V_s ^o Standard state volume change of solids in a reaction - Mole fraction of H₂O and CO₂ - Activity coefficient of H₂O and CO₂