Methane,carbon monoxide and light non-methane hydrocarbon emissions from African savanna burnings during the FOS/DECAFE experiment

Atmospheric samples from savanna burnings were collected in the Ivory Coast during two campaigns in January 1989 and January 1991. About 30 nonmethane hydrocarbons from C₂ to C₆, carbon monoxide, carbon dioxide and methane were measured from the background and also at various distances from the burning. Concentrations in the fire plume reached ppmv levels for C₂-C₄ hydrocarbons, and 5300, 500 and 93 ppmv for CO₂, CO and CH₄ respectively. The excess in the mixing ratios of these gases above their background level is used to derive emission factors relative to CO and CO₂. For the samples collected immediately in the fire plume, a differentiation between high and low combustion efficiency conditions is made by considering the CO/CO₂ ratio. Ethene (C₂H₄), acetylene (C₂H₂), ethane (C₂H₆) and propene (C₃H₆) are the major NMHC produced in the flaming stage, whereas a different pattern with an increasing contribution of alkanes is observed in samples typical of post flaming processes. A strong correlation between methane and carbon monoxide suggests that these compounds are produced during the same stage of the combustion. In samples collected at a distance from the fire and integrated over a period of 30 minutes, the composition is very similar to that of flaming. NMHC/CO₂ is of the order of 0.7%, CH₄/CO₂ of the order of 0.4% and CO/CO₂ of the order of 6.3%. From this study, a global production by African savanna fires is derived: 65 Tg of CO-C, 4.2 Tg of CH₄-C and 6.7 Tg of NMHC-C. Whereas acetylene can be used as a conservative tracer of the fire plumes, only ethene, propene and butenes can be considered in terms of their direct photochemical impact.     

An Electron-Balance Based Approach to Predict the Decreasing Denitrification Potential of an Aquifer

Numerical models for reactive transport can be used to estimate the breakthrough of a contaminant in a pumping well or at other receptors. However, as natural aquifers are highly heterogeneous with unknown spatial details, reactive transport predictions on the aquifer scale require a stochastic framework for uncertainty analysis. The high computational demand of spatially explicit reactive-transport models hampers such analysis, thus motivating the search for simplified estimation tools. We suggest performing an electron balance between the reactants in the infiltrating solution and in the aquifer matrix to obtain the hypothetical time of dissolved-reactant breakthrough at a receptor if the reaction with the matrix was instantaneous. This time we denote as the advective breakthrough time for instantaneous reaction (τ_inst ). It depends on the amount of the reaction partner present in the matrix, the mass flux of the dissolved reactant, and the stoichiometry. While the shape of the reactive-species breakthrough curve depends on various kinetic parameters, the overall timing scales with τ_inst . We calculate the latter by particle tracking. The effort of computing τ_inst is so low that stochastic calculations become feasible. We apply the concept to a two-dimensional test case of aerobic respiration and denitrification. A detailed spatially explicit reactive-transport model includes microbial dynamics. Scaling the time of local breakthrough curves observed at individual points by τ_inst decreased the variability of electron-donor breakthrough curves significantly. We conclude that the advective breakthrough time for instantaneous reaction is efficient in estimating the time over which an aquifer retains its degradation potential.     

An interbasin comparison of tree‐ring reconstructed streamflow in the eastern United States

Tree‐ring reconstructions of streamflow are uncommon in the eastern United States compared with the western United States. Although the east has not experienced severe drought on the scale of the west over the last 100 years, multiyear droughts have stressed the water management systems throughout the east. Here, we reconstruct mean May–September streamflow of three rivers serving population centers in the northeast (Beaver Kill River serving New York, NY), mid‐Atlantic (Potomac River serving Washington, DC), and southeast (Flint River serving Atlanta, GA) to demonstrate the efficacy of reconstructing streamflow in the eastern United States. Then, we conducted an interbasin comparison to identify periods of common variability and examined the influence of the North Atlantic subtropical high on reconstructed streamflow. Our models explained 40–61% of the variance in the instrumental record and passed verification tests in all basins during the period 1675–2000 CE. Droughts and pluvials showed some synchrony across all basins, but the mid‐Atlantic region acted as a hinge, sometimes behaving more like the northeast, and other times like the southeast. Climatic analyses suggest a relationship exists between the North Atlantic subtropical high and reconstructed streamflow that influences the probability of drought and pluvial events. Given the many factors influencing tree growth in closed‐canopy systems, we have shown that careful standardization of individual tree‐ring series, nested regression models, and the use of multiple species can produce robust proxies of streamflow across the eastern seaboard.     

Influences of subsurface heterogeneity and vegetation cover on soil moisture, surface temperature and evapotranspiration at hillslope scales

Physical processes are at the root of determining hydrologic response at all scales. Here, the physical mechanisms linking (1) subsurface heterogeneities to soil moisture and (2) resulting land-surface energy feedbacks to the atmosphere, are examined at the hillslope scale using a fully coupled surface-subsurface-land-surface model, ParFlow. A hillslope with a heterogeneous subsurface and uniform topography was modeled numerically using summer atmospheric conditions and a single precipitation event under controlled boundary conditions in order to isolate the contribution of hydraulic conductivity to land-surface hydrological processes and energy interactions. Patterns of subsurface hydraulic conductivity are shown to govern soil-moisture distribution at the hillslope scale following precipitation. This variability in soil moisture is closely linked to the variability in land-surface energy feedbacks. The role that vegetation plays in subsurface soil moisture and land energy communications is also examined. Results show that hillslope soil moisture variation is first established by patterns in vertical hydraulic conductivity, while later on in the dry-down period, vegetation exerts greater control on the land-surface energy fluxes and controls the rate of hillslope dry down. Furthermore, as compared to bare-soil simulations, grass-cover simulations show an increase in near-surface soil moisture despite water up-take along the rooting depth.     

Earthquake triggering of mud volcanoes

Mud volcanoes sometimes erupt within days after nearby earthquakes. The number of such nearly coincident events is larger than would be expected by chance and the eruptions are thus assumed to be triggered by earthquakes. Here we compile observations of the response of mud volcanoes and other geologic systems (earthquakes, volcanoes, liquefaction, ground water, and geysers) to earthquakes. The compilation shows a clear magnitude–distance threshold for triggering, suggesting that these seemingly disparate phenomena may share similar underlying triggering mechanisms. The compilation also shows that pre-existing geysers and already-erupting volcanoes and mud volcanoes are much more sensitive to earthquakes than quiescent systems.     

Lipids of Recent sediments,Part I: Straight-chain hydrocarbons and carboxylic acids of some temperate lacustrine and sub-tropical lagoonal/tidal flat sediments

Analyses of the lipid constituents of three temperate lacustrine sediments (Rostherne Mere, Esthwaite Water and Grasmere, Great Britain) and three sub-tropical lagoonal/tidal flat sediments (U.S. Virgin Islands, Rockhampton, Qld., Australia and Port Moresby, Papua, New Guinea) indicate the presence of straight-chain components attributable to autochthonous and allochthonous sources. Despite broad similarities in carbon-number distributions, minor differences observed in the respective hydrocarbon and in the respective fatty-acid compositions of the various sediments reflect differences in the sedimentary environments. Lipid constituents obtained by organic solvent extraction following acid hydrolysis appear to include a larger bacterial contribution than that observed in the lipids extracted by solvent alone.     

CSEM technology as a value driver for hydrocarbon exploration

The use of the controlled source electromagnetic (CSEM) method as a risk reduction tool in marine hydrocarbon exploration is gaining increased acceptance in the oil industry. This is related to the ability to map resistivity contrasts in the sub-surface and thus aid the detection of hydrocarbons which are typically more resistive than surrounding rocks. Whereas acoustic (seismic) energy allows for mapping sub-surface structures that may contain hydrocarbons, electromagnetic (EM) energy can often say something about the fluids contained within the structures. Numerous successful CSEM case stories have been published over the past several years. However, there are also quite a few stories about “failure”-cases, although not well documented in the literature. Such “failure”-cases may reflect the lack of understanding of the CSEM technology and how CSEM data can act as a value driver. In order to understand this, it is necessary to handle uncertainties and decisions associated with the technology, These include geological uncertainties, noise models, survey designs, forward modelling parameters, inversion/migration parameters and pre-processing of real data. A proper handling of these uncertainties and decisions will aid in defining and constraining the chance of geologic success and geologic-success-case net present value for prospects prior to drilling wells. As such, the CSEM technology has a significant potential to increase exploration efficiency, if applied correctly.     

Evolution of the Pelagonian carbonate platform complex and the adjacent oceanic realm in response to plate tectonic forcing (Late Triassic and Jurassic), Evvoia, Greece

The Late Triassic and Jurassic platform and the oceanic complexes in Evvoia, Greece, share a complementary plate-tectonic evolution. Shallow marine carbonate deposition responded to changing rates of subsidence and uplift, whilst the adjacent ocean underwent spreading, and then convergence, collision and finally obduction over the platform complex. Late Triassic ocean spreading correlated with platform subsidence and the formation of a long-persisting peritidal passive-margin platform. Incipient drowning occurred from the Sinemurian to the late Middle Jurassic. This subsidence correlated with intra-oceanic subduction and plate convergence that led to supra-subduction calc-alkaline magmatism and the formation of a primitive volcanic arc. During the Middle Jurassic, plate collision caused arc uplift above the carbonate compensation depth (CCD) in the oceanic realm, and related thrust-faulting, on the platform, led to sub-aerial exposures. Patch-reefs developed there during the Late Oxfordian to Kimmeridgian. Advanced oceanic nappe-loading caused platform drowning below the CCD during the Tithonian, which is documented by intercalations of reefal turbidites with non-carbonate radiolarites. Radiolarites and bypass-turbidites, consisting of siliciclastic greywacke, terminate the platform succession beneath the emplaced oceanic nappe during late Tithonian to Valanginian time.