Adoption of flood-related preventive behaviours by people having different risks and histories of flooding

Natural Hazards - The increase in the frequency of floods, which is a projected consequence of climate change, can have wide-ranging health and economic impacts. To cope with these floods and to...     

Estimation of large wood budgets in a watershed and river corridor at interdecadal to interannual scales in a cold‐temperate fluvial system

Large wood (LW) is a ubiquitous feature in rivers of forested watersheds worldwide, and its importance for river diversity has been recognized for several decades. Although the role of LW in fluvial dynamics has been extensively documented, there is a need to better quantify the most significant components of LW budgets at the river scale. The purpose of our study was to quantify each component (input, accumulation, and output) of a LW budget at the reach and watershed scales for different time periods (i.e. a 50‐year period, decadal cycle, and interannual cycle). The LW budget was quantified by measuring the volumes of LW inputs, accumulations, and outputs within river sections that were finally evacuated from the watershed. The study site included three unusually large but natural wood rafts in the delta of the Saint‐Jean River (SJR; Québec, Canada) that have accumulated all LW exported from the watershed for the last 50 years. We observed an increase in fluvial dynamics since 2004, which led to larger LW recruitment and a greater LW volume trapped in the river corridor, suggesting that the system is not in equilibrium in terms of the wood budget but is rather recovering from previous human pressures as well as adjusting to hydroclimatic changes. The results reveal the large variability in the LW budget dynamics during the 50‐year period and allow us to examine the eco‐hydromorphological trajectory that highlights key variables (discharge, erosion rates, bar surface area, sinuosity, wood mobility, and wood retention). Knowledge on the dynamics of these variables improves our understanding of the historical and future trajectories of LW dynamics and fluvial dynamics in gravel‐bed rivers. Extreme events (flood and ice‐melt) significantly contribute to LW dynamics in the SJR river system. Copyright © 2017 John Wiley & Sons, Ltd.     

Non‐Destructive or Noninvasive? The Potential Effect of X‐Ray Fluorescence Spectrometers on Luminescence Age Estimates of Archaeological Samples

The non‐destructive nature of X‐ray fluorescence (XRF) spectrometers is a principal reason for an increase in their use in archaeological science over the last 15 years, especially for analyzing museum‐curated artifacts and in situ site fabrics. Here, we show that low‐power XRF spectrometry can be detrimental for luminescence dating (surface applications such as mud‐wasp nest dating in particular). We investigated the effects of irradiation by X‐rays emitted from handheld and benchtop spectrometers on optically stimulated luminescence (OSL) signals. Measurements were taken using a portable OSL (pOSL) unit on the following unprepared archaeological materials: sedimentary quartz grains, pottery, a mud‐wasp nest, stone tools, and a rock flake with anthropogenically applied pigment and natural pigmentation (iron oxides). We observed an increase in luminescence compared to initial background counts for all materials tested, which could lead to overestimation of age determinations in some situations. Our experiment provides a reminder of the potential effects of X‐ray radiation, and the need for thorough documentation of all recording and analytical techniques applied to archaeological materials.     

On the limits of using combined U-series/ESR method to date fossil teeth from two Early Pleistocene archaeological sites of the Orce area (Guadix-Baza basin,Spain)

The combined U-series/electron spin resonance (ESR) dating method was applied to nine teeth from two Early Pleistocene archaeological sites located in the Orce area (Guadix-Baza Basin, Southern Spain): Fuente Nueva-3 (FN-3) and Barranco León (BL). The combination of biostratigraphy and magnetostratigraphy places both sites between the Olduvai and Jaramillo subchrons (1.78–1.07 Ma).Our results highlight the difficulty of dating such old sites and point out the limits of the combined U-series/ESR dating method based on the US model. We identified several sources of uncertainties that may lead to inaccurate age estimates. Seven samples could not be dated because the dental tissues had (²³⁰Th/²³⁴U) activity ratios higher than equilibrium, indicating that uranium had probably leached from these tissues. It was however possible to calculate numerical estimates for two of the teeth, both from FN-3. One yielded a Middle Pleistocene age that seems to be strongly underestimated; the other provided an age of 1.19 ± 0.21 Ma, in agreement with data obtained from independent methods. The latter result gives encouragement that there are samples that can be used for routine dating of old sites.     

Ensemble-Based Seismic and Production Data Assimilation Using Selection Kalman Model

Data assimilation in reservoir modeling often involves model variables that are multimodal, such as porosity and permeability. Well established data assimilation methods such as ensemble Kalman filter and ensemble smoother approaches, are based on Gaussian assumptions that are not applicable to multimodal random variables. The selection ensemble smoother is introduced as an alternative to traditional ensemble methods. In the proposed method, the prior distribution of the model variables, for example the porosity field, is a selection-Gaussian distribution, which allows modeling of the multimodal behavior of the posterior ensemble. The proposed approach is applied for validation on a two-dimensional synthetic channelized reservoir. In the application, an unknown reservoir model of porosity and permeability is estimated from the measured data. Seismic and production data are assumed to be repeatedly measured in time and the reservoir model is updated every time new data are assimilated. The example shows that the selection ensemble Kalman model improves the characterisation of the bimodality of the model parameters compared to the results of the ensemble smoother.

     

Tinted windows: The presence of the UV absorbing compounds called mycosporine-like amino acids embedded in the frustules of marine diatoms

Diatom frustule-bound organic compounds presumably play an important role in biomineralization and constitute an important pool of organic matter preserved in diatom frustule-rich sediments. In this study, detailed analysis of diatom frustule-bound organic matter in opal-rich Southern Ocean plankton and sediments revealed for the first time the presence of low molecular weight, UV light absorbing compounds called mycosporine-like amino acids (MAAs). Chemically cleaned diatom frustule-derived biosilica was dissolved in HF, releasing bound or entrapped organic compounds that were subsequently characterized using liquid chromatography with UV-Vis and electrospray ionization mass spectrometry (LC/PDA/ESI-MS). Palythine ([M+H]⁺ = 245), porphyra-334 ([M+H]⁺ = 347) and shinorine ([M+H]⁺ = 333) were the most abundant MAAs detected in HF digests of plankton and sediment. Traces of asterina ([M+H]⁺ = 289), palythinol ([M+H]⁺ = 303) and palythinic acid ([M+H]⁺ = 329) were also detected. MAAs in cleaned HF digested frustules were up to two orders of magnitude more abundant than methanol extractable MAAs. MAAs are substituted with acid hydrolysable amino acid residues. Our results suggest that MAAs, and not proteins, could be responsible for the high proportion of the amino acids glycine and threonine found in hydrolysates of HF digested diatom-rich environmental samples. Total MAAs accounted for 3-27% of the carbon and 2-18% of total nitrogen in the frustules undergoing various chemical cleaning treatments. This is the first report of MAAs in close association with a mineral phase and we hypothesize that the mineral matrix could stabilize these compounds, thereby enhancing photoprotection against the harmful effects of UV light. The presence of frustule-bound MAAs in sediment cores further suggests the possibility that they could be used in compound-specific isotope analysis of diatom-bound organic matter and as indicators of past solar irradiance.     

Influence of glass polymerisation and oxidation on micro-Raman water analysis in alumino-silicate glasses

The development of an accurate analytical procedure for determination of dissolved water in complex alumino-silicate glasses via micro-Raman analysis requires the assessment of the spectra topology dependence on glass composition. We report here a detailed study of the respective influence of bulk composition, iron oxidation state and total water content on the absolute and relative intensities of the main Raman bands related to glass network vibrations (LF: ∼490 cm⁻¹; HF: ∼960 cm⁻¹) and total water stretching (H₂O_T: ∼3550 cm⁻¹) in natural glasses. The evolution of spectra topology was examined in (i) 33 anhydrous glasses produced by the re-melting of natural rock samples, which span a very large range of polymerisation degree (NBO/T from 0.00 to 1.16), (ii) 2 sets of synthetic anhydrous basaltic glasses with variable iron oxidation state (Fe³⁺/Fe_T from 0.05 to 0.87), and (iii) 6 sets of natural hydrous glasses (C_H2OT from 0.4 to 7.0 wt%) with NBO/T varying from 0.01 to 0.76.In the explored domain of water concentration, external calibration procedure based on the H₂O_T band height is matrix-independent but its accuracy relies on precise control of the focusing depth and beam energy on the sample. Matrix-dependence strongly affects the internal calibrations based on H₂O_T height scaled to that of LF or HF bands but its effect decreases from acid (low NBO/T, SM) to basic (high NBO/T, SM) glasses. Structural parameters such as NBO/T (non-bridging oxygen per tetrahedron) and SM (sum of structural modifiers) describe the matrix-dependence better than simple compositional parameters (e.g. SiO₂, Na₂O + K₂O). Iron oxidation state has only a minor influence on band topology in basalts and is thus not expected to significantly affect the Raman determinations of water in mafic (e.g. low SiO₂, iron-rich) glasses. Modelling the evolution of the relative band height with polymerisation degree allows us to propose a general equation to predict the dissolved water content in natural glasses:

     

Recent climatic trends and linkages to river discharge in Central Vietnam

In this study, change in rainfall, temperature and river discharge are analysed over the last three decades in Central Vietnam. Trends and rainfall indices are evaluated using non‐parametric tests at different temporal levels. To overcome the sparse locally available network, the high resolution APHRODITE gridded dataset is used in addition to the existing rain gauges. Finally, existing linkages between discharge changes and trends in rainfall and temperature are explored. Results are indicative of an intensification of rainfall (+15%/decade), with more extreme and longer events. A significant increase in winter rainfall and a decrease in consecutive dry days provides strong evidence for a lengthening wet season in Central Vietnam. In addition, trends based on APHRODITE suggest a strong orographic signal in winter and annual trends. These results underline the local variability in the impacts of climatic change at the global scale. Consequently, it is important that change detection investigations are conducted at the local scale. A very weak signal is detected in the trend of minimum temperature (+0.2°C/decade). River discharge trends show an increase in mean discharge (31 to 35%/decade) over the last decades. Between 54 and 74% of this increase is explained by the increase in precipitation. The maximum discharge also responds significantly to precipitation changes leading to a lengthened wet season and an increase in extreme rainfall events. Such trends can be linked with a likely increase in floods in Central Vietnam, which is important for future adaptation planning and management and flood preparedness in the region. Copyright © 2012 John Wiley & Sons, Ltd.