Ultraviolet irradiation of naphthalene in H2O ice: Implications for meteorites and biogenesis

Abstract— The polycyclic aromatic hydrocarbon (PAH) naphthalene was exposed to ultraviolet radiation in H₂O ice under astrophysical conditions, and the products were analyzed using infrared spectroscopy and high‐performance liquid chromatography. As we found in our earlier studies on the photoprocessing of coronene in H₂O ice, aromatic alcohols and ketones (quinones) were formed. The regiochemistry of the reactions is described and leads to specific predictions of the relative abundances of various oxidized naphthalenes that should exist in meteorites if interstellar ice photochemistry influenced their aromatic inventory. Since oxidized PAHs are present in carbon‐rich meteorites and interplanetary dust particles (IDPs), and ubiquitous in and fundamental to biochemistry, the delivery of such extraterrestrial molecules to the early Earth may have played a role in the origin and evolution of life.     

The anastomosing pattern and the extensively distributed scroll bars in the middle Amazon River

The middle Amazon River, between the confluences of the Negro and Madeira Rivers in Brazil, shows an anastomosing morphology with relatively stable, multiple interconnected channels that locally enclose floodbasins. Additionally, this system is characterized by sinuous secondary channels with meander development, discontinuous natural levees concentrated on the concave banks and extensively distributed scroll bars mainly in the islands, related to subrecent and present‐day migration of mainly secondary channels. This distinguishes the Amazon from many other anastomosing rivers that have laterally stable, non‐meandering channels. We analyzed sedimentary processes using field data, morphology and channel changes trough a temporal analysis using remote sensing data and obtained optically stimulated luminescence (OSL) dating to understand the genesis of this large anastomosing river and the development of its meandering secondary channels. Scroll bars have developed in a multichannel river system at least since 7.5 ± 0.85 ka. Avulsion is inferred to have played a minor role in the formation of this anastomosing system, with only one documented case while mid‐channel bar formation and chute cut‐offs of the main and secondary channels are the main formative mechanisms of anastomosis in this system. Differences in resistance to erosion control the relatively straight main channel and allow secondary channels to develop a meandering platform. Vegetation contributes to the relative stability of islands and the floodplain. Low gradient and high average aggradation rate (1.1 mm yr^?1) are conditions which favor the development of anastomosis. Additionally, stable external conditions, low abandonment rate of older channels and independence from high avulsion frequency suggest a long‐lived, semi‐static type of anastomosing river in this reach of the Amazon. Copyright © 2012 John Wiley & Sons, Ltd.     

Magnetic crustal character in Central Ireland

The simplest magnetic model for the upper 20 km of crust in central Ireland is of two layers. A thin, weakly magnetic upper layer carrying a number of magnetic bodies that can be related to surface geology overlies a magnetic crustal zone whose gross magnetization increases towards the north. The deeper trace of the lapetus Suture in central Ireland forms the boundary between a more magnetic northern crustal area and a less magnetic southern area. A pre-Carboniferous major dextral offset of this suture boundary occurs in the Limerick area. The suture is traced beneath the Dingle peninsula in the far south-west of Ireland. In east-central Ireland, between the Iapetus Suture and Southern Upland Line, the crust contains a large, south-dipping magnetic body with no surface expression, which produces the Virginia magnetic anomaly. The development of magnetic bodies — in particular, volcanic rocks of Carboniferous age — has been controlled by regional stress patterns. The major volcanic centre at Limerick lies at the intersection of two major Caledonian block fault systems just to the north of the surface trace of the Hercynian Front.