Slab melt as metasomatic agent in island arc magma mantle sources, Negros and Batan (Philippines)

Abstract Two new cases of association of adakites with ‘normal’ island arc lavas and transitional adakites are recognized in the islands of Batan and Negros in northern and central Philippines, respectively. The Batan lavas are related to the subduction of the middle Miocene portion of the South China Sea basin along the Manila trench; those of Negros come from the almost aseismic subduction of the middle Miocene Sulu Sea crust along the Negros trench. The occurrence of the Batan adakites is consistent with previous findings showing adakitic glass inclusions within minerals of mantle xenoliths associated with Batan arc lavas. The similarity of adakite ages (1.09 Ma) and that of the metasomatized xenoliths (1 Ma) suggests that both are linked to the same slab‐melting and metasomatic event. Earlier Sr, Pb and Nd‐isotopic studies, however, also reveal the presence of an important sediment contribution to the Batan lava geochemistry. Thus, the role played by slab melts, assumed to have mid‐ocean ridge basalts‐like (MORB) isotopic characteristics, in enriching the Batan subarc mantle is largely masked by the sediment input. The Negros adakites are present only in Mount Cuernos, the volcanic center nearest to the Negros trench. Batch partial melting calculations show that the Negros adakites could be derived from a garnet amphibolitic source with normal‐MORB (N‐MORB) geochemistry. This is supported by the MORB‐like isotopic characteristics of the Mount Cuernos lavas. The volcanic rocks from the other volcanoes consist of normal arc and transitional adakitic lavas that have slightly higher Sr‐ and Pb‐isotopic ratios, probably due to slight sediment input. Mixing of adakites and normal arc lavas to produce transitional adakites is only partly supported by trace element geochemistry and not by field evidence. The transitional adakites can be modeled as partial melts of an adakite‐enriched mantle. Trace element enrichment of non‐adakitic lavas could reflect the interaction of their mantle source with uprising slab melts, as metasomatic mantle minerals scavenge certain trace elements from the adakitic fluids. Therefore, in arcs beneath which thick (up to 2 km) continent‐derived detrital sediments are involved in subduction, like in Batan, the sediment signature can overwhelm the slab melt input. In arcs like Negros where slow subduction could cause a more efficient scraping of thinner (approximately 1 km) detrital sediments, the contribution of slab melts is easier to detect.     

Behavior of Niobium, Tantalum and other high field strength elements in adakites and related lavas from The Philippines

Abstract Pliocene–Quaternary adakites and spatially and temporally associated niobium-enriched basalts (the latter thought to be derived by melting of slab melt-metasomatized mantle) from the Philippine island arcs have been selected for analysis of high field strength elements (HFSE). All these samples have nearly constant and chondritic Zr/Hf ratio (36.5) and slightly infrachondritic Nb/Ta ratio (14.7). We interpret adakitic magmas to be derived from the partial melting at approximately 900°C of subducted mid-ocean ridge basalts (MORB) crust, with rutile and/or ilmenite as residual minerals. Melting calculations show that, under these conditions, slab melts should have suprachondritic Nb/Ta ratios. The obvious discrepancy with our data is attributed to insufficient knowledge of rutile-melt partition coefficients for HFSE. Consequently, abnormal Nb/Ta or Zr/Hf ratios cannot be considered as potential markers of slab melting processes in island arcs.     

Collision, subduction and accretion events in the Philippines: A synthesis

Abstract The Philippines preserves evidence of the superimposition of tectonic processes in ancient and present‐day collision and subduction zone complexes. The Baguio District in northern Luzon, the Palawan–Central Philippine region and the Mati–Pujada area in southeastern Mindanao resulted from events related to subduction polarity reversal leading to trench initiation, continent‐arc collision and autochthonous oceanic lithosphere emplacement, respectively. Geological data on the Baguio District in Northern Luzon reveal an Early Miocene trench initiation for the east‐dipping Manila Trench. This followed the Late Oligocene cessation of subduction along the west‐dipping proto‐East Luzon Trough. The Manila Trench initiation, which is modeled as a consequence of the counter‐clockwise rotation of Luzon, is attributed to the collision of the Palawan microcontinental block with the Philippine Mobile Belt. In the course of rotation, Luzon onramped the South China Sea crust, effectively converting the shear zone that bounded them into a subduction zone. Several collision‐related accretionary complexes (e.g. Romblon, Mindoro) are present in the Palawan–Central Philippine region. The easternmost collision zone boundary is located east of the Romblon group of islands. The Early Miocene southwestward shift of the collision boundary from Romblon to Mindoro started to end by the Pliocene. Continuous interaction between the Palawan microcontinental block and the Philippine Mobile Belt is presently taken up again along the collisional boundary east of the Romblon group of islands. The Mati–Pujada Peninsula area, on the other hand, is underlain by the Upper Cretaceous Pujada Ophiolite. This supra‐subduction zone ophiolite is capped by chert and pelagic limestones which suggests its derivation from a relatively deep marginal basin. The Pujada Ophiolite could be a part of a proto‐Molucca Sea plate. The re‐interpretation of the geology and tectonic settings of the three areas reaffirm the complex geodynamic evolution of the Philippine archipelago and addresses some of its perceived geological enigmas.     

From alkali basalt to phonolite in hand-size samples: vapor-differentiation effects in the Bouzentès lava flow (Cantal, France)

The Bouzentès lava flow is a 20-m-thick alkali basalt flow emplaced during the last stage of formation of the Cantal stratovolcano at 4.2 Ma. Its upper part has 1- to 20-cm-thick vesicle-rich segregation sheets which recur every 0.1–2 m. These horizontal veins are hawaiitic in composition. They are characterized by hypertrophic development of their minerals (‘pegmatoids’) and by glassy phonolitic segregation vesicles. Internal differentiation within the Bouzentès lava flow was triggered by an unusually high water content, as suggested by pre-emptive iddingsite alteration of olivine phenocrysts. The proposed model of formation of the segregation sheets includes the upward motion of diapirs of residual melt plus addition of vapor from the bottom of the central liquid lens to the base of the upper solidified crust of the cooling lava flow. Olivine settling appears to have been inhibited or at least retarded by upward migration of melt plus vesicles. Most of the features observed in Bouzentès recall the internal differentiation processes usually described within thick Hawaiian lava lakes. The segregation vesicles are believed to result from an increase of gas solubility in residual melt during the crystallization process.     

Modeling environmental effects on the size-structured energy flow through marine ecosystems. Part 1: The model

This paper presents an original size-structured mathematical model of the energy flow through marine ecosystems, based on established ecological and physiological processes and mass conservation principles. The model is based on a nonlocal partial differential equation which represents the transfer of energy in both time and body weight (size) in marine ecosystems. The processes taken into account include size-based opportunistic trophic interactions, competition for food, allocation of energy between growth and reproduction, somatic and maturity maintenance, predatory and starvation mortality. All the physiological rates are temperature-dependent. The physiological bases of the model are derived from the dynamic energy budget theory. The model outputs the dynamic size-spectrum of marine ecosystems in term of energy content per weight class as well as many other size-dependent diagnostic variables such as growth rate, egg production or predation mortality.In stable environmental conditions and using a reference set of parameters derived from empirical studies, the model converges toward a stationary linear log–log size-spectrum with a slope equal to −1.06, which is consistent with the values reported in empirical studies. In some cases, the distribution of the largest sizes departs from the stationary linear solution and is slightly curved downward. A sensitivity analysis to the parameters is conducted systematically. It shows that the stationary size-spectrum is not very sensitive to the parameters of the model. Numerical simulations of the effects of temperature and primary production variability on marine ecosystems size-spectra are provided in a companion paper [Maury, O., Shin, Y.-J., Faugeras, B., Ben Ari, T., Marsac, F., 2007. Modeling environmental effects on the size-structured energy flow through marine ecosystems. Part 2: simulations. Progress in Oceanography, doi:10.1016/j.pocean.2007.05.001].     

Clinopyroxene composition as a method of identification of the magmatic affinities of paleo-volcanic series

Uranium contents and²³⁴U/²³⁸U activity ratios have been determined for groundwaters from the Lincolnshire Limestone artesian aquifer in eastern England. Changes in the quantitative and isotopic chemistry of the dissolved uranium are explained in terms of a mixing model involving the rapidly moving fissure water and much older water stored in the pore system of this oolitic limestone. The western part of the aquifer, closest to recharge, is dominated by oxidising groundwaters which then enter a reducing zone towards the east, where there is an abrupt decrease in Eh and the chlorinity of the groundwaters begins to increase. Uranium contents in the oxidising zone range from 0.7 to 3.4 μg kg^?1 and²³⁴U/²³⁸U activity ratio of this dissolved uranium is close to unity, the equilibrium value. The uranium content decreases abruptly when the grounwaaters enter the reducing zone, averaging 0.04 μg kg^?1 east of the oxidation/reduction barrier. Simultaneously with the decrease in uranium content, there is an increase in²³⁴U/²³⁸U activity ratio and this ratio increases to a maximum within 7 km of the oxidation/reduction barrier. This increase in activity ratio is attributed to enhanced²³⁴U solution due to²³⁴Th recoil from uraniferous fissure surfaces east of the oxidising zone. The activity ratio of dissolved uranium in the ancient pore waters could in principle reach high values due to²³⁴Th recoil from the oolith surfaces. However, the activity ratio actually declines further east and this can only be explained as a consequence of mixing with pore waters in which the uranium activity ratio is closer to equilibrium.²³⁴Th recoil from the oolith surfaces has probably been inhibited by sealing of the uranium-bearing surfaces in the process of oolith cementation.     

Le magmatisme sursaturé infrabréchique du centre du Cantal (Massif Central français)

Silica oversaturated lavas and pyroclastic flows, 9 to 7,5 M.Y. old, have been emplaced during the sinking of the central volcanotectonic caldera of alkalic stratovolcano Cantal. They can be grouped in a non linear fractional crystallisation series ranging from mugearites to rhyolitic trachytes, comenditic trachytes and comendites through benmoreites. Their evolution results mainly from plagioclase fractionation, alkali feldspar and ferromagnesian minerals playing only a restricted role. We consider this oversaturated group, which follows primordial basanitic lavas in the history of the stratovolcano, as the most evolved liquids resulting from differentiation under high water pressures and oxygen fugacities of alkali basic magmas in a great magma chamber. The less evolved liquids (intermediate and basic) would have been emplaced later, building the greatest part of the volcanic pile.     

Bimodal back-arc alkaline magmatism after ridge subduction: Pliocene felsic rocks from Central Patagonia (47°S)

Volumetrically minor microsyenites, alkali microgranite and related trachytic dykes intrude early Pliocene OIB-like alkali basaltic and basanitic flows of the Meseta del Lago Buenos Aires in Central Patagonia (47°S–71°30′W), and occur together with scarce trachytic lava flows. Whole-rock K–Ar ages between 3.98 and 3.08 Ma indicate that the emplacement of these felsic rocks occurred more or less synchronously with that of the post-plateau basaltic sequence that they intrude, during a bimodal mafic–felsic magmatic episode devoid of intermediate compositions. Chemically, these rocks have A₁-type granitoid affinities and are characterized by high silica and alkali contents (60–68 wt.% SiO₂; 8.7–10.8 wt.% Na₂O + K₂O), major and trace elements patterns evidencing evolution by low-pressure fractional crystallization, and Sr and Nd isotopic signatures similar to those of coeval basalts ((⁸⁷Sr/⁸⁶Sr)_o = 0.70488–0.70571; (¹⁴³Nd/¹⁴⁴Nd)_o = 0.512603–0.512645). Nevertheless, some of them have the most radiogenic Sr values ever reported for a magmatic rock in the Meseta and even in the whole Neogene Patagonian Plateau Lavas province ((⁸⁷Sr/⁸⁶Sr)_o = 0.70556–0.70571; (¹⁴³Nd/¹⁴⁴Nd)_o = 0.512603–0.512608). In addition, very high contents of strongly incompatible elements in the most evolved rocks, together with Sr isotopic ratios higher than those of coeval basalts, suggest the occurrence of open-system magmatic processes. Continuous fractional crystallization from a primitive basaltic source, similar to post-plateau coeval basalts, towards alkali granites combined with small rates of assimilation of host Jurassic tuffs (AFC) in a shallow magmatic reservoir, best explains the geochemical and petrographic features of the felsic rocks. Therefore, A₁-type magmatic rocks can be generated by open-system crystallization of deep asthenospheric melts in back-arc tectonic settings.

In Central Patagonia, these  3–4 Ma old alkaline intrusions occur aligned along a  N160–170 trending lineament, the Zeballos Fault Zone, stacking the morphotectonic front of one segment of the Patagonian Cordillera. Intrusion along this fault zone occurred during the onset of a new transtensional or extensional event in the area, related to major regional tectonics occurring in possible relation with the collision of one segment of the Chile Spreading Ridge with the trench.     

Water contents of clinopyroxenes from sub‐arc mantle peridotites

One poorly constrained reservoir of the Earth's water budget is that of clinopyroxene in metasomatised, mantle peridotites. This study presents reconnaissance Sensitive High‐Resolution, Ion Microprobe–Stable Isotope (SHRIMP–SI) determinations of the H₂O contents of (dominantly) clinopyroxenes in rare mantle xenoliths from four different subduction zones, i.e. Mexico, Kamchatka, Philippines, and New Britain (Tabar‐Feni island chain) as well as one intra‐plate setting (western Victoria). All of the sub‐arc xenoliths have been metasomatised and carry strong arc trace element signatures. Average measured H₂O contents of the pyroxenes range from 70 ppm to 510 ppm whereas calculated bulk H₂O contents range from 88 ppm to 3 737 ppm if the variable presence of amphibole is taken into account. In contrast, the intra‐plate, continental mantle xenolith from western Victoria has higher water contents (3 447 ppm) but was metasomatised by alkali and/or carbonatitic melts and does not carry a subduction‐related signature. Material similar to the sub‐arc peridotites can either be accreted to the base of the lithosphere or potentially be transported by convection deeper into the mantle where it will lose water due to amphibole breakdown.