Characterization of particulate matter in the Apulia Region (South of Italy): features and critical episodes

The chemical composition of PM₁₀ and PM_2.5 samples collected during two seasonal monitoring campaigns at residential, urban and industrial Apulia Region- sites was investigated. Ionic fraction, carbonaceous compounds and Polycyclic Aromatic Hydrocarbons were determined for all samples. High correlations among PM data collected in the investigated sites suggested the regional character of particulate matter. It was also confirmed by five days back trajectories analysis. Moreover, no significant seasonal trend in PM mass concentration was observed in the investigated sites. These results, relevant for the area under investigations, were not observed in the North of Italy and Europe and allow to conclude that PM₁₀ and PM_2.5 cannot be considered ‘good’ indicators for the evaluation of local anthropic contributions to air quality. On the contrary, the high levels of Polycyclic Aromatic Hydrocarbons found in Taranto sampling sites suggested that PAHs can be a better indicator for this purpose. This result is also relevant in order to weigh the importance of industrial area and to suggest right policy control to decision makers.     

Examining Granger causality between atmospheric parameters and radon

In this paper, we study the relationship between atmospheric parameters (i.e., temperature and humidity) and radon data. We use the linear Granger causality in order to observe possible connections, on short and mid time scale periods, between radon time series and meteorological parameters that strongly influence radon emissions. The analysis suggests radon emission is not affected by these atmospheric parameters on short periods, while there is an evidence of Granger causality on mid periods.     

Geomaterials related to photovoltaics: a nanostructured Fe-bearing kuramite,Cu<Subscript>3</Subscript>SnS<Subscript>4</Subscript>

The successful synthesis of nanoparticles of Fe-bearing kuramite, (Cu,Fe)₃SnS₄, is reported in this study. Nanocrystalline powders were obtained through a mild, environmentally friendly and scalable solvothermal approach, in a single run. The sample was the object of a multidisciplinary investigation, including X-ray diffraction and absorption, scanning electron microscopy and microanalysis, electron paramagnetic resonance, diffuse reflectance and Mössbauer spectroscopy as well as SQUID magnetometry. The nanoparticles consist of pure Fe-bearing kuramite, exhibiting tetragonal structure. The valence state of the metal cations was assessed to be Cu⁺, Sn⁴⁺ and Fe³⁺. The material presents a band gap value of 1.6 eV, which is fully compatible with solar cell applications. The uptake of Fe by nanokuramite opens a compositional field where the physical properties can be tuned. We thus foster the application of Fe-bearing nanokuramite for photovoltaics and energy storage purposes.     

Planktonic foraminiferal distribution record productivity cycles: evidence from the Aptian-Albian Piobbico core (central Italy)

The Aptian-Albian 'Scisti a Fucoidi' varicoloured pelagic sediments in central Italy, show a 'couplet' alternation of carbonate-rich/carbonate-poor layers, which are interpreted as the sedimentary expression of precession (frequency 19–23 kyr). Carbonate content, chromatic variation, and planktonic foraminiferal abundance were analysed at a 1-cm spacing for a 10-m interval of the Piobbico core, specifically drilled through this formation. Spectral analysis of these parameters shows a prominent signal equated to the c . 100 kyr cycle of orbital eccentricity at a sedimentation rate of 5 mm kyr⁻¹. The coherency of the spectral response of each parameter suggests that a single mechanism controlled the whole sedimentary record. Detailed study of planktonic foraminiferal distribution of the same section at 1-mm scale resolves the Milankovitch frequencies of 41 kyr and 18 to 23 kyr, equated with the obliquity and precessional cycles. But foraminiferal abundance is not in phase with carbonate content, which was largely controlled by calcareous nannofossils, but peaked at intermediate carbonate values. The proposed model for explaining the discrepancy at the precessional level is that foraminifera thrived at intermediate values of the precession index, when the environment was only moderately fertile but stable, while during highs of the precession index, mixing of the water column increased fertility and caused calcareous nannofossil blooms and restriction of planktonic foraminifera to few and tolerant species. The resulting bimodality of foraminiferal abundance per precessional cycle appears to be recorded in the spectrum by peaks at the 11 and 14 kyr levels. Cross correlation of foraminiferal abundances with the calcium carbonate curve over 1–2 Myr intervals produces discrepant results (apparent phase lags) which we attribute to differences in the response to the fundamental eccentricity cycles.     

Analytical prediction of ultimate moment and curvature of RC rectangular sections in compression

This paper presents closed form expressions linking the ultimate bearing capacity to the ultimate curvature of rectangular RC sections subjected to axial load and bending moment acting in one of the two symmetry planes of the section. With respect to possible simplified formulations the following effects are also considered: confinement of the concrete, hardening of the longitudinal reinforcement, and presence of reinforcing bars distributed orthogonally to the neutral axis. The formulation is proposed in dimensional terms after a preliminary definition of the geometrical and mechanical parameters governing the structural response of the class of sections considered. The analytical expressions derived using the proposed approach also allow one to determine the compression level that makes the ultimate bending moment maximum as well as to evaluate the curvature corresponding to the first yielding of the principal reinforcement in tension. Comparing this value of curvature with the ultimate one, an approximate estimation of the available ductility of curvature of the section can be made. The analytical procedure is validated by comparing the results with those obtained using a typical numerical approach. Some experimental results are also considered.     

Modelling river and riparian vegetation interactions and related importance for sustainable ecosystem management

We discuss the importance of modelling riparian vegetation and river flow interactions under differing hydrologic regimes. Modelling tools have notable implications with regard to the understanding of riverine ecosystem functioning and to promote sustainable management of water resources. We present both deterministic and stochastic approaches with different levels of simplification, and discuss their use in relation to river and vegetation dynamics at the related scale of interest. We apply such models to both meandering and braided rivers, in particular focusing on the floodplain dynamics of an alpine braided river affected by water impoundment. For this specific case we show what the expected changes in riparian vegetation may be in a ‘controlled release’ scenario for the postdam river Maggia, Switzerland. Finally, the use of these models is discussed in the context of current research efforts devoted to river restoration practice.     

Bombs behaving badly: unexpected trajectories and cooling of volcanic projectiles

We collected thermal infrared video of two explosive eruptions at Stromboli in June 2008 and manually traced the trajectories of 95 particles launched during two eruptions. We found that 10–15?% of the analyzed trajectories deviated from predicted curves due to collisions, causing one particle to travel horizontally more than twice as far as expected. Furthermore, we observed an oscillatory cooling behavior for the airborne pyroclasts, with a median period of 0.46?s. Measured cooling was typically much faster than model-predicted cooling with discrepancies of up to 40?% between measured cooling and theoretical modeling. We interpret the measured cooling curves as resulting from the spinning and twisting and tearing of particles during travel: the periodic re-exposing of the hotter core of the pyroclasts to the atmosphere may cause the observed oscillations, and the spinning may accelerate cooling by enhancing convective heat transfer. Current volcanic trajectory and cooling models do not account for projectile collisions, spinning, or tearing and can thus severely underestimate the maximum landing distance and cooling rates of large pyroclasts.     

A revisitation of TRIX for trophic status assessment in the light of the European Water Framework Directive: application to Italian coastal waters

The trophic status classification of coastal waters at the European scale requires the availability of harmonised indicators and procedures. The composite trophic status index (TRIX) provides useful metrics for the assessment of the trophic status of coastal waters. It was originally developed for Italian coastal waters and then applied in many European seas (Adriatic, Tyrrhenian, Baltic, Black and Northern seas). The TRIX index does not fulfil the classification procedure suggested by the WFD for two reasons: (a) it is based on an absolute trophic scale without any normalization to type-specific reference conditions; (b) it makes an ex ante aggregation of biological (Chl-a) and physico-chemical (oxygen, nutrients) quality elements, instead of an ex post integration of separate evaluations of biological and subsequent chemical quality elements. A revisitation of the TRIX index in the light of the European Water Framework Directive (WFD, 2000/60/EC) and new TRIX derived tools are presented in this paper. A number of Italian coastal sites were grouped into different types based on a thorough analysis of their hydro-morphological conditions, and type-specific reference sites were selected. Unscaled TRIX values (UNTRIX) for reference and impacted sites have been calculated and two alternative UNTRIX-based classification procedures are discussed. The proposed procedures, to be validated on a broader scale, provide users with simple tools that give an integrated view of nutrient enrichment and its effects on algal biomass (Chl-a) and on oxygen levels. This trophic evaluation along with phytoplankton indicator species and algal blooms contribute to the comprehensive assessment of phytoplankton, one of the biological quality elements in coastal waters.