The formation conditions of enstatite chondrites: Insights from trace element geochemistry of olivine‐bearing chondrules in Sahara 97096 (EH3)

We report in situ LA‐ICP‐MS trace element analyses of silicate phases in olivine‐bearing chondrules in the Sahara 97096 (EH3) enstatite chondrite. Most olivine and enstatite present rare earth element (REE) patterns comparable to their counterparts in type I chondrules in ordinary chondrites. They thus likely share a similar igneous origin, likely under similar redox conditions. The mesostasis however frequently shows negative Eu and/or Yb (and more rarely Sm) anomalies, evidently out of equilibrium with olivine and enstatite. We suggest that this reflects crystallization of oldhamite during a sulfidation event, already inferred by others, during which the mesostasis was molten, where the complementary positive Eu and Yb anomalies exhibited by oldhamite would have possibly arisen due to a divalent state of these elements. Much of this igneous oldhamite would have been expelled from the chondrules, presumably by inertial acceleration or surface tension effects, and would have contributed to the high abundance of opaque nodules found outside them in EH chondrites. In two chondrules, olivine and enstatite exhibit negatively sloped REE patterns, which may be an extreme manifestation of a general phenomenon (possibly linked to near‐liquidus partitioning) underlying the overabundance of light REE observed in most chondrule silicates relative to equilibrium predictions. The silicate phases in one of these two chondrules show complementary Eu, Yb, and Sm anomalies providing direct evidence for the postulated occurrence of the divalent state for these elements at some stage in the formation reservoir of enstatite chondrites. Our work supports the idea that the peculiarities of enstatite chondrites may not require a condensation sequence at high C/O ratios as has long been believed.     

GPS measurements of ground deformation induced by water level variations into a granitic aquifer (French Brittany)

We used two semi‐permanent GPS receivers with differential configuration to measure the hydrological subsidence of an aquifer used for water supply, located on a fractured granitic area. The time series of the vertical deformation measurements of the ground surface show a variation of 2 cm between winter and summer. We investigate the relationship between this vertical deformation and hydraulic head variations. We show that this kind of GPS survey allows characterizing part of the hydrological properties of such a heterogeneous aquifer. This is thus a new approach of time continuous monitoring of the deformation related to hydrogeological processes.     

The orbit and atmospheric trajectory of the Orgueil meteorite from historical records

Abstract— Using visual observations that were reported 140 years ago in the Comptes Rendus de l'Académie des Sciences de Paris, we have determined the atmospheric trajectory and the orbit of the Orgueil meteorite, which fell May 14, 1864, near Montauban, France. Despite the intrinsic uncertainty of visual observations, we were able to calculate a reasonably precise atmospheric trajectory and a moderately precise orbit for the Orgueil meteoroid. The atmosphere entry point was ?70 km high and the meteoroid terminal point was ?20 km high. The calculated luminous path was ?150 km with an entry angle of 20°. These characteristics are broadly similar to that of other meteorites for which the trajectory is known. Five out of six orbital parameters for the Orgueil orbit are well constrained. In particular, the perihelion lies inside the Earth's orbit (q ?0.87 AU), as is expected for an Earth‐crossing meteorite, and the orbital plane is close to the ecliptic (i ?0°). The aphelion distance (Q) depends critically on the pre‐atmospheric velocity. From the calculated atmospheric path and the fireball duration, which was reported by seven witnesses, we have estimated the pre‐atmospheric velocity to be larger than 17.8 km/sec, which corresponds to an aphelion distance Q larger than 5.2 AU, the semi‐major axis of Jupiter orbit. These results suggest that Orgueil has an orbit similar to that of Jupiter‐family comets (JFCs), although an Halley‐type comet cannot be excluded. This is at odds with other meteorites that have an asteroidal origin, but it is compatible with 140 years of data‐gathering that has established the very special nature of Orgueil compared to other meteorites. A cometary origin of the Orgueil meteorite does not contradict cosmochemistry data on CI1 chondrites. If CI1 chondrites originate from comets, it implies that comets are much more processed than previously thought and should contain secondary minerals. The forthcoming return of cometary samples by the Stardust mission will provide a unique opportunity to corroborate (or contradict) our hypothesis.     

Field evidence for flank instability,basal spreading and volcano-tectonic interactions at Mt Cameroon,West Africa

The Mt Cameroon volcano is the highest and most active volcano of the Cameroon Volcanic Line. Little geological information is available for improving the understanding of the structure of this large volcanic system and its relationship to regional tectonics. After reviewing the tectonic evolution of the region, the analysis of a Digital Elevation Model and results from a field campaign dedicated to mapping geological structures in the summit area and at the SE base of Mt Cameroon are presented. Mt Cameroon is a lava-dominated volcano with long steep (over 30°) flanks. It is elongate parallel to its well defined rift zone. The summit plateau is bordered by 10 m high cliffs formed by summit subsidence along normal faults. Geological profiles were measured along rivers cutting through a topographic step at the SE base of Mt Cameroon. This step is associated with deformed Miocene sediments from the Douala basin that are overlain by volcanic products. Weak sediments of this area are deformed by 050°–060° and 020°–030° trending asymmetrical folds verging toward the SE, and thrusts faults related to the spreading of the volcano over its mechanically weak substratum. Combined remote sensing and field observations suggest that spreading is accommodated by summit subsidence and flanks sliding. Both slow spreading movements and catastrophic collapses of the steep flanks are interpreted to result from complex interactions between the growing edifice, repeated dyke intrusions, the weak sedimentary substratum and tectonic structures.     

Disappearance of a crater lake: implications for potential explosivity at Soufrière volcano,St Vincent,Lesser Antilles

Soufrière volcano in St Vincent, West Indies, is one of the most active volcanoes in the Eastern Caribbean with at least six eruptions since 1718 AD, the latest of which occurred in 1979. Prior to the 1979 eruption, the active crater hosted deep-water lakes during periods of repose, which were always replenished within a few years after the eruptions. In 1979, the crater was filled with 10⁸ m³ of fragmental material and, despite constant precipitation, has remained virtually dry ever since, with the exception of a small shallow pond. A resistivity survey was conducted in July 2006 to investigate groundwater occurrence in the crater. Results from the resistivity data inversion on several 2-D profiles show a shallow horizontal conductor across the crater floor, consistent with a water-saturated aquifer. They also show that the post-1979 pond, currently present in the crater lake is in fact an outcropping part of the groundwater water reservoir. The reservoir water table is ∼28 m above the pre-1979 lake level and reflects mass equilibrium in the system where constant seepage underground balances the meteoric recharge. We suggest that the groundwater body extends at depth to the bottom of the pre-1979 crater lake, either due to a significant structural discontinuity or because of a reduction of permeability at depth. The estimated maximum volume of water stored underground is 10–30 × 10⁶ m³ and energy considerations indicate that 2.4–7.3 × 10¹⁰ kg of magma would potentially be sufficient to vaporise the whole groundwater body. This amount of magma represents only 13–41% of the mass erupted during the last eruption in 1979 which was the smallest of the past 3 eruptions (1902, 1971–72, 1979). Since explosive phreatic or phreatomagmatic eruptions at Soufrière seem to be linked to magma-water interaction within confined space, the results from this survey suggests that phreatic or phreatomagmatic activity is a distinct possibility during future magma intrusion in the summit area, despite the apparent disappearance of water in the summit crater.     

Metasomatism and graphite formation at a lithological interface in Malaspina (Alpine Corsica, France)

Multiple pieces of geologic evidence suggest that interfaces between contrasted lithologies exert a strong control on the fate of volatiles in subduction zones. Here we present results from a contact between serpentinites and sediments, located in Corsica and metamorphosed in the blueschist facies during the alpine orogeny. It was shown previously that carbonates in the sediments have been reduced to graphitic carbonaceous material within a 5–10-cm-thick reaction zone at the contact with serpentinites. In an effort to investigate the mechanisms governing this unusual process, bulk rock geochemical analyses incorporating a statistical analysis of compositional data are presented. Observations show that the fate of C was decoupled from that of other elements such as O, H, and large-ion lithophile elements—e.g. K, Sr, Ba...,As—that were extensively leached from the reaction zone. Notably, Na is strongly enriched in the reaction zone and structurally linked to pectolite. Reducing conditions, manifested by the depletion of O in the reaction zone compared to the bulk metasediment, were likely maintained by the presence of Fe(II) in the serpentinite. Moreover, thermodynamic calculations show that the low solubility of carbon in COH fluids at high-pressure and low-temperature conditions was the main driver for graphite precipitation synchronously with carbonate destabilization. This may have been kinetically favored by the presence of already existing graphitized carbonaceous material and phengite in the metasediment. Limited lateral flow might have contributed as well to the geochemical and petrological patterns observed in these rocks.     

Lower Palaeozoic unconformities in an intracratonic platform setting: glacial erosion versus tectonics in the eastern Murzuq Basin (southern Libya)

The stratigraphic record of the eastern Murzuq Basin has been importantly influenced by deformation resulting in angular and/or deeply erosional unconformities, though the overall context is intracratonic. Major transgressive events and the Ordovician glaciation are nevertheless documented, allowing the delineation of tectonic-, eustasy- or climate-driven unconformities. Lower Palaeozoic key events and related unconformities that characterize the North Gondwana platform have therefore a signature in the eastern Murzuq Basin. The basement/cover unconformity, also known as the infra-Tassilian surface, truncates all the deformed and metamorphosed Lower Cambrian and older rocks. Above is a ?Middle Cambrian to Lower Ordovician megasequence (Murizidié and Hasawnah Fms.), which is in turn truncated by an intra-Ordovician, angular unconformity. This megasequence is unconformably overlain by a Middle Ordovician (Hawaz Fm.) to Silurian (Tanzzuft and Akakus Fms) megasequence, which includes the Upper Ordovician glaciogenic unit (Mamuniyat Fm.), bounded at the base by a polygenic glacial erosion surface showing corrugated glacial lineations, tillites, and glaciotectonic structures. The Middle Ordovician to Silurian megasequence is finally truncated by a base-Devonian, angular unconformity overlain by fluvial sandstones. Regarding the possibility that those fluvial deposits may be as younger as Late Devonian in the eastern Murzuq Basin based on palaeoflora, the so-called Caledonian unconformity might be here a much younger (mid-Eifelian?) surface, and the occurrence of the Lower Devonian “Tadrart Fm.” is questioned. The Upper Ordovician glacial erosion surface, which is sometimes referred to as the Taconic unconformity, usually truncates Middle Ordovician strata in the Murzuq Basin but reaches significantly deeper stratigraphic levels in places that have been previously involved in the intra-Ordovician deformation event. In the Murizidié (southeastern Murzuq Basin), the infra-Tassilian surface, the intra-Ordovician unconformity, and the Upper Ordovician glacial erosion surface amalgamate together. Here, an estimate of the glacial erosion depth cannot be derived from the stratigraphic hiatus beneath the glacial incision, the main part of which relate to the intra-Ordovician tectonic event. The Upper Ordovician climate-related glacial erosion surface is not a valid unconformity for a sequence hierarchy framework of the Lower Palaeozoic, although it presents most of the physical attributes of tectonic-driven unconformities.     

Magnetic classification of stony meteorites: 2. Non‐ordinary chondrites

Abstract— A database of magnetic susceptibility (χ) measurements on different non‐ordinary chondrites (C, E, R, and ungrouped) populations is presented and compared to our previous similar work on ordinary chondrites. It provides an exhaustive study of the amount of iron‐nickel magnetic phases (essentially metal and magnetite) in these meteorites. In contrast with all the other classes, CM and CV show a wide range of magnetic mineral content, with a two orders of magnitude variation of χ. Whether this is due to primary parent body differences, metamorphism or alteration, remains unclear. C3–4 and C2 yield similar χ values to the ones shown by CK and CM, respectively. By order of increasing χ, the classes with well‐grouped χ are: R << CO < CK ≈ CI < Kak < CR < E ≈ CH < CB. Based on magnetism, EH and EL classes have indistinguishable metal content. Outliers that we suggest may need to have their classifications reconsidered are Acfer 202 (CO), Elephant Moraine (EET) 96026 (C4–5), Meteorite Hills (MET) 01149, and Northwest Africa (NWA) 521 (CK), Asuka (A)‐88198, LaPaz Icefield (LAP) 031156, and Sahara 98248 (R). χ values can also be used to define affinities of ungrouped chondrites, and propose pairing, particularly in the case of CM and CV meteorites.     

Contrasting the termination of moderate and extreme El Niño events in coupled general circulation models

As in the observed record, the termination of El Niño in the coupled IPCC-AR4 climate models involves meridional processes tied to the seasonal cycle. These meridional processes both precondition the termination of El Niño events in general and lead to a peculiar termination of extreme El Niño events (such as those of 1982–83 and 1997–98), in which the eastern equatorial Pacific warm sea surface temperature anomalies (SSTA) persist well into boreal spring/early-summer. The mechanisms controlling the peculiar termination of extreme El Niño events, which involves to the development of an equatorially centred intertropical convergence zone, are consistent across the four models that exhibit extreme El Niños and observational record, suggesting that this peculiar termination represents a general feature of extreme El Niños. Further, due to their unusual termination, extreme El Niños exhibit an apparent eastward propagation of their SSTA, which can strongly influence estimates of the apparent propagation of ENSO over multi-decadal periods. Interpreting these propagation changes as evidence of changes in the underlying dynamical feedbacks behind El Niño could therefore be misleading, given the strong influence of a single extreme event.